scholarly journals Effect of Calcium Carbonate Whisker and Fly Ash on Mechanical Properties of Cement Mortar under High Temperatures

2019 ◽  
Vol 2019 ◽  
pp. 1-13 ◽  
Author(s):  
Li Wang ◽  
Hongliang Zhang ◽  
Bendong Zhao ◽  
Yang Gao

Calcium carbonate (CaCO3) whisker, as a new type of microfibrous material, has been extensively used in the reinforcement of cementitious materials. However, the combined effect of CaCO3 whisker and fly ash on mechanical properties of cementitious materials under high temperatures was still unknown. In this study, the coupling effect of CaCO3 whisker, and fly ash on mechanical properties of the cement was investigated. Two sets of cement mortars were fabricated, including CaCO3 whisker-based mortar which contained 0 wt.%, 5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.% CaCO3 whisker as cement substitution and CaCO3 whisker-based fly ash mortar which contained 30 wt.% fly ash in addition to 0 wt.%, 5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.% CaCO3 whisker as cement substitution. Mass loss, compressive strength, and flexural strength of these two sets of specimens before and after being subjected to high temperatures of 200°C, 400°C, 600°C, 800°C, and 1000°C were measured. Based on the results of the aforementioned tests, load-deflection test was performed on the specimen which exhibited the superior performance to further study its mechanical behavior after exposure to high temperatures. Moreover, microstructural analysis, such as mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM), was conducted to reveal the damage mechanism of high temperature and to illustrate the combined effect of CaCO3 whisker and fly ash on high-temperature resistance of the cement. Results showed that fly ash could improve the high-temperature performance of CaCO3 whisker-based mortar before 600°C and limit the loss of strength after 600°C.

Materials ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 1833 ◽  
Author(s):  
Dong Lu ◽  
Zhuo Tang ◽  
Liang Zhang ◽  
Jianwei Zhou ◽  
Yue Gong ◽  
...  

Concrete has low porosity and compact microstructure, and thus can be vulnerable to high temperature, and the increasing application of various types of supplementary cementitious materials (SCMs) in concrete makes its high-temperature resistant behavior more complex. In this study, we investigate the effects of four formulations with typical SCMs combinations of fly ash (FA), ultra-fine fly ash (UFFA) and metakaolin (MK), and study the effects of SCMs combinations on the thermal performance, microstructure, and the crystalline and amorphous phases evolution of concrete subjected to high temperatures. The experimental results showed that at 400 °C, with the addition of 20% FA (wt %), the thermal conductivity of the sample slightly increased to 1.5 W/(m·K). Replacing FA with UFFA can further increase the thermal conductivity to 1.7 W/(m·K). Thermal conductivity of concrete slightly increased at 400 °C and significantly reduced at 800 °C. Further, combined usage of SCMs delayed and reduced micro-cracks of concrete subjected to high temperatures. This study demonstrates the potential of combining the usage of SCMs to promote the high-temperature performance of concrete and explains the micro-mechanism of concrete containing SCMs at high temperatures.


Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4387
Author(s):  
Wei Zhou ◽  
Wenxiang Tian ◽  
Tianqi Qi ◽  
Shuhua Liu ◽  
Chuqiao Feng ◽  
...  

The composited cementitious materials usually have superior performance; for example, using limestone powder (LP) and fly ash (FA) as the admixtures of cement in concrete/mortar is a popular way of improving the properties of concrete/mortar structures. In this work, we performed experimental tests to study the hydration process and pore distribution in mortar containing different ratios of LP and FA. Based on the results of mercury intrusion porosimetry (MIP), a numerical mortar model with random pore is built. The model can reflect the synergistic hydration interaction and filling effect caused by the admixtures of LP and FA. After analyzing the hydration process, the coupled chemical–thermal–mechanical method was used to simulate the characteristics of mortar containing LP and FA. The coupling model can simulate the “hump-type” hydration acceleration stage of the mortar at early age, which is specifically caused by the LP, proved in the experimental test. Additionally, the special, “hump-type” stage is important to enhance the early strength of the mortar. At different levels of admixture content, the random pore model and coupled method can predict the evolution process of the mechanical properties well, at early age and for long-term strength. Both experimental and numerical results suggest that the mortar containing admixtures of the proper ratio of LP to FA have good mechanical properties, which can be applied to engineering structures.


2021 ◽  
Vol 20 (2) ◽  
pp. 393-406
Author(s):  
Mehmet Kaya ◽  
◽  
Fuat Köksal ◽  

In this study, a geopolymer composite containing PVA fiber was produced to recycle waste fly ash and obtain an eco-friendly binder. Mechanical properties of geopolymer mortars, produced by using F class fly ash which was activated with NaOH (sodium hydroxide), and reinforced by PVA (polyvinyl alcohol) fiber were investigated after high temperature effect. Geopolymer mortar samples produced by mixing with fly ash, sand, water and NaOH were placed in standard molds of 40×40×160 mm3. PVA fibers were used at percentages of 0,5%, 1% and 1,5% by volume in the experiment. Tests were performed on mortars exposed to high temperatures of 200°C, 400°C, 600°C and 800°C for physical and mechanical properties. For the specimens not subjected to high temperatures, an increase in the compressive strength of mortars containing PVA fibers was observed in comparison to mortar without PVA fiber. On the other hand, it was concluded that losses in compressive strength were less for mortar without PVA fiber when compared with the mortars containing PVA fibers. As a result of the modeling, the PVA ratio, which gives the optimum flexural and compressive strength, was determined as 1,47%. As a result of melting of PVA fibers under the effect of high temperature, 83,58% loss of compressive strength was determined in samples containing 1,5% PVA after 800ºC temperature.


2012 ◽  
Vol 532-533 ◽  
pp. 234-237
Author(s):  
Wei Lai Chen ◽  
Ding Hong Yi ◽  
Jian Fu Zhang

The purpose of this paper is to study the effect of high temperature in injection molding process on mechanical properties of the warp-knitted and nonwoven composite fabrics (WNC)used in car interior. Tensile, tearing and peeling properties of WNC fabrics were tested after heat treatment under120, 140,160,180°C respectively. It was found that, after 140°C heat treatment, the breaking and tearing value of these WNC fabrics are lower than others. The results of this study show that this phenomenon is due to the material properties of fabrics. These high temperatures have no much effect on peeling properties of these WNC fabrics. It is concluded that in order to preserve the mechanical properties of these WNC fabrics, the temperature near 140°C should be avoided possibly during injection molding process.


2014 ◽  
Vol 1014 ◽  
pp. 49-52
Author(s):  
Xiao Ping Su

With the wide application of high strength concrete in the building construction,the risk making concrete subject to high temperatures during a fire is increasing. Comparison tests on the mechanical properties of high strength concrete (HSC) and normal strength concrete (NSC) after the action of high temperature were made in this article, which were compared from the following aspects: the peak stress, the peak strain, elasticity modulus, and stress-strain curve after high temperature. Results show that the laws of the mechanical properties of HSC and NSC changing with the temperature are the same. With the increase of heating temperature, the peak stress and elasticity modulus decreases, while the peak strain grows rapidly. HSC shows greater brittleness and worse fire-resistant performance than NSC, and destroys suddenly. The research and evaluation on the fire-resistant performance of HSC should be strengthened during the structural design and construction on the HSC buildings.


2013 ◽  
Vol 275-277 ◽  
pp. 2107-2111
Author(s):  
Qiu Lin Zou ◽  
Jun Li ◽  
Zhen Yu Lai

Barite concrete with density grade of 3 and strength grade of C30 was prepared by mixing with different fineness of fly ash. The workability, mechanical properties and long-term high temperature performance of the prepared barite concrete were researched. Results show that the workability of barite concrete is improved by mixing with fly ash, and no segregation of mixture has been observed. The apparent density and 3d, 28d compressive strength of barite concrete are decreased obviously after mixing with fly ash. But with the increasing of the fineness of fly ash, the apparent density and 3d, 28d compressive strength of barite concrete have a slight increase. High temperature residual compressive strength is decreased with the increasing of temperature. The cycle times of heat treatment at 400°C only has a little effect on residual compressive strength of barite concrete.


2019 ◽  
Vol 12 (1) ◽  
pp. 31-38 ◽  
Author(s):  
N. SCHWANTES-CEZARIO ◽  
M. F. PORTO ◽  
G. F. B. SANDOVAL ◽  
G. F. N. NOGUEIRA ◽  
A. F. COUTO ◽  
...  

Abstract This study aims to evaluate the influence of B. subtilis AP91 spores addition on the mechanical properties of mortars. B. subtilis strain AP91, isolated from rice leaves of the needle variety, which has an early cycle of production, was used at the concentration of 105 spores/mL in mortars with cement-to-sand ratio of 1:3 (by weight) and water-to-cement ratio (w/c) of 0.63. These spores were added in two different ways: in the mixing water and by immersion in a solution containing bacterial spores. Scanning Electron Microscope (SEM) analysis showed crystals with calcium peaks on the EDS, which possibly indicates the presence of bioprecipitated calcium carbonate. The results obtained in the mechanical analysis showed that the bioprecipitation of CaCO3 by B. subtilis strain AP91 was satisfactory, particularly when the spores were added in the mixing water, increasing the compressive strength up to 31%. Thus, it was concluded that the addition of B. subtilis AP91 spores in the mixing water of cement mortars induced biocementation, which increased the compressive strength. This bioprecipitation of calcium carbonate may very well have other advantageous consequences, such as the closure of pores and cracks in cementitious materials that could improve durability properties, although more research is still needed on this matter.


2020 ◽  
Vol 5 (2) ◽  
pp. 14
Author(s):  
Matthew S. Sullivan ◽  
Mi G. Chorzepa ◽  
Stephan A. Durham

Ternary blends of cementitious materials are investigated. A cement replacement level of 45% is used for all ternary mixtures consisting of 15% metakaolin and 30% slag replacements. Three metakaolin and two blast furnace slag, referred to as ‘slag’ for short, products commercially available are used to compare performance in ternary blends. A mixture with a 45% fly ash replacement is included to serve as a benchmark for performance. The control mixture contains 422 kg of cement per cubic meter of concrete, and a water-to-cementitious material ratio of 0.43 is used for all mixtures with varying dosages of superplasticizer to retain workability. Mixtures are tested for mechanical properties, durability, and volumetric stability. Mechanical properties include compression, split-cylinder tension, modulus of rupture, and dynamic Young’s modulus. Durability measures are comprised of rapid chloride-ion penetrability, sulfate resistance, and alkali–silica reactivity. Finally, the measure of dimensional stability is assessed by conducting drying shrinkage and coefficient of thermal expansion tests. Results indicate that ternary mixtures including metakaolin perform similarly to the control with respect to mechanical strength. It is concluded that ternary blends perform significantly better than both control and fly ash benchmark in tests measuring durability. Furthermore, shrinkage is reduced while the coefficients of thermal expansion are slightly higher than control and the benchmark.


2019 ◽  
Vol 292 ◽  
pp. 102-107 ◽  
Author(s):  
Josef Fládr ◽  
Petr Bílý ◽  
Karel Šeps ◽  
Roman Chylík ◽  
Vladimír Hrbek

High-performance concrete is a very specific type of concrete. Its production is sensitive to both the quality of compounds used and the order of addition of particular compounds during the homogenization process. The mechanical properties were observed for four dosing procedures of each of the three tested concrete mixtures. The four dosing procedures were identical for the three mixes. The three mixes varied only in the type of supplementary cementitious material used and in water content. The water content difference was caused by variable k-value of particular additives. The water-to-binder ratio was kept constant for all the concretes. The additives used were metakaolin, fly ash and microsilica. The comparison of particular dosing procedures was carried out on the values of basic mechanical properties of concrete. The paper compares compressive strength and depth of penetration of water under pressure. Besides the comparsion of macro-mechanical properties, the effect of microsilica and fly ash additives on micro-mechanical properties was observed with the use of scanning electron microscopy (SEM) and nanoindentation data analysis. Nanoindentation was used to determine the thickness and strength of interfacial transition zone (ITZ) for different sequence of addition of cement, additive and aggregate. The thickness obtained by nanoindentation was further investigated by SEM EDS line scanning.


2020 ◽  
Vol 12 (20) ◽  
pp. 8612 ◽  
Author(s):  
Edoardo Bocci ◽  
Emiliano Prosperi ◽  
Volkmar Mair ◽  
Maurizio Bocci

In road construction, it can happen that, for different reasons, the time between hot-mix asphalt (HMA) production and paving is extended to some hours. This can be reflected in several problems such as mix cooling and temperature segregation, but also in an extremely severe bitumen ageing due to its prolonged exposure to high temperatures. This paper deals with the investigation of these phenomena both in the laboratory and on site. In particular, the first part of the research aimed at observing the influence of the conditioning time, when the loose HMA is kept in the oven at a high temperature, on the mix properties. The second part focused on the ageing/cooling that happens on site during HMA hauling, as a function of time and type of truck. Temperatures were monitored using a thermal camera and different probes, and gyratory compactor specimens were produced by sampling some HMA from the trucks every 1 h for 3 h. The results showed that HMA stiffness rises if the time when the loose mix stays in the laboratory oven before compaction increases. However, on site, the HMA volumetric and mechanical properties do not change with hauling time up to 3 h, probably because the external material in the truck bed protects the HMA core from the access of oxygen, hindering bitumen oxidation and loss of volatiles. The temperature monitoring highlighted that temperature segregation, after 3 h hauling, can be higher than 30 °C but it can be reduced using insulated truck beds.


Sign in / Sign up

Export Citation Format

Share Document