scholarly journals Investigation on Hydration and Mechanical Properties of Mortar Containing Limestone Powder and Fly Ash Based on the Coupled Chemical–Thermal–Mechanical Method

Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4387
Author(s):  
Wei Zhou ◽  
Wenxiang Tian ◽  
Tianqi Qi ◽  
Shuhua Liu ◽  
Chuqiao Feng ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Fly Ash ◽  
Experimental Tests ◽  
Cementitious Materials ◽  
Hydration Process ◽  
Limestone Powder ◽  
Superior Performance ◽  
Early Age ◽  
Mechanical Method ◽  
Engineering Structures

The composited cementitious materials usually have superior performance; for example, using limestone powder (LP) and fly ash (FA) as the admixtures of cement in concrete/mortar is a popular way of improving the properties of concrete/mortar structures. In this work, we performed experimental tests to study the hydration process and pore distribution in mortar containing different ratios of LP and FA. Based on the results of mercury intrusion porosimetry (MIP), a numerical mortar model with random pore is built. The model can reflect the synergistic hydration interaction and filling effect caused by the admixtures of LP and FA. After analyzing the hydration process, the coupled chemical–thermal–mechanical method was used to simulate the characteristics of mortar containing LP and FA. The coupling model can simulate the “hump-type” hydration acceleration stage of the mortar at early age, which is specifically caused by the LP, proved in the experimental test. Additionally, the special, “hump-type” stage is important to enhance the early strength of the mortar. At different levels of admixture content, the random pore model and coupled method can predict the evolution process of the mechanical properties well, at early age and for long-term strength. Both experimental and numerical results suggest that the mortar containing admixtures of the proper ratio of LP to FA have good mechanical properties, which can be applied to engineering structures.

scholarly journals Effect of Calcium Carbonate Whisker and Fly Ash on Mechanical Properties of Cement Mortar under High Temperatures

2019 ◽  
Vol 2019 ◽  
pp. 1-13 ◽  
Author(s):  
Li Wang ◽  
Hongliang Zhang ◽  
Bendong Zhao ◽  
Yang Gao
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Fly Ash ◽  
Calcium Carbonate ◽  
High Temperatures ◽  
Coupling Effect ◽  
Microstructural Analysis ◽  
Cementitious Materials ◽  
Combined Effect ◽  
Superior Performance

Calcium carbonate (CaCO3) whisker, as a new type of microfibrous material, has been extensively used in the reinforcement of cementitious materials. However, the combined effect of CaCO3 whisker and fly ash on mechanical properties of cementitious materials under high temperatures was still unknown. In this study, the coupling effect of CaCO3 whisker, and fly ash on mechanical properties of the cement was investigated. Two sets of cement mortars were fabricated, including CaCO3 whisker-based mortar which contained 0 wt.%, 5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.% CaCO3 whisker as cement substitution and CaCO3 whisker-based fly ash mortar which contained 30 wt.% fly ash in addition to 0 wt.%, 5 wt.%, 10 wt.%, 15 wt.%, and 20 wt.% CaCO3 whisker as cement substitution. Mass loss, compressive strength, and flexural strength of these two sets of specimens before and after being subjected to high temperatures of 200°C, 400°C, 600°C, 800°C, and 1000°C were measured. Based on the results of the aforementioned tests, load-deflection test was performed on the specimen which exhibited the superior performance to further study its mechanical behavior after exposure to high temperatures. Moreover, microstructural analysis, such as mercury intrusion porosimetry (MIP) and scanning electron microscopy (SEM), was conducted to reveal the damage mechanism of high temperature and to illustrate the combined effect of CaCO3 whisker and fly ash on high-temperature resistance of the cement. Results showed that fly ash could improve the high-temperature performance of CaCO3 whisker-based mortar before 600°C and limit the loss of strength after 600°C.

scholarly journals Effects of Nano-CaCO3/Limestone Composite Particles on the Hydration Products and Pore Structure of Cementitious Materials

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Huashan Yang ◽  
Yujun Che
Keyword(s):  
Mechanical Properties ◽  
Pore Structure ◽  
Reaction System ◽  
Cementitious Materials ◽  
Limestone Powder ◽  
Composite Particles ◽  
Gravimetric Analysis ◽  
Hydration Products ◽  
Scanning Calorimetry ◽  
Necked Flask

The agglomeration of nano-CaCO3 (NC) is the largest bottleneck in applications in cementitious materials. If nano-CaCO3 modifies the surface of micron-scale limestone powder (LS), then it will form nano-CaCO3/limestone composite particles (NC/LS). It is known that micron-scale limestone is easily dispersed, and the “dispersion” of NC is governed by that of LS. Therefore, the dispersion of nano-CaCO3 can be improved by the NC/LS in cementitious materials. In this work, the preparation of NC/LS was carried out in a three-necked flask using the Ca(OH)2-H2O-CO2 reaction system. The morphology of NC/LS was observed by a field emission scanning electron microscope (FE-SEM). The effects of NC/LS on the hydration products and pore structure of cementitious materials are proposed. 5% NC/LS was added into cement paste and mortar, and the mechanical properties of the specimens were measured at a certain age. Differential scanning calorimetry (DSC), thermal gravimetric analysis (TG), and backscattered electron imaging (BSE) were conducted on the specimens to investigate the hydration products and pore structure. The properties of specimens with NC/LS were compared to that of control specimens (without NC/LS). The results revealed that NC/LS reduced the porosity and improved the mechanical properties of the cementitious materials.

scholarly journals Effect of nano-SnO2 on early-age hydration of Portland cement paste

2019 ◽  
Vol 11 (6) ◽  
pp. 168781401985194 ◽  
Author(s):  
Jianping Zhu ◽  
Genshen Li ◽  
Ruijie Xia ◽  
Huanhuan Hou ◽  
Haibin Yin ◽  
...  
Keyword(s):  
Portland Cement ◽  
Cement Paste ◽  
Cement Hydration ◽  
Cementitious Materials ◽  
Hydration Process ◽  
Strength Development ◽  
Early Age ◽  
Test Machine ◽  
Portland Cement Paste ◽  
Scanning Electron

Nanomaterial, as a new emerging material in the field of civil engineering, has been widely utilized to enhance the mechanical properties of cementitious material. Nano-SnO2 has presented high hardness characteristics, but there is little study of the application of nano-SnO2 in the cementitious materials. This study mainly investigated the hydration characteristics and strength development of Portland cement paste incorporating nano-SnO2 powders with 0%, 0.08%, and 0.20% dosage. It was found that the early-age compressive strength of cement paste could be greatly improved when nano-SnO2 was incorporated with 0.08% dosage. The hydration process and microstructure were then measured by hydraulic test machine, calorimeter, nanoindentation, X-ray diffraction, scanning electron microscope, and mercury intrusion porosimetry. It was found that the cement hydration process was promoted by the addition of nano-SnO2, and the total amount of heat released from cement hydration is also increased. In addition, the addition of nano-SnO2 can promote the generations of high density C-S-H and reduce the generations of low density C-S-H indicating the nucleation effect of nano-SnO2 in the crystal growth process. The porosity and probable pore diameter of cement paste with 0.08% nano-SnO2 were decreased, and the scanning electron microscopic results also show that the cement paste with 0.08% nano-SnO2 promotes the densification of cement microstructure, which are consistent with the strength performance.

scholarly journals Characterizing the Performance of Ternary Concrete Mixtures Involving Slag and Metakaolin

2020 ◽  
Vol 5 (2) ◽  
pp. 14
Author(s):  
Matthew S. Sullivan ◽  
Mi G. Chorzepa ◽  
Stephan A. Durham
Keyword(s):  
Mechanical Properties ◽  
Thermal Expansion ◽  
Fly Ash ◽  
Coefficient Of Thermal Expansion ◽  
Drying Shrinkage ◽  
Chloride Ion ◽  
Cementitious Materials ◽  
Ternary Mixtures ◽  
Modulus Of Rupture ◽  
Ternary Blends

Ternary blends of cementitious materials are investigated. A cement replacement level of 45% is used for all ternary mixtures consisting of 15% metakaolin and 30% slag replacements. Three metakaolin and two blast furnace slag, referred to as ‘slag’ for short, products commercially available are used to compare performance in ternary blends. A mixture with a 45% fly ash replacement is included to serve as a benchmark for performance. The control mixture contains 422 kg of cement per cubic meter of concrete, and a water-to-cementitious material ratio of 0.43 is used for all mixtures with varying dosages of superplasticizer to retain workability. Mixtures are tested for mechanical properties, durability, and volumetric stability. Mechanical properties include compression, split-cylinder tension, modulus of rupture, and dynamic Young’s modulus. Durability measures are comprised of rapid chloride-ion penetrability, sulfate resistance, and alkali–silica reactivity. Finally, the measure of dimensional stability is assessed by conducting drying shrinkage and coefficient of thermal expansion tests. Results indicate that ternary mixtures including metakaolin perform similarly to the control with respect to mechanical strength. It is concluded that ternary blends perform significantly better than both control and fly ash benchmark in tests measuring durability. Furthermore, shrinkage is reduced while the coefficients of thermal expansion are slightly higher than control and the benchmark.

The Effect of Homogenization Procedure on Mechanical Properties of High-Performance Concrete with Partial Replacement of Cement by Supplementary Cementitious Materials

2019 ◽  
Vol 292 ◽  
pp. 102-107 ◽  
Author(s):  
Josef Fládr ◽  
Petr Bílý ◽  
Karel Šeps ◽  
Roman Chylík ◽  
Vladimír Hrbek
Keyword(s):  
Mechanical Properties ◽  
Fly Ash ◽  
Water Content ◽  
High Performance ◽  
High Performance Concrete ◽  
Cementitious Materials ◽  
Supplementary Cementitious Materials ◽  
Partial Replacement ◽  
Depth Of Penetration ◽  
Cement Additive

High-performance concrete is a very specific type of concrete. Its production is sensitive to both the quality of compounds used and the order of addition of particular compounds during the homogenization process. The mechanical properties were observed for four dosing procedures of each of the three tested concrete mixtures. The four dosing procedures were identical for the three mixes. The three mixes varied only in the type of supplementary cementitious material used and in water content. The water content difference was caused by variable k-value of particular additives. The water-to-binder ratio was kept constant for all the concretes. The additives used were metakaolin, fly ash and microsilica. The comparison of particular dosing procedures was carried out on the values of basic mechanical properties of concrete. The paper compares compressive strength and depth of penetration of water under pressure. Besides the comparsion of macro-mechanical properties, the effect of microsilica and fly ash additives on micro-mechanical properties was observed with the use of scanning electron microscopy (SEM) and nanoindentation data analysis. Nanoindentation was used to determine the thickness and strength of interfacial transition zone (ITZ) for different sequence of addition of cement, additive and aggregate. The thickness obtained by nanoindentation was further investigated by SEM EDS line scanning.

scholarly journals Characterization of Titanium Nanotube Reinforced Cementitious Composites: Mechanical Properties, Microstructure, and Hydration

Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1617 ◽  
Author(s):  
Hyeonseok Jee ◽  
Jaeyeon Park ◽  
Erfan Zalnezhad ◽  
Keunhong Jeong ◽  
Seung Min Woo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Cement Paste ◽  
Cementitious Materials ◽  
Cement Clinker ◽  
Early Age ◽  
Potential Candidate ◽  
Hydration Kinetics ◽  
Cement Pastes ◽  
Viable Solution ◽  
First Time

In recent years, nano-reinforcing technologies for cementitious materials have attracted considerable interest as a viable solution for compensating the poor cracking resistance of these materials. In this study, for the first time, titanium nanotubes (TNTs) were incorporated in cement pastes and their effect on the mechanical properties, microstructure, and early-age hydration kinetics was investigated. Experimental results showed that both compressive (~12%) and flexural strength (~23%) were enhanced with the addition of 0.5 wt.% of TNTs relative to plain cement paste at 28 days of curing. Moreover, it was found that, while TNTs accelerated the hydration kinetics of the pure cement clinker phase (C3S) in the early age of the reaction (within 24 h), there was no significant effect from adding TNTs on the hydration of ordinary Portland cement. TNTs appeared to compress the microstructure by filling the cement paste pore of sizes ranging from 10 to 100 nm. Furthermore, it could be clearly observed that the TNTs bridged the microcracks of cement paste. These results suggested that TNTs could be a great potential candidate since nano-reinforcing agents complement the shortcomings of cementitious materials.

Research on Mechanical Properties of C100 High-Strength Concrete Used for Frozen Shaft

2012 ◽  
Vol 598 ◽  
pp. 388-392
Author(s):  
Hong Qiang Chu ◽  
Lin Hua Jiang ◽  
Ning Xu ◽  
Chuan Sheng Xiong
Keyword(s):  
Mechanical Properties ◽  
Elastic Modulus ◽  
Fly Ash ◽  
High Strength Concrete ◽  
High Strength ◽  
Cementitious Materials ◽  
Poisson's Ratio ◽  
Strength Concrete ◽  
Tensile Elastic Modulus ◽  
Early Strength

The mechanical properties of C100 high-strength concrete used for frozen shaft were studied in this research. The results demonstrate that: The cementitious materials 570kg/m3 concrete 28 strength is only 104.5MPa, which is lower than the C100 requirements; the early strength (3d) of the concrete doped with 30% admixture is less than 20% admixture concrete, but with the age increase, its strength gradually reaches close to concrete doped with 20% admixture, and eventually exceeds the concrete doped with 20% admixture.The tension-compression of high strength concrete doped with 15% fly ash and 15% slag is the smallest, while the tension-compression of the concrete doped 10% fly ash and 10% slag reaches the maximum.The Poisson's ratio of C100 concrete is between 0.20 and 0.24; the compressive elastic modulus is about 50GPa; and the tensile elastic modulus is about 110GPa.

Effect of Fly Ash and Activator on Performance of Steam-Cured Concrete

2010 ◽  
Vol 113-116 ◽  
pp. 1013-1016 ◽  
Author(s):  
Zhi Min He ◽  
You Jun Xie ◽  
Guang Cheng Long ◽  
Jun Zhe Liu
Keyword(s):  
Mechanical Properties ◽  
Tensile Strength ◽  
Compressive Strength ◽  
Fly Ash ◽  
Precast Concrete ◽  
Early Age ◽  
Flexure Strength ◽  
Concrete Elements ◽  
Chemical Activator

In precast concrete elements manufacturing, steam-cured concrete incorporating 30% fly ash encountered the problem of a too low demoulding compressive strength. To resolve it, this paper developed a new steam-cured concrete (AFSC) incorporating fly ash and a chemical activator. Experiments were conducted to investigate the mechanical properties of AFSC. The corresponding mechanism was also discussed by testing the microstructure of concrete. Results indicate that the demoulding compressive strength of AFSC can meet production requirements, and compressive and flexure strength of AFSC at later ages increase well. Compared with that of ordinary steam-cured concrete, AFSC has a higher tensile strength, and the capability of AFSC to resist cracks is enhanced remarkably. At an early age, addition of the chemical activator can distinctly accelerate the extent of hydration of the fly ash cement systems, and thus the microstructure of concrete becomes denser.

Enhanced mechanical properties of wood ash and fly ash as supplementary cementitious materials

2017 ◽  
Vol 116 (7) ◽  
pp. 355-361 ◽  
Author(s):  
Zaib Hussain ◽  
Rohama Maqsood ◽  
Muhammad Imran Din ◽  
Shahzad Maqsood Khan ◽  
Akhtar Shahnaz ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Fly Ash ◽  
Cementitious Materials ◽  
Wood Ash ◽  
Supplementary Cementitious Materials
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