Synthesis of (R)-(+)-Tanikolide through Stereospecific C–H Insertion Reaction of Dichlorocarbene with Optically Active Secondary Alcohol Derivatives

Hideki Arasaki; Masashi Iwata; Miyuki Makida; Yukio Masaki

doi:10.1248/cpb.52.848

Synthesis of (R)-(+)-Tanikolide through Stereospecific C–H Insertion Reaction of Dichlorocarbene with Optically Active Secondary Alcohol Derivatives

Chemical and Pharmaceutical Bulletin ◽

10.1248/cpb.52.848 ◽

2004 ◽

Vol 52 (7) ◽

pp. 848-852 ◽

Cited By ~ 26

Author(s):

Hideki Arasaki ◽

Masashi Iwata ◽

Miyuki Makida ◽

Yukio Masaki

Keyword(s):

Secondary Alcohol ◽

Optically Active ◽

Insertion Reaction

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Synthesis of (R)-(+)-Tanikolide Through Stereospecific C—H Insertion Reaction of Dichlorocarbene with Optically Active Secondary Alcohol Derivatives.

ChemInform ◽

10.1002/chin.200451184 ◽

2004 ◽

Vol 35 (51) ◽

Author(s):

Hideki Arasaki ◽

Masashi Iwata ◽

Miyuki Makida ◽

Yukio Masaki

Keyword(s):

Secondary Alcohol ◽

Optically Active ◽

Insertion Reaction

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ChemInform Abstract: Facile Synthesis of Optically Active Tertiary Alcohol Building Blocks by Stereospecific C-H Insertion Reaction of Dichlorocarbene with Secondary Alcohol Derivatives.

ChemInform ◽

10.1002/chin.200108088 ◽

2001 ◽

Vol 32 (8) ◽

pp. no-no

Author(s):

Yukio Masaki ◽

Hideki Arasaki ◽

Motoo Shiro

Keyword(s):

Secondary Alcohol ◽

Building Blocks ◽

Optically Active ◽

Tertiary Alcohol ◽

Insertion Reaction ◽

Facile Synthesis

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Facile Synthesis of Optically Active Tertiary Alcohol Building Blocks by Stereospecific C–H Insertion Reaction of Dichlorocarbene with Secondary Alcohol Derivatives

Chemistry Letters ◽

10.1246/cl.2000.1180 ◽

2000 ◽

Vol 29 (10) ◽

pp. 1180-1181 ◽

Cited By ~ 15

Author(s):

Yukio Masaki ◽

Hideki Arasaki ◽

Motoo Shiro

Keyword(s):

Secondary Alcohol ◽

Building Blocks ◽

Optically Active ◽

Tertiary Alcohol ◽

Insertion Reaction ◽

Facile Synthesis

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Chemo- and stereoselective dirhodium(II)-catalyzed C-H insertion reaction of 5,6-dioxygenated 2-diazo-3-oxohexanoates: Synthesis of an optically active highly functionalized cyclopentane

Tetrahedron ◽

10.1016/s0040-4020(99)00369-5 ◽

1999 ◽

Vol 55 (24) ◽

pp. 7461-7470 ◽

Cited By ~ 21

Author(s):

Takayuki Yakura ◽

Akiharu Ueki ◽

Tsuyoshi Kitamura ◽

Kenji Tanaka ◽

Masatake Nameki ◽

...

Keyword(s):

Optically Active ◽

Insertion Reaction

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A Raney nickel — sodium hypophosphite combination system for reductive desulfurization without racemization of optically active secondary alcohol

Tetrahedron ◽

10.1016/s0040-4020(97)00804-1 ◽

1997 ◽

Vol 53 (38) ◽

pp. 12883-12894 ◽

Cited By ~ 36

Author(s):

Manabu Node ◽

Kiyoharu Nishide ◽

Yukihiro Shigeta ◽

Kenichi Obata ◽

Hiroaki Shiraki ◽

...

Keyword(s):

Raney Nickel ◽

Secondary Alcohol ◽

Optically Active ◽

Sodium Hypophosphite ◽

Combination System ◽

Reductive Desulfurization

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Total synthesis of (−)-ephedradine A: an efficient construction of optically active dihydrobenzofuran-ring via C–H insertion reaction

Tetrahedron ◽

10.1016/j.tet.2004.06.144 ◽

2004 ◽

Vol 60 (43) ◽

pp. 9615-9628 ◽

Cited By ~ 58

Author(s):

Wataru Kurosawa ◽

Hideki Kobayashi ◽

Toshiyuki Kan ◽

Tohru Fukuyama

Keyword(s):

Total Synthesis ◽

Optically Active ◽

Insertion Reaction ◽

Efficient Construction

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ChemInform Abstract: A Raney Nickel-Sodium Hypophosphite Combination System for Reductive Desulfurization Without Racemization of Optically Active Secondary Alcohol.

ChemInform ◽

10.1002/chin.199803056 ◽

2010 ◽

Vol 29 (3) ◽

pp. no-no

Author(s):

M. NODE ◽

K. NISHIDE ◽

Y. SHIGETA ◽

K. OBATA ◽

H. SHIRAKI ◽

...

Keyword(s):

Raney Nickel ◽

Secondary Alcohol ◽

Optically Active ◽

Sodium Hypophosphite ◽

Combination System ◽

Reductive Desulfurization

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Asymmetric Carbene C–O Insertion Reaction Using Optically Active Bipyridine-Copper Complex as a Catalyst. Ring Expansion of Oxetanes to Tetrahydrofurans

Chemistry Letters ◽

10.1246/cl.1994.1857 ◽

1994 ◽

Vol 23 (10) ◽

pp. 1857-1860 ◽

Cited By ~ 48

Author(s):

Katsuji Ito ◽

Tsutomu Katsuki

Keyword(s):

Copper Complex ◽

Ring Expansion ◽

Optically Active ◽

Insertion Reaction

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ChemInform Abstract: Asymmetric Carbene C-O Insertion Reaction Using Optically Active Bipyridine-Copper Complex as a Catalyst. Ring Expansion of Oxetanes to Tetrahydrofurans.

ChemInform ◽

10.1002/chin.199517116 ◽

2010 ◽

Vol 26 (17) ◽

pp. no-no

Author(s):

K. ITO ◽

T. KATSUKI

Keyword(s):

Copper Complex ◽

Ring Expansion ◽

Optically Active ◽

Insertion Reaction

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Palladium-catalyzed intra-molecular olefin insertion reaction of α-alkenyl-α-acyloxytrialkylsilane. Synthesis of optically active carbocycle

Tetrahedron Letters ◽

10.1016/j.tetlet.2007.03.029 ◽

2007 ◽

Vol 48 (22) ◽

pp. 3925-3928 ◽

Cited By ~ 7

Author(s):

Kazuhiko Sakaguchi ◽

Takuya Okada ◽

Takeshi Yamada ◽

Yasufumi Ohfune

Keyword(s):

Optically Active ◽

Insertion Reaction ◽

Palladium Catalyzed

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