Facile Synthesis of Optically Active Tertiary Alcohol Building Blocks by Stereospecific C–H Insertion Reaction of Dichlorocarbene with Secondary Alcohol Derivatives

2000 ◽  
Vol 29 (10) ◽  
pp. 1180-1181 ◽  
Author(s):  
Yukio Masaki ◽  
Hideki Arasaki ◽  
Motoo Shiro
Keyword(s):  
Secondary Alcohol ◽  
Building Blocks ◽  
Optically Active ◽  
Tertiary Alcohol ◽  
Insertion Reaction ◽  
Facile Synthesis

scholarly journals A facile synthesis of cysteine-based diketopiperazine from thiol-protected precursor

2018 ◽  
Vol 5 (6) ◽  
pp. 180272
Author(s):  
Di Zhang ◽  
Wayne Wang
Keyword(s):  
Amino Acid ◽  
Potential Application ◽  
Click Reaction ◽  
Building Blocks ◽  
Optically Active ◽  
Spectroscopic Methods ◽  
Synthetic Route ◽  
Facile Synthesis ◽  
Chiroptical Property ◽  
Potential Applications

l -Cysteine is one of the most promising biomass-based building blocks with great potential applications. Herein, we report a versatile synthetic route to produce cysteine-based 2,5-diketopiperazine (DKP) with good yield from the thiol-ene click reaction of l -cysteine and commercially available acrylates, followed by dimerization of the amino acid intermediates. The achieved DKP diastereomers were successfully separated and fully characterized by spectroscopic methods. Moreover, the chiroptical property of DKP in the presence of various metal ions was investigated by circular dichroism spectroscopy. The potential application of the optically active cysteine-based DKP as a chiral probe for detection of silver ion in water has been demonstrated.

The synthesis of optically active building blocks carrying an α, α-dihalogeno-β, β, β-trifluoroethyl group

1989 ◽  
Vol 42 (1) ◽  
pp. 17-29 ◽  
Author(s):  
Tomoya Kitazume ◽  
Takeshi Ohnogi ◽  
Jenq Tain Lin ◽  
Takashi Yamazaki ◽  
Keizo Ito
Keyword(s):  
Building Blocks ◽  
Optically Active

Optically Active Functionalized Building Blocks for Peptidyl Olefin Peptidomimetics

2021 ◽  
Vol 6 (31) ◽  
pp. 7912-7918
Author(s):  
Ekaterina Lerman ◽  
Shlomo Levinger ◽  
Amnon Albeck
Keyword(s):  
Building Blocks ◽  
Optically Active

scholarly journals A Facile Synthesis of α-N-Ribosyl-Asparagine and α-N-Ribosyl-Glutamine Building Blocks

Molecules ◽  
2013 ◽  
Vol 18 (8) ◽  
pp. 8779-8785 ◽  
Author(s):  
Gaetano Speciale ◽  
Anna Bernardi ◽  
Filippo Nisic
Keyword(s):  
Building Blocks ◽  
Facile Synthesis

Facile synthesis of optically active polyaniline and polytoluidine

Polymer ◽  
1996 ◽  
Vol 37 (2) ◽  
pp. 359-362 ◽  
Author(s):  
Mir Reza Majidi ◽  
Leon A.P. Kane-Maguire ◽  
Gordon G.G. Wallace
Keyword(s):  
Optically Active ◽  
Facile Synthesis
Sign in / Sign up

Export Citation Format

Share Document