scholarly journals HIGH SULFIDATION EPITHERMAL MINERALIZATION AND ORE MINERAL ASSEMBLAGES OF CIJULANG PROSPECT, WEST JAVA, INDONESIA

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Myo Min Tun ◽  
I Wayan Warmada ◽  
Arifudin Idrus ◽  
Agung Harijoko ◽  
Okki Verdiansyah ◽  
...  
Keyword(s):  
Mineral Assemblage ◽  
Early Stage ◽  
Acid Leaching ◽  
Gangue Mineral ◽  
Calc Alkaline ◽  
Acid Sulfate ◽  
High Sulfidation ◽  
Epithermal Mineralization ◽  
Mineral Assemblages ◽  
Ore Minerals

Cijulang is a high-sulfidation epithermal system hosted in the calc-alkaline rocks of andesite lava and lapilli tuff. Mineralization in the prospect is characterized by pyrite-enargite-gold and associated acid sulfate alteration. Studies on ore and gangue mineral assemblages and their mutual textural relationships were carried out in order to explore the paragenetic sequence of mineralization. Hypogene mineralization primarily occurs in the silicic core and the advanced argillic zone in the form of massive replacement, fracture-filling veinlets, vug-filling, patches and dissemination. Mineralization is apparently controlled by both lithology and structures. Common ore minerals include pyrite, enargite, luzonite, tennantite, chalcopyrite, covellite, galena, emplectite and Te-bearing minerals. The paragenetic study indicates that the epithermal prospect evolved from an early stage of intense acid leaching resulting in the formation of vuggy silica and advantage argillic mineral assemblage which was followed by the sulfides deposition. Two metal stages were identified during ore deposition: an early Fe-As-S stage and the later Cu-Fe-As-S stage. The former stage is char- acterized high-sulfidation state sulfides such as enargite/ luzonite+covellite whereas a later stage of Cu- Fe-As–S is represented by intermediate sulfidation state sulfides assemblage of tennantite+chalcopyrite. Gold is probably introduced in the early stage within the ore system and more abundant in the late stage. Keywords: Cijulang, high-sulfidation, acid sulfate, mineralization, enargite, paragenetic, metal stages

scholarly journals MANGANESE MINERALISATIONS AT THE BASE OF MIOCENE SEDIMENTS IN NORTHERN SARDINIA (ITALY)

2017 ◽  
Vol 43 (5) ◽  
pp. 2588
Author(s):  
S. Fadda ◽  
M. Fiori ◽  
S. Pretti ◽  
P. Valera
Keyword(s):  
Hydrothermal Activity ◽  
Gangue Mineral ◽  
Manganese Ore ◽  
Calc Alkaline ◽  
Vein Quartz ◽  
Marine Transgression ◽  
Hydrothermal Vein ◽  
Fe Oxides ◽  
Ore Minerals ◽  
Near Shore

During the eastward drift of the Palaeozoic-Mesozoic block formed by Sardinia and Corsica in the Oligocene-Miocene, calc-alkaline volcanism developed mostly in the western part of the island. Most Tertiary metallogenic phoenomena are related to hydrothermal activity associated with this volcanism. Following volcanic and related hydrothermal activity, sediments were deposited during the Oligocene-Miocene as a consequence of a marine transgression. The basal part of this series is clastic and includes elements derived from erosion of unaltered volcanics as well as hydrothermally altered rocks and hydrothermal vein quartz. Inside the Tertiary volcanics manganese ore-minerals occur as nodules, veinlets, and stockworks and mainly include Mn and Fe oxides; quartz in different forms is the most common gangue mineral. The mineralisations at the contact between volcanics and Miocene sediments are the most homogeneous, the ore-minerals occur in the cement, but also as fairly continuous thin beds, nodules and veinlets containing pyrolusite, frequent ramsdellite, less frequent manganite, psilomelane, cryptomelane-manjiroite, rare ranciéite, and todorokite. The nature of the ore-bearing beds indicate a near-shore clastic environment along the ancient coastal lines of the Miocene sea. Genetic considerations point to a supergenic transport and redeposition after erosion of primary dispersion and residual concentrations of Mn in the volcanics.

scholarly journals Petrogenesis of a late-stage calc-alkaline granite in a giant S-type batholith: geochronology and Sr–Nd–Pb isotopes from the Nomatsaus granite (Donkerhoek batholith), Namibia

2021 ◽  
Author(s):  
S. Aspiotis ◽  
S. Jung ◽  
F. Hauff ◽  
R. L. Romer
Keyword(s):  
Partial Melting ◽  
Mineral Assemblage ◽  
Central Zone ◽  
Calc Alkaline ◽  
Pb Isotope ◽  
Alkaline Granite ◽  
Ti Oxides ◽  
Eu Anomaly ◽  
Environment Characteristic ◽  
Southern Central

AbstractThe late-tectonic 511.4 ± 0.6 Ma-old Nomatsaus intrusion (Donkerhoek batholith, Damara orogen, Namibia) consists of moderately peraluminous, magnesian, calc-alkalic to calcic granites similar to I-type granites worldwide. Major and trace-element variations and LREE and HREE concentrations in evolved rocks imply that the fractionated mineral assemblage includes biotite, Fe–Ti oxides, zircon, plagioclase and monazite. Increasing K2O abundance with increasing SiO2 suggests accumulation of K-feldspar; compatible with a small positive Eu anomaly in the most evolved rocks. In comparison with experimental data, the Nomatsaus granite was likely generated from meta-igneous sources of possibly dacitic composition that melted under water-undersaturated conditions (X H2O: 0.25–0.50) and at temperatures between 800 and 850 °C, compatible with the zircon and monazite saturation temperatures of 812 and 852 °C, respectively. The Nomatsaus granite has moderately radiogenic initial 87Sr/86Sr ratios (0.7067–0.7082), relatively radiogenic initial εNd values (− 2.9 to − 4.8) and moderately evolved Pb isotope ratios. Although initial Sr and Nd isotopic compositions of the granite do not vary with SiO2 or MgO contents, fSm/Nd and initial εNd values are negatively correlated indicating limited assimilation of crustal components during monazite-dominated fractional crystallization. The preferred petrogenetic model for the generation of the Nomatsaus granite involves a continent–continent collisional setting with stacking of crustal slices that in combination with high radioactive heat production rates heated the thickened crust, leading to the medium-P/high-T environment characteristic of the southern Central Zone of the Damara orogen. Such a setting promoted partial melting of metasedimentary sources during the initial stages of crustal heating, followed by the partial melting of meta-igneous rocks at mid-crustal levels at higher P–T conditions and relatively late in the orogenic evolution.

The occurrence of gold in Voia deposit, South Apuseni Mountains, Romania

2021 ◽  
Author(s):  
Elena-Luisa Iatan
Keyword(s):  
Iron Oxides ◽  
Base Metal ◽  
Mineral Assemblage ◽  
Native Gold ◽  
Metal Sulfides ◽  
Volcanic Complex ◽  
Apuseni Mountains ◽  
Base Metal Sulfides ◽  
Mineral Assemblages ◽  
Phyllic Alteration

<p>Voia deposit belongs to the Săcărâmb-Cetraș-Cordurea Miocene volcano-tectonic alignment of the South Apuseni Mountains, Romania. This large volcanic complex represents a Sarmatian-Pannonian magmatic-hydrothemal mega-system of around 5 km<sup>2</sup> with an estimated 3–4 Ma time-space evolution, consisting of seven andesitic volcanic structures grouped in a circle, three subvolcanic andesite-quartz porphyry microdiorite and associated porphyry Cu-Au(Mo), pyrite Ca-Mg skarns and epithermal Au-Ag-Pb-Zn-Cu mineralizations.</p><p>The mineral assemblages of alteration and mineralization processes belong to several mineralized zones on a vertical scale, according to sampling evidence and laboratory studies. HS products are found in the upper part of the structure (300-500 m), with dominant advanced and intermediate argillic alterations and sulfide-sulfate gold-poor veins (pyrite, marcasite, base metal sulfides, Fe-Ti oxides, vuggy quartz, alunite, gypsum, anhydrite). Within the 500-1200 m depth, the HS mineral assemblages gradually decrease in favor of IS and LS products. It is characterized by the coexistence of gold-rich LS assemblage (native gold, base metal sulfide, adularia, sericite-illite, chlorite, carbonates ± anhydrite veins), with the IS assemblage (iron oxides, chalcopyrite, pyrite, quartz, anhydrite). These assemblages overprint the HS mineral associations, resulting in a transition zone characterized by gold - pyrite - chalcopyrite - iron oxides - quartz - anhydrite mineral assemblage characteristic for HS and native gold - pyrite - base metal sulfides - carbonates - quartz mineral assemblage corresponding to IS+LS type.</p><p>Gold is present in all of the identified mineralization forms: porphyry-epithermal Cu-Au, epi-mesothermal carbonate veins with gold - base metal sulfides, quartz veins with pyrite - chalcopyrite - magnetite ± hematite ± anhydrite, anhydrite veins with base metal sulfides and sulfosalts, anhydrite veins with pyrite - anhydrite ± quartz, vuggy quartz (silica residue) with gold-poor pyrite veins and impregnations in porphyry systems.</p><p>Drilling core samples revealed that in Voia deposit, gold is concentrated in chalcopyrite (drills no. 7, 19, 37) along with pyrite - magnetite - hematite - quartz assemblage from the late potassic stage. The major amount of gold associated with chalcopyrite tends to be mainly submicroscopic. Pyrite from anhydrite veins of the early potassic stage ± phyllic alteration is relatively poor in gold (drills no. 1-6, 8-14). However, the highest gold contents are present in pentagonal dodecahedron pyrites (drills no. 33, 38, 39) of pyrite-chalcopyrite-magnetite ± hematite-quartz assemblage from late potassic stage ± phyllic alteration. Pyrite associated with magnetite from anhydrite veins tends to be poor in gold (drills no. 8, 11, 15, 28, 29). A carbonate vein containing gold-bearing base metal sulfides that was intercepted at 960,00-960,30m depth by drill no. 17 is one of the richest in gold.</p><p>Native gold occurs as fine inclusions in ore minerals (5-20 μm). Large irregular grains of native gold (>50 μm) appear at mineral boundaries and along the fissures. The gold color is bright yellow and has a measured Au:Ag ratio of 5:1, suggesting that native gold has been formed at a relatively high temperature.</p><p>Acknowledgments: This work was supported by two Romanian Ministry of Research and Innovation grants: PN-III-P4-ID-PCCF-2016-4-0014 and PN-III-P1-1.2-PCCDI-2017-0346/29.</p>

The system Pd–Ag–S: phase relations and mineral assemblages

2020 ◽  
Vol 84 (1) ◽  
pp. 125-130
Author(s):  
Anna Vymazalová ◽  
František Laufek ◽  
Alexandr V. Kristavchuk ◽  
Dmitriy A. Chareev
Keyword(s):  
Mineral Assemblage ◽  
Glass Tube ◽  
S Phase ◽  
Mineral Deposits ◽  
Mineral Assemblages ◽  
Pd Alloy ◽  
Stable Association ◽  
Silver Palladium ◽  
New Phase ◽  
Silica Glass Tube

AbstractPhase equilibria in the system Pd–Ag–S were studied using the silica-glass tube method at 400°C and 550°C. In the system we synthesised three ternary phases: coldwellite (Pd3Ag2S), kravtsovite (PdAg2S) and a new phase Pd13Ag3S4. At 400°С, coldwellite forms a stable association with vysotskite (PdS) and vasilite (Pd16S7); vysotskite and kravtsovite; phase Pd4S and a Ag–Pd alloy; it also coexists with a new phase Pd13Ag3S4. Kravtsovite is stable up to 507°C; the presence of kravtsovite in the mineral assemblage reflects its formation below this temperature. The occurrence of coldwellite, vysotskite and Ag2S together in equilibrium reflects the formation of this mineral assemblage above this temperature (507°C). Coldwellite is stable up at 940°С. Mineral assemblages defined in this study can be expected in Cu–Ni–PGE mineral deposits, associated with mafic and ultramafic igneous rocks, in particular in mineralisations with known silver–palladium sulfides.

scholarly journals A step towards unraveling the paleogeographic attribution of pre-Mesozoic basement complexes in the Western Alps based on U–Pb geochronology of Permian magmatism

2020 ◽  
Vol 113 (1) ◽  
Author(s):  
Michel Ballèvre ◽  
Audrey Camonin ◽  
Paola Manzotti ◽  
Marc Poujol
Keyword(s):  
Early Stage ◽  
Western Alps ◽  
Geochemical Data ◽  
Alkaline Magmatism ◽  
Low Grade ◽  
Calc Alkaline ◽  
Alpine Orogeny ◽  
History Of ◽  
External Part ◽  
The One

Abstract The Briançonnais Domain (Western Alps) represented the thinned continental margin facing the Piemonte-Liguria Ocean, later shortened during the Alpine orogeny. In the external part of the External Briançonnais Domain (Zone Houillère), the Palaeozoic basement displays microdioritic intrusions into Carboniferous sediments and andesitic volcanics resting on top of the Carboniferous sediments. These magmatic rocks are analysed at two well-known localities (Guil volcanics and Combarine sill). Geochemical data show that the two occurrences belong to the same calc-alkaline association. LA-ICP-MS U–Pb ages have been obtained for the Guil volcanics (zircon: 291.3 ± 2.0 Ma and apatite: 287.5 ± 2.6 Ma), and the Combarine sill (zircon: 295.9 ± 2.6 Ma and apatite: 288.0 ± 4.5 Ma). These ages show that the calc-alkaline magmatism is of Early Permian age. During Alpine orogeny, a low-grade metamorphism, best recorded by lawsonite-bearing veins in the Guil andesites, took place at about 0.4 GPa, 350 °C in the External Briançonnais and Alpine metamorphism was not able to reset the U–Pb system in apatite. The Late Palaeozoic history of the Zone Houillère is identical to the one recorded in the Pinerolo Unit, located further East in the Dora-Maira Massif, and having experienced a garnet-blueschist metamorphism during the Alpine orogeny. The comparison of these two units allows for a better understanding of the link between the Palaeozoic basements, mostly subducted during the Alpine convergence, and their Mesozoic covers, generally detached at an early stage of the convergence history.

scholarly journals Magmatic sulfides in high-potassium calc-alkaline to shoshonitic and alkaline rocks

Solid Earth ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 1-21 ◽  
Author(s):  
Ariadni A. Georgatou ◽  
Massimo Chiaradia
Keyword(s):  
Solid Solution ◽  
Early Stage ◽  
Volcanic Field ◽  
Geodynamic Setting ◽  
Calc Alkaline ◽  
High Potassium ◽  
Western Turkey ◽  
Monosulfide Solid Solution ◽  
Magmatic Sulfides ◽  
Saturation Stage

Abstract. We investigate the occurrence and chemistry of magmatic sulfides and their chalcophile metal cargo behaviour during the evolution of compositionally different magmas from diverse geodynamic settings both in mineralised and barren systems. The investigated areas are the following: (a) the Miocene Konya magmatic province (hosting the Doğanbey Cu–Mo porphyry and Inlice Au epithermal deposits, representing post-subduction) and (b) the Miocene Usak basin (Elmadag, Itecektepe, and Beydagi volcanoes, the latter associated with the Kişladağ Au porphyry in western Turkey, representing post-subduction). For comparison we also investigate (c) the barren intraplate Plio-Quaternary Kula volcanic field west of Usak. Finally, we discuss and compare all the above areas with the already studied (d) Quaternary Ecuadorian volcanic arc (host to the Miocene Llurimagua Cu–Mo and Cascabel Cu–Au porphyry deposits, representing subduction). The volcanism of the newly studied areas ranges from basalts to andesites–dacites and from high-K calc-alkaline to shoshonitic series. Multiphase magmatic sulfides occur in different amounts in rocks of all investigated areas, and, based on textural and compositional differences, they can be classified into different types according to their crystallisation at different stages of magma evolution (early versus late saturation). Our results suggest that independently of the magma composition, geodynamic setting, and association with an ore deposit, sulfide saturation occurred in all investigated magmatic systems. Those systems present similar initial metal contents of the magmas. However, not all studied areas present all sulfide types, and the sulfide composition depends on the nature of the host mineral. A decrease in the sulfide Ni∕Cu (a proxy for the monosulfide solid solution (mss) to intermediate solid solution (iss) ratio) is noted with magmatic evolution. At an early stage, Ni-richer, Cu-poorer sulfides are hosted by early crystallising minerals, e.g. olivine–pyroxene, whereas, at a later stage, Cu-rich sulfides are hosted by magnetite. The most common sulfide type in the early saturation stage is composed of a Cu-poor, Ni-rich (pyrrhotite mss) phase and one to two Cu-rich (cubanite, chalcopyrite iss) phases, making up ∼84 and ∼16 area % of the sulfide, respectively. Sulfides resulting from the late stage, consisting of Cu-rich phases (chalcopyrite, bornite, digenite iss), are hosted exclusively by magnetite and are found only in evolved rocks (andesites and dacites) of magmatic provinces associated with porphyry Cu (Konya and Ecuador) and porphyry Au (Beydagi) deposits.

scholarly journals Magmatic sulphides in high-K calc-alkaline to shoshonitic and alkaline rocks

2019 ◽  
Author(s):  
Ariadni Georgatou ◽  
Massimo Chiaradia
Keyword(s):  
Solid Solution ◽  
Early Stage ◽  
Volcanic Field ◽  
Geodynamic Setting ◽  
Calc Alkaline ◽  
Western Turkey ◽  
Epithermal Deposits ◽  
High K ◽  
Wide Range ◽  
Magmatic Sulphides

Abstract. We investigate in both mineralised and barren systems the occurrence and chemistry of magmatic sulphides and their chalcophile metal cargo behaviour during evolution of compositionally different magmas in diverse geodynamic settings. The investigated areas are: (a) the Miocene Konya magmatic province (hosting the Doganbey Cu-Mo and Inlice Au-epithermal deposits) (Post-Subduction) and (b) the Miocene Usak basin (Elmadag, Itecektepe and Beydagi volcanoes, the latter associated with the Kisladag Au porphyry) in Western Turkey (Post-Subduction). For comparison we also investigate (c) the barren Plio-Quaternary Kula volcanic field, west of Usak (Intraplate) and finally we discuss and compare all the above areas with the already studied (d) Quaternary Ecuadorian volcanic arc (host to the Miocene Llurimagua Cu-Mo and Cascabel Cu-Au porphyry deposits) (Subduction). The volcanism of the studied areas displays a wide range of SiO2 spanning from basalts to andesites/dacites and from high K-calc-alkaline to shoshonitic series. Multiphase magmatic sulphides occur in different amounts in all investigated areas and based on textural and compositional differences, they can be classified in different types, which crystallised at different times (early versus late saturation). A decrease in the sulphide Ni/Cu (proxy for mss-monosulphide solid solution/iss-intermediate solid solution) ratio is noted with magmatic evolution. Starting with an early stage, saturating Ni-richer/Cu-poorer sulphides hosted by early crystallising minerals e.g. olivine/pyroxene, leading up to a later stage, producing Cu-richer sulphides hosted by magnetite. The most common sulphide type resulting from an early saturating stage is composed of a Cu-poor/Ni-rich (pyrrhotite/mss) and one/two Cu-rich (cubanite, chalcopyrite/iss) phases making up 84 and 16 area % of the sulphide, respectively. Our results suggest that independently of the magma composition, geodynamic setting and whether or not the system has generated an ore deposit on the surface, sulphide saturation occurred in variable degrees in all studied areas and magmatic systems and is characterised by a similar initial metal content of the magmas. However not all studied areas present all sulphide types and the sulphide composition is dependent on the nature of the host mineral. In particular sulphides, resulting from the late stage, consisting of Cu-rich phases (chalcopyrite ,bornite, digenite/iss) are hosted exclusively by magnetite and are found only in magmatic provinces associated with porphyry Cu (Konya and Ecuador) and porphyry Au (Beydagi) deposits.

Venting of Acid-Sulfate Fluids in a High-Sulfidation Setting at NW Rota-1 Submarine Volcano on the Mariana Arc

2007 ◽  
Vol 102 (6) ◽  
pp. 1047-1061 ◽  
Author(s):  
J. A. Resing ◽  
G. Lebon ◽  
E. T. Baker ◽  
J. E. Lupton ◽  
R. W. Embley ◽  
...  
Keyword(s):  
Submarine Volcano ◽  
Acid Sulfate ◽  
High Sulfidation ◽  
Mariana Arc
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