scholarly journals Characteristics of Organic Matter Pores and the Relationship with Current Pressure System of Lower Silurian Longmaxi Shales in Dingshan Field, Southern Sichuan, China

Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-15
Author(s):  
Qian Cao ◽  
Ke Jiang ◽  
Zhentao Wen ◽  
Xingzhi Wang ◽  
Minghui Qi ◽  
...  

Organic matter pores (OMP) provide significant storage space for hydrocarbons in lower Silurian Longmaxi shales in the Dingshan field of southern Sichuan, China. The distributions of organic matter and the different OMP structure parameters were characterized through Ar-ion polishing, scanning electron microscopy (SEM), and image analysis software for shale samples of different wells. The research results indicated that organic matter has been divided into two categories based on its occurrence, location, and its relationship with authigenic minerals: organic matter in situ and migrated organic matter. OMP for organic matter in situ are mainly micropores mostly arranged isolatedly, while in migrated organic matter pores show larger sizes and higher roundness. The development of OMP in samples is predominantly controlled by the formation pressure. The existence of overpressure alleviated the stress on the rock skeleton, causing the compaction of some migrated organic matters to lag or decrease. This played a positive role in protecting the development of pores in the interior and edge of the rock skeleton, and it can also induce the development of microfractures in shale. The protective effect of formation pressure on organic pores was provided for understanding the exploration and exploitation of Longmaxi shales in the study area.

1996 ◽  
Vol 44 (2) ◽  
pp. 103-110 ◽  
Author(s):  
J.W. Cone ◽  
A.H. Van Gelder ◽  
A.M. Van Vuuren

The amount of rumen fermentable organic matter (FOM) can be calculated using tables, taking into account the amount of digestible organic matter, the content of fat and fermentation products, and the amount of starch and protein escaping rumen fermentation, or FOM can be calculated using in situ incubations. An in vitro method is described to predict FOM using amylase and other carbohydrate degrading enzymes. FOM estimated by the enzymic method showed a moderate correlation (Rsuperscript 2 = 0.71) with FOM estimated by the in situ method. The relationship could be improved by separating the high crude fibre samples (Rsuperscript 2 = 0.88) from the other samples (Rsuperscript 2 = 0.77). Because degradation rates with the enzymic method were high compared with the assumed rumen passage rates, it proved that FOM could be predicted with a similar accuracy (Rsuperscript 2 = 0.76 - 0.80) by the undegraded fraction after 24 h.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
M. Shigemitsu ◽  
T. Yokokawa ◽  
H. Uchida ◽  
S. Kawagucci ◽  
A. Murata

AbstractMicrobial community structure in the hadal water is reported to be different from that in the upper abyssal water. However, the mechanism governing the difference has not been fully understood. In this study, we investigate the vertical distributions of humic-like fluorescent dissolved organic matter (FDOMH), chemoautotrophic production, apparent oxygen utilization (AOU), and N* in the Izu-Ogasawara Trench. In the upper abyssal waters (< 6000 m), FDOMH has a significantly positive correlation with AOU; FDOMH deviates from the relationship and increases with depth without involving the increment of AOU in the hadal waters. This suggests that FDOMH is transferred from the sediments to the hadal waters through pore water, while the FDOMH is produced in situ in the upper abyssal waters. Chemoautotrophic production and N* increases and decreases with depth in the hadal waters, respectively. This corroborates the effluxes of dissolved substances, including dissolved organic matter and electron donors from sediments, which fuels the heterotrophic/chemoautotrophic microbial communities in the hadal waters. A simple box model analysis reveals that the funnel-like trench topography facilitates the increase in dissolved substances with depth in the hadal waters, which might contribute to the unique microbiological community structure in these waters.


2011 ◽  
Vol 8 (5) ◽  
pp. 517 ◽  
Author(s):  
Jacqueline Levy ◽  
Hao Zhang ◽  
William Davison ◽  
Rene Groben

Environmental context Interaction of metals with dissolved organic matter is one of the key processes defining metal bioavailability in water. The technique of diffusive gradients in thin films was used to investigate the kinetics of the interaction between metals and dissolved organic matter released by algae. For most metals the rate at which they were released from the organic matter was fast, but release of iron was kinetically limited. AbstractThe interaction of metals with organic matter is one of the key processes determining metal speciation and bioavailability in water. Fulvic acid tends to dominate dissolved organic carbon (DOC) in freshwaters, but organic carbon produced in situ, e.g. exudates released by algae and bacteria, is also significant. The technique of diffusive gradients in thin films (DGT) was used to investigate the lability of metal–exudate complexes using a kinetic signature approach. Exudates were harvested from three cultured freshwater alga (Chlorella vulgaris, Cryptomonas pyrenoidifera, Anabaena flos-aquae) and the filtered media supplemented with trace metals. DGT-labile metal concentrations and kinetic signatures were determined (24-h deployment). The relationship between Fe and DOC was a defining feature of the kinetic signatures. Iron was the most kinetically limited metal followed by Al and Cu, whereas Co, Ni and Pb were effectively completely labile. Exudates from Chlorella vulgaris produced the most DOC and the most marked kinetic limitation.


2018 ◽  
Vol 156 (3) ◽  
pp. 443-449 ◽  
Author(s):  
G. V. Kozloski ◽  
E. M. C. Zilio ◽  
F. Ongarato ◽  
B. C. Kuinchtner ◽  
A. G. Saccol ◽  
...  

AbstractThe current study aimed to test whether organic matter intake by free-ranging ruminants could be estimated from the amount of nitrogen (N) excreted in faeces and to compare this approach to conventional techniques. An equation describing the relationship between excreted N and nutrient intake was developed in indoor digestibility trials conducted with male sheep (n= 36) and cattle (n= 24) housed in metabolism cages and solely fed hay harvested from a local rangeland. Faecal N excretion was linearly related to organic matter (OM) intake without a significant animal species effect. To evaluate the linear equation, data from free-ranging trials conducted with sheep and cattle were used. The faecal N approach was compared with eitherin situdigestibility plus external marker (n= 123) orn-alkanes (n= 272) to estimate OM intake and digestible OM intake. Estimates obtained through the faecal N approach did not closely fit those obtained with either conventional technique for any variable. Averaging all individual values, the supply of metabolizable energy (ME) estimated through faecal N was similar to the required level, whereas both thein situandn-alkanes techniques overestimated ME supply. In conclusion, OM intake by free-ranging sheep and cattle can be estimated based on the amount of N excreted in faeces with some advantages over conventional techniques: knowledge about herbage attributes is not required and it accounts for individual variability on selectivity and digestion processes.


2016 ◽  
Author(s):  
Urban Johannes Wünsch ◽  
Boris Peter Koch ◽  
Matthias Witt ◽  
Joseph Andrew Needoba

Abstract. The in situ detection of fluorescent dissolved organic matter (FDOM) at high temporal resolution is a powerful proxy to follow dissolved organic matter (DOM) dynamics and DOM flux to coastal oceans when FDOM measurements and dissolved organic carbon (DOC) are highly correlated. Here, we investigated the relationship between FDOM sensors and DOC concentration in the lower Columbia River, USA in spring and summer 2013. Furthermore, we studied the seasonal variability of FDOM and chromophoric DOM (CDOM) optical indices, as well as the seasonal and spatial variability for the molecular characteristics of DOM using ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS). The fieldwork was conducted concurrently with the operation of in situ sensor platforms that recorded physical and biogeochemical data at hourly intervals. In situ FDOM and DOC concentration was highly correlated and the relationship was used to quantify the river's DOC flux between March and August 2013. The average flux was 0.93 Gg d−1, which included over three-fold temporal variability (0.45 to 1.62 Gg d−1) associated with seasonal biogeochemical variability. Spectrofluorometry measurements demonstrated that FDOM parameters correlated with major seasonal biogeochemical shifts in the river associated with phytoplankton blooms and river discharge and thus revealed predictable seasonal patterns in DOM quality. FT-ICR-MS analyses elucidated these shifts on the molecular level: the relative abundance of 561 formulas, most of which contained N and S, correlated significantly with chlorophyll a, while 417 formulas (mostly CHO) correlated with CDOM absorbance at 254 nm.


Author(s):  
Ewa Szymczak ◽  
Dorota Galińska

AbstractThe aim of this study was to analyze the variability of the suspension concentration in the area where the Vistula River discharges into the Gulf of Gdańsk. While analyzing the relationship between suspension concentration and the distance from the river mouth and the spatial location in the water column, a number of other important factors were considered, i.e. salinity, temperature, the composition of suspension and in situ hydrodynamic conditions. The samples of surficial sediment were analyzed with regard to the content of organic matter and <0.063 mm size fraction.


Author(s):  
O.L. Krivanek ◽  
G.J. Wood

Electron microscopy at 0.2nm point-to-point resolution, 10-10 torr specimei region vacuum and facilities for in-situ specimen cleaning presents intere; ing possibilities for surface structure determination. Three methods for examining the surfaces are available: reflection (REM), transmission (TEM) and profile imaging. Profile imaging is particularly useful because it giv good resolution perpendicular as well as parallel to the surface, and can therefore be used to determine the relationship between the surface and the bulk structure.


Author(s):  
Kun Lee ◽  
Jingyi Si ◽  
Ricai Han ◽  
Wei Zhang ◽  
Bingbing Tan ◽  
...  

There are more supports for the view that human papillomavirus (HPV) infection might be an etiological factor in the development of cervical cancer when the association of persistent condylomata is considered. Biopsies from 318 cases with squamous cell carcinoma of uterine cervix, 48 with cervical and vulvar condylomata, 14 with cervical intraepithelial neoplasia (CIN), 34 with chronic cervicitis and 24 normal cervical epithelium were collected from 5 geographic regions of China with different cervical cancer mortalities. All specimens were prepared for Dot blot, Southern blot and in situ DNA-DNA hybridizations by using HPV-11, 16, 18 DNA labelled with 32P and 3H as probes to detect viral homologous sequences in samples. Among them, 32 cases with cervical cancer, 27 with condyloma and 10 normal cervical epitheliums were randomly chosen for comparative EM observation. The results showed that: 1), 192 out of 318 (60.4%) cases of cervical cancer were positive for HPV-16 DNA probe (Table I)


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