scholarly journals MANGANESE MINERALISATIONS AT THE BASE OF MIOCENE SEDIMENTS IN NORTHERN SARDINIA (ITALY)

2017 ◽  
Vol 43 (5) ◽  
pp. 2588
Author(s):  
S. Fadda ◽  
M. Fiori ◽  
S. Pretti ◽  
P. Valera

During the eastward drift of the Palaeozoic-Mesozoic block formed by Sardinia and Corsica in the Oligocene-Miocene, calc-alkaline volcanism developed mostly in the western part of the island. Most Tertiary metallogenic phoenomena are related to hydrothermal activity associated with this volcanism. Following volcanic and related hydrothermal activity, sediments were deposited during the Oligocene-Miocene as a consequence of a marine transgression. The basal part of this series is clastic and includes elements derived from erosion of unaltered volcanics as well as hydrothermally altered rocks and hydrothermal vein quartz. Inside the Tertiary volcanics manganese ore-minerals occur as nodules, veinlets, and stockworks and mainly include Mn and Fe oxides; quartz in different forms is the most common gangue mineral. The mineralisations at the contact between volcanics and Miocene sediments are the most homogeneous, the ore-minerals occur in the cement, but also as fairly continuous thin beds, nodules and veinlets containing pyrolusite, frequent ramsdellite, less frequent manganite, psilomelane, cryptomelane-manjiroite, rare ranciéite, and todorokite. The nature of the ore-bearing beds indicate a near-shore clastic environment along the ancient coastal lines of the Miocene sea. Genetic considerations point to a supergenic transport and redeposition after erosion of primary dispersion and residual concentrations of Mn in the volcanics.

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Myo Min Tun ◽  
I Wayan Warmada ◽  
Arifudin Idrus ◽  
Agung Harijoko ◽  
Okki Verdiansyah ◽  
...  

Cijulang is a high-sulfidation epithermal system hosted in the calc-alkaline rocks of andesite lava and lapilli tuff. Mineralization in the prospect is characterized by pyrite-enargite-gold and associated acid sulfate alteration. Studies on ore and gangue mineral assemblages and their mutual textural relationships were carried out in order to explore the paragenetic sequence of mineralization. Hypogene mineralization primarily occurs in the silicic core and the advanced argillic zone in the form of massive replacement, fracture-filling veinlets, vug-filling, patches and dissemination. Mineralization is apparently controlled by both lithology and structures. Common ore minerals include pyrite, enargite, luzonite, tennantite, chalcopyrite, covellite, galena, emplectite and Te-bearing minerals. The paragenetic study indicates that the epithermal prospect evolved from an early stage of intense acid leaching resulting in the formation of vuggy silica and advantage argillic mineral assemblage which was followed by the sulfides deposition. Two metal stages were identified during ore deposition: an early Fe-As-S stage and the later Cu-Fe-As-S stage. The former stage is char- acterized high-sulfidation state sulfides such as enargite/ luzonite+covellite whereas a later stage of Cu- Fe-As–S is represented by intermediate sulfidation state sulfides assemblage of tennantite+chalcopyrite. Gold is probably introduced in the early stage within the ore system and more abundant in the late stage. Keywords: Cijulang, high-sulfidation, acid sulfate, mineralization, enargite, paragenetic, metal stages


2006 ◽  
Vol 11 ◽  
pp. 101-114 ◽  
Author(s):  
Henrik Stendal ◽  
Karsten Secher ◽  
Robert Frei

Pb-isotopic data for magnetite from amphibolites in the Nagssugtoqidian orogen, central West Greenland, have been used to trace their source characteristics and the timing of metamorphism. Analyses of the magnetite define a Pb-Pb isochron age of 1726 ± 7 Ma. The magnetite is metamorphic in origin, and the 1726 Ma age is interpreted as a cooling age through the closing temperature of magnetite at ~600°C. Some of the amphibolites in this study come from the Naternaq supracrustal rocks in the northern Nagssugtoqidian orogen, which host the Naternaq sulphide deposit and may be part of the Nordre Strømfjord supracrustal suite, which was deposited at around 1950 Ma ago. Pb-isotopic signatures of magnetite from the Arfersiorfik quartz diorite in the central Nagssugtoqidian orogen are compatible with published whole-rock Pb-isotopic data from this suite; previous work has shown that it is a product of subduction-related calc-alkaline magmatism between 1920 and 1870 Ma. Intrusion of pegmatites occurred at around 1800 Ma in both the central and the northern parts of the orogen. Pegmatite ages have been determined by Pb stepwise leaching analyses of allanite and monazite, and source characteristics of Pb point to an origin of the pegmatites by melting of the surrounding late Archaean and Palaeoproterozoic country rocks. Hydrothermal activity took place after pegmatite emplacement and continued below the closure temperature of magnetite at 1800– 1650 Ma. Because of the relatively inert and refractory nature of magnetite, Pb-isotopic measurements from this mineral may be of help to understand the metamorphic evolution of geologically complex terrains.


Minerals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 408
Author(s):  
Brenton J. Fairey ◽  
Martin J. Timmerman ◽  
Masafumi Sudo ◽  
Harilaos Tsikos

The Postmasburg Manganese Field (PMF), Northern Cape Province, South Africa, once represented one of the largest sources of manganese ore worldwide. Two belts of manganese ore deposits have been distinguished in the PMF, namely the Western Belt of ferruginous manganese ores and the Eastern Belt of siliceous manganese ores. Prevailing models of ore formation in these two belts invoke karstification of manganese-rich dolomites and residual accumulation of manganese wad which later underwent diagenetic and low-grade metamorphic processes. For the most part, the role of hydrothermal processes and metasomatic alteration towards ore formation has not been adequately discussed. Here we report an abundance of common and some rare Al-, Na-, K- and Ba-bearing minerals, particularly aegirine, albite, microcline, banalsite, sérandite-pectolite, paragonite and natrolite in Mn ores of the PMF, indicative of hydrothermal influence. Enrichments in Na, K and/or Ba in the ores are generally on a percentage level for most samples analysed through bulk-rock techniques. The presence of As-rich tokyoite also suggests the presence of As and V in the hydrothermal fluid. The fluid was likely oxidized and alkaline in nature, akin to a mature basinal brine. Various replacement textures, particularly of Na- and K- rich minerals by Ba-bearing phases, suggest sequential deposition of gangue as well as ore-minerals from the hydrothermal fluid, with Ba phases being deposited at a later stage. The stratigraphic variability of the studied ores and their deviation from the strict classification of ferruginous and siliceous ores in the literature, suggests that a re-evaluation of genetic models is warranted. New Ar-Ar ages for K-feldspars suggest a late Neoproterozoic timing for hydrothermal activity. This corroborates previous geochronological evidence for regional hydrothermal activity that affected Mn ores at the PMF but also, possibly, the high-grade Mn ores of the Kalahari Manganese Field to the north. A revised, all-encompassing model for the development of the manganese deposits of the PMF is then proposed, whereby the source of metals is attributed to underlying carbonate rocks beyond the Reivilo Formation of the Campbellrand Subgroup. The main process by which metals are primarily accumulated is attributed to karstification of the dolomitic substrate. The overlying Asbestos Hills Subgroup banded iron formation (BIF) is suggested as a potential source of alkali metals, which also provides a mechanism for leaching of these BIFs to form high-grade residual iron ore deposits.


2020 ◽  
Author(s):  
Ali Erdem Bakkalbasi ◽  
Hatice Nur Bayram ◽  
Mustafa Kumral ◽  
Ali Tugcan Unluer

<p><strong>Geochemical significance and Formation of  Suçatı Pb-Zn Deposits – Eastern Taurides</strong></p><p>Hatice Nur Bayram<sup>(1)*</sup>, Ali Erdem Bakkalbaşı <sup>(1)*</sup>, Mustafa Kumral<sup>(1)</sup>, Ali Tuğcan Ünlüer<sup>(1)</sup></p><p><sup>(1)</sup>Istanbul Technical University, Department of Geological Engineering, Istanbul/Turkey</p><p>(*E-mail: [email protected])</p><p> </p><p>The Middle Tauride Orogenic Belt is a productive enviroment in terms of Pb-Zn ore deposits, mostly associated with Permian aged dolomitized, shallow marine platform type carbonate rocks. There have been many studies on the origin of the ore deposits in the region, there are two important approaches that stand out for the formation of the ore deposits: the first theory is hydrothermal deposits with magmatic origin, and the other theory is Missisippi Valley-type (MVT) deposits related with the carbonate rocks commonly found in the region. Field studies at the Suçatı (Kayseri – Yahyalı, Central Anatolia, Turkey, East of Aladağlar extension of the Taurides) ore district in the Aladağ geologic unit indicate that the deposits in the region are associated with Paleo-Tethys limestones, fossiliferous limestones and dolomitic limestones. Mineralization is related to Lower Permian aged carbonate rocks include primary mineralization ore minerals as galena, sphalerite, smithsonite and goethite and as a product of hydrothermal activity, calcite mineral filled within fractures and cracks represents gangue minerals. As a result of geochemical analysis of the samples collected from the ore zones, PbO values range between 25.93% - 0.012%, ZnO values range between 51.01% - 0.042%, Fe<sub>2</sub>O<sub>3</sub> values range between 42.81% - 10.21%. In conclusion hydrothermal activities closely related with compressional and extentional tectonic regimes took place in multiphase mineralization.</p><p> </p><p><strong>Keywords:</strong> Pb-Zn Deposits, MVT, Taurides, Yahyalı</p>


1958 ◽  
Vol 53 (1) ◽  
pp. 109-0
Author(s):  
B. L. Sreenivas
Keyword(s):  

2013 ◽  
Vol 47 (1) ◽  
pp. 477 ◽  
Author(s):  
P. Voudouris ◽  
I. Psimis ◽  
C. Mavrogonatos ◽  
C. Kanellopoulos ◽  
M. Kati ◽  
...  

Epithermal-altered volcanic rocks in Greece host gem-quality amethyst veins in association with various silicates, carbonates, oxides, sulfides and halides. Host rocks are Oligocene to recent calc-alkaline to shoshonitic lavas and pyroclastics of intermediate- to acid composition. The amethyst-bearing veins occur in the periphery of porphyry-type and/or high-sulfidation epithermal mineralized centers in northern Greece (e.g. Sapes, Kirki, Kornofolia/Soufli, Lesvos island) and on Milos island in the active Aegean Volcanic Arc. Hydrothermal alteration around the quartz veins includes sericitic, K-feldspar (adularia), argillic, propylitic and zeolitic types. Precipitation of amethyst in the northern Greece occurrences, took place during the final stages of the magmatic-hydrothermal activity from near-neutral to alkaline fluids, as indicated by the presence of gangue adularia, calcite, smectite, chlorite, sericite, pyrite, zeolites (laumontite, heulandite, clinoptilolite), analcime and minor amounts of barite, halite, epidote and fluorite in the quartz veins. Amethyst at Milos Island (Chondro Vouno and Kalogries-Vani areas), is accompanied by barite, smectite and lepidocrocite. Colloform-crustiform banding with alternations of amethyst, chalcedony and/or carbonates is a common characteristic of the studied amethyst-bearing veins. Fluid inclusion- and mineralogical data suggest that the studied amethyst were formed at: 174-246 °C (Sapes area), 100-175 °C (Kirki and Kornofolia areas) and 223-234°C (Lesvos island). The amethyst formation requires oxidizing conditions and is probably the result of mixing between meteoric or seawater with upwelling hydrothermal fluids. The involvement of seawater in the studied mineralization is supported by the presence of halite and abundant barite in the veins. Finally, the studied amethyst deposits should be evaluated as potential gemstone sources in Greece.


1995 ◽  
Vol 11 ◽  
Author(s):  
M. R. Dhital

In the Gorkha-Ampipal area, low-grade metamorphic rocks of the Kuncha Formation are delimited in the north by the Masel Thrust. The Kuncha Formation is characterised by doubly-plunging, en-echelon types of noncylindrical folds which are 2 to 20 km long (essentially in NW-SE direction), and have wavelengths of a few km. Mineral and stretching lineations are gently plunging due NNE or SSW. The hanging wall of the Masel Thrust is represented by garnet-biotite schists and gneisses. The schists and gneisses make up a steeply northward dipping homocline. In contrast to the rocks of the footwall, they are generally gently dipping and constitute several mesoscopic folds. Further north, the homocline is discordantly overlain by the intensely deformed unit of phyllites, graphitic schists, marbles, crystalline limestones, and calcareous quartzites. The Main Central Thrust sharply overrides the latter unit and brings with it gently northward dipping kyanite-garnet-biotite schists, quartzites, feldspathic schists, and mylonitic gneisses. There are several nepheline syenite intrusive bodies in the Kuncha Formation in the vicinity of the villages Harmi Bhnnjyang, Ampipal, Chanp Bhanjyang, Bhulbhule Khar, and Luintel Bhanjyang. Two separate bodies are also encountered at the confluence of the Masel Khola and the Daraundi Khola. The nepheline syenite bodies observed in the study area vary widely in their shape, size, and orientation. The largest pluton is observed in the vicinity of the villages Ampipal and Chanp Bhanjyang. It is about 7.5 km long in NNE-SSW direction and about 2 km wide. The second largest body is observed between the villages Bandre and Luintel Bhanjyang. It is about 2.5 km long approximately in east-west direction and 300 m wide. Numerous other smaller bodies ranging in size from hundreds of m to a few cm also occur in the region. The nephelinesyenites show sharp and irregular contacts with the country rock, they are crosscut by numerous dykes, and occasionally the effect of contact metamorphism is also observed in the country rock. The northeastern part of the largest nepheline syenite pluton (which occurs between Ampipal and Chanp Bhanjyang) is covered by about 500 m thick band of impure marbles. Rare, thin alternations of impure marble with phyllite as well as large (more than 10 m in diameter) scattered marble boulders areseen on the slopes NE of Chanp Bhanjyang, N of Bhulbhule Khar, at the saddle of Lagamkot, and at Khanigaun. The secondary mineralisation in the marbles is represented by magnetite, actinolite, biotite, and chlorite. There exist a few old iron mine workings in the magnetite mineralisation zones. Similar minerals are also seen in the nepheline syenite suggesting a direct relationship between the mineralisation in the nepheline syenite and the marbles. Generally, the nepheline syenite bodies exhibit the same trends of foliation and lineation as those of the country rock, and therefore, they must be intruded before the development of the secondary structures. There are a few hot springs at Bhulbhule Khar, which contain a high amount of H2S gas and sulphur, and are coming through the nepheline syenite. The development of copper as well as other secondary ore minerals and several generations of veins in the country rock, and the presence of hot springs probably indicate a continued hydrothermal activity in that area up to the recent times.


Sign in / Sign up

Export Citation Format

Share Document