scholarly journals Influence of Degree of Dispersion of Noncovalent Functionalized Graphene Nanoplatelets on Rheological Behaviour of Aqueous Drilling Fluids

2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
Arif Ibrahim ◽  
Syahrir Ridha ◽  
Asna Amer ◽  
Radzi Shahari ◽  
Tarek Ganat

Application of carbon nanomaterials in oil well drilling fluid has been previously studied and was found to enhance its filtration properties. There is a general consensus that addition of colloids in suspension will alter its rheology, i.e., carbon nanomaterials, in this research work; graphene nanoplatelets are hydrophobic materials, which require functionalisation to improve its dispersion in aqueous solution. However, different degrees of dispersion may vary the rheological properties behaviour of drilling fluid. The objective of this study was to characterize the colloidal dispersion of graphene nanoplatelets (GNP) in aqueous solution and its impact on the rheological properties behaviour of water-based drilling fluid. Dispersion of graphene nanoplatelets was achieved through noncovalent functionalisation by means of surfactant attachment. UV-visible spectroscopy was employed to analyze the dispersion of GNP in aqueous solution. The rheological test was carried out using a simple direct-indicating viscometer at six different speeds. Results revealed that the degree of dispersion of GNP using Triton X-100 was generally higher than both SDS and DTAB. Comparison between the rheological properties behaviour of drilling fluid with GNP dispersed using different surfactants shows little to no difference at low shear rates. At high shear rates, however, greater dispersion of GNP shows higher thinning properties while fluid with a low dispersion of GNP exhibited linear behaviour to thickening properties.

2021 ◽  
Author(s):  
Emmanuel Ayodele ◽  
David Ekuma ◽  
Ikechukwu Okafor ◽  
Innocent Nweze

Abstract Drilling fluid are complex fluids consisting of several additives. These additives are added to enhance and control the rheological properties (such as viscosity, gel strength and yield point) of the mud. These properties are controlled for effective drilling of a well. This research work is focused on determining the rheological behavior of drilling mud using industry-based polymer and Irvingia Gabonensis (ogbono) as viscosifiers. Water based muds were formulated from the aforementioned locally sourced viscosifier and that of the conventional used viscosifier (Carboxylmetyl cellulose, CMC). Laboratory tests were carried out on the different muds formulated and their rheological properties (such as yield stress, shear stress, plastic viscosity and shear rate) are evaluated. The concentration of the viscosifiers were varied. The expected outcome of the research work aims at lowering the total drilling cost by reducing the importation of foreign polymer which promotes the development of local content in the oil and gas industry. The research compares the rheology of mud samples and the effect of varying the concentration (2g, 4g, 6g, 8g, and 10g) of both CMC and Ogbono and determining the changes in their rheological properties. The total volume of each mud sample is equivalent to 350ml which represent one barrel (42gal) in the lab. From the result, at concentration of 2g, the ogbono mud has a better rheology than the CMC mud, but at a concentration above 2g, CMC mud shows a better rheology than ogbono mud, that is, as the concentration of CMC is increased, the rheological properties of the mud increased while as the concentration of ogbono is increased the rheological properties decreased. The viscosity of the drilling fluid produced from the ogbono were lower than that of CMC, it could be used together with another local product such as cassava starch, offor or to further improve the rheology and then be a substitute to the conventional viscosifiers.


Author(s):  
Eric Cayeux ◽  
Amare Leulseged

Drilling fluids are visco-elastic materials, i.e. they behave as a viscous fluid when subject to a sufficient shear stress and like an elastic solid otherwise. Both their elastic and viscous properties are time-dependent, i.e. drilling fluids are thixotropic. Because of thixotropy, it takes a finite time before the effective viscosity of a drilling fluid attains an equilibrium when the fluid is subject to a change of shear rate. This effect is visible when one changes the applied shear rate in a rheometer, as the fluid will gradually adapt to the new shearing conditions. When the velocity of a drilling fluid changes, for instance due to a change in pump flow rate, movement of the drill string, or change of flow geometry, the fluid will exhibit a time-dependent response to the new shearing conditions, requiring a certain time to reach the new equilibrium condition. Unfortunately, the time-dependence of the rheological properties of drilling fluids are usually not measured during drilling operations and therefore it is difficult to estimate how thixotropy impacts pressure losses in drilling operations. For that reason, we have systematically measured the time-dependence of the rheological properties of several samples of water-based, oil-based and micronized drilling fluids with a scientific rheometer in order to capture how drilling fluids systems respond to variations of shear rates. Based on these measurements, we propose to investigate how one existing thixotropic model manages to predict the shear stress as a function of the shear rate while accounting for the shear history and gelling conditions. Then we propose a modified model that fits better, overall, with the measurements even though there are still noticeable discrepancies, especially when switching back to low shear rates.


2014 ◽  
Vol 136 (3) ◽  
Author(s):  
Arild Saasen

Controlling the annular frictional pressure losses is important in order to drill safely with overpressure without fracturing the formation. To predict these pressure losses, however, is not straightforward. First of all, the pressure losses depend on the annulus eccentricity. Moving the drillstring to the wall generates a wider flow channel in part of the annulus which reduces the frictional pressure losses significantly. The drillstring motion itself also affects the pressure loss significantly. The drillstring rotation, even for fairly small rotation rates, creates unstable flow and sometimes turbulence in the annulus even without axial flow. Transversal motion of the drillstring creates vortices that destabilize the flow. Consequently, the annular frictional pressure loss is increased even though the drilling fluid becomes thinner because of added shear rate. Naturally, the rheological properties of the drilling fluid play an important role. These rheological properties include more properties than the viscosity as measured by API procedures. It is impossible to use the same frictional pressure loss model for water based and oil based drilling fluids even if their viscosity profile is equal because of the different ways these fluids build viscosity. Water based drilling fluids are normally constructed as a polymer solution while the oil based are combinations of emulsions and dispersions. Furthermore, within both water based and oil based drilling fluids there are functional differences. These differences may be sufficiently large to require different models for two water based drilling fluids built with different types of polymers. In addition to these phenomena washouts and tool joints will create localised pressure losses. These localised pressure losses will again be coupled with the rheological properties of the drilling fluids. In this paper, all the above mentioned phenomena and their consequences for annular pressure losses will be discussed in detail. North Sea field data is used as an example. It is not straightforward to build general annular pressure loss models. This argument is based on flow stability analysis and the consequences of using drilling fluids with different rheological properties. These different rheological properties include shear dependent viscosity, elongational viscosity and other viscoelastic properties.


2021 ◽  
Author(s):  
Mehrdad Gharib Shirangi ◽  
Roger Aragall ◽  
Reza Ettehadi ◽  
Roland May ◽  
Edward Furlong ◽  
...  

Abstract In this work, we present our advances to develop and apply digital twins for drilling fluids and associated wellbore phenomena during drilling operations. A drilling fluid digital twin is a series of interconnected models that incorporate the learning from the past historical data in a wide range of operational settings to determine the fluids properties in realtime operations. From several drilling fluid functionalities and operational parameters, we describe advancements to improve hole cleaning predictions and high-pressure high-temperature (HPHT) rheological properties monitoring. In the hole cleaning application, we consider the Clark and Bickham (1994) approach which requires the prediction of the local fluid velocity above the cuttings bed as a function of operating conditions. We develop accurate computational fluid dynamics (CFD) models to capture the effects of rotation, eccentricity and bed height on local fluid velocities above cuttings bed. We then run 55,000 CFD simulations for a wide range of operational settings to generate training data for machine learning. For rheology monitoring, thousands of lab experiment records are collected as training data for machine learning. In this case, the HPHT rheological properties are determined based on rheological measurement in the American Petroleum Institute (API) condition together with the fluid type and composition data. We compare the results of application of several machine learning algorithms to represent CFD simulations (for hole cleaning application) and lab experiments (for monitoring HPHT rheological properties). Rotating cross-validation method is applied to ensure accurate and robust results. In both cases, models from the Gradient Boosting and the Artificial Neural Network algorithms provided the highest accuracy (about 0.95 in terms of R-squared) for test datasets. With developments presented in this paper, the hole cleaning calculations can be performed more accurately in real-time, and the HPHT rheological properties of drilling fluids can be estimated at the rigsite before performing the lab experiments. These contributions advance digital transformation of drilling operations.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jinliang Liu ◽  
Fengshan Zhou ◽  
Fengyi Deng ◽  
Hongxing Zhao ◽  
Zhongjin Wei ◽  
...  

Abstract Most of bentonite used in modern drilling engineering is physically and chemically modified calcium bentonite. However, with the increase of drilling depth, the bottom hole temperature may reach 180 °C, thus a large amount of calcium bentonite used in the drilling fluid will be unstable. This paper covers three kinds of calcium bentonite with poor rheological properties at high temperature, such as apparent viscosity is greater than 45 mPa·s or less than 10 mPa·s, API filtration loss is greater than 25 mL/30 min, which are diluted type, shear thickening type and low-shear type, these defects will make the rheological properties of drilling fluid worse. The difference is attributed to bentonite mineral composition, such as montmorillonite with good hydration expansion performance. By adding three kinds of heat-resistant water-soluble copolymers Na-HPAN (hydrolyzed polyacrylonitrile sodium), PAS (polycarboxylate salt) and SMP (sulfomethyl phenolic resin), the rheological properties of calcium bentonite drilling fluids can be significantly improved. For example, the addition of 0.1 wt% Na-HPAN and 0.1 wt% PAS increased the apparent viscosity of the XZJ calcium bentonite suspension from 4.5 to 19.5 mPa·s at 180 °C, and the filtration loss also decreased from 20.2 to 17.8 mL.


2020 ◽  
Vol 10 (8) ◽  
pp. 3449-3466
Author(s):  
Atul Kumar Patidar ◽  
Anjali Sharma ◽  
Dev Joshi

Abstract The hydrocarbon extraction and exploitation using state-of-the-art modern drilling technologies urge the use of biodegradable, environment-friendly drilling fluid and drilling fluid additives to protect the environment and humanity. As more environmental laws are enacted and new safety rules implemented to oust the usage of toxic chemicals as fluid additives, it becomes inevitable that we re-evaluate our choice of drilling fluid additives. Drilling fluids and its additives play a crucial role in drilling operations as well as project costing; hence, it is needed that we develop cost-effective environment-friendly drilling fluid additives that meet the requirements for smooth functioning in geologically complex scenarios as well as have a minimal ecological impact. The current research work demonstrates key outcomes of investigations carried out on the formulation of a sustainable drilling fluid system, where groundnut husk is used as a fluid loss additive and a rheological modifier having no toxicity and high biodegradability. Cellulose was generated from groundnut husk at two varying particle sizes using mesh analysis, which was then compared with the commercially available PAC at different concentrations to validate its properties as a comparable fluid loss retarder additive as well as a rheological modifier. In the present work, various controlling characteristics of proposed groundnut husk additive are discussed, where comparison at different concentrations with a commercially available additive, PAC, is also validated. The API filtration losses demonstrated by the (63–74) µm and the (250–297) µm proposed additive showed a decrease of 91.88% and 82.31%, respectively, from the base mud at 4% concentration. The proposed husk additives acted as a filtrate retarder additive without much deviation from base rheology and with considerably higher pH than the base mud. This investigation indicates that the proposed fluid loss additive and rheological modifier can minimize the environmental hazards and have proved to be a cost-effective eco-friendly alternative in this challenging phase of the hydrocarbon exploration industry.


Author(s):  
Eric Cayeux ◽  
Amare Leulseged

Abstract It is nowadays well accepted that the steady state rheological behavior of drilling fluids must be modelled by at least three parameters. One of the most often used models is the yield power law, also referred as the Herschel-Bulkley model. Other models have been proposed like the one from Robertson-Stiff, while other industries have used other three-parameter models such as the one from Heinz-Casson. Some studies have been made to compare the degree of agreement between different rheological models and rheometer measurements but in most cases, already published works have only used mechanical rheometers that have a limited number of speeds and precision. For this paper, we have taken measurements with a scientific rheometer in well-controlled conditions of temperature and evaporation, and for relevant shear rates that are representative to normally encountered drilling operation conditions. Care has been made to minimize the effect of thixotropy on measurements, as the shear stress response of drilling fluids depends on its shear history. Measurements have been made at different temperatures, for various drilling fluid systems (both water and oil-based), and with variable levels of solid contents. Also, the shear rate reported by the rheometer itself, is corrected to account for the fact that the rheometer estimates the wall shear rate on the assumption that the tested fluid is Newtonian. A measure of proximity between the measurements and a rheological model is defined, thereby allowing the ranking of different rheological behavior model candidates. Based on the 469 rheograms of various drilling fluids that have been analyzed, it appears that the Heinz-Casson model describes most accurately the rheological behavior of the fluid samples, followed by the model of Carreau, Herschel-Bulkley and Robertson-Stiff, in decreasing order of fidelity.


2020 ◽  
Vol 7 (2) ◽  
pp. 191230
Author(s):  
Yuhuan Bu ◽  
Rui Ma ◽  
Jiapei Du ◽  
Shenglai Guo ◽  
Huajie Liu ◽  
...  

This research work designed a novel mud-cake solidification method to improve the zonal isolation of oil and gas wells. The calculation methodology of mud-cake compressive strength was proposed. The optimal formula of activator and solid precursors, the proper activating time and the best activator concentration were determined by the compressive strength test. The effects of solid precursors on the properties of drilling fluid were evaluated. Test results show that the respective percentage of bentonite, metakaolin, slag and activator is 1 : 1 : 0.3 : 0.8, as well as the optimum ratio of Na 2 SiO 3 /NaOH is 40 : 1. The optimum concentration of activator is 0.21 and the activating time should be more than 10 min. The solid precursors did not show any bad influence on the rheological property of drilling fluids. Even though the compressive strength decreased when the solid precursors blended with barite, the strength values can still achieve 8 MPa. The reaction of metakaolin and activator formed cross-link structure in the mud-cake matrix, which enhanced the connection of the loose bentonite particles, lead to the significant enhancement of shear bonding strength and hydraulic bonding strength. This mud-cake solidification method provides a new approach to improve the quality of zonal isolation.


SPE Journal ◽  
2020 ◽  
Vol 25 (05) ◽  
pp. 2220-2233
Author(s):  
Weian Huang ◽  
Ming Lei ◽  
Jingwen Wang ◽  
Kaihe Lv ◽  
Lin Jiang ◽  
...  

Summary The rheology of drilling fluid is commonly regulated by chemical methods. In this work, a physical method of a high-frequency and high-voltage alternating current (AC) electric field to regulate the rheological properties of water-based drilling fluid is established. The effects of the electric field on the continuous phase and dispersed phase, as well as two kinds of water-based drilling fluids, were investigated, and the response relationship among rheological properties modeled by Bingham and Herschel-Bulkley (H-B) models and electric-field parameters was explored. Results showed that water conductivity increased when voltage reached 4 kV, whereas it was restored to the original state after 3 hours in the absence of an electric field, showing a memory effect. The effect was also observed on bentonite suspension, whose plastic viscosity increased with the aid of an electric field and decreased over time. Voltage showed the greatest effect on bentonite-suspension viscosity, followed by frequency and pulse-width ratio. Under the condition of voltage of 5 kV, frequency of 5 kHz, and pulse-width ratio of 80%, there was a maximum increase of 50% in viscosity. The addition of salts caused bentonite-suspension flocculation, and electric field reduced the consistency coefficient and relieved flocculation state. When polymers were incorporated in bentonite suspension, the electric field could decrease the adsorption amount between clay particles and polymeric additives such as amphoteric and acrylamide-based polymers. For two typical drilling fluids, the voltage of an introduced electric field was the main controlling factor to change the rheological properties; their plastic viscosity and consistency coefficient both started to increase when voltage reached 4 kV.


2011 ◽  
Vol 134 (1) ◽  
Author(s):  
J. Abdo ◽  
M. Danish Haneef

The idea of pushing the limits of drilling oil and gas wells by improving drilling fluids for undemanding and cost efficient drilling operations by extracting advantage from the wonders of nanotechnology forms the basis of the work presented here. Foremost, in order to highlight the significance of reducing the size distribution of particles, new clay ATR which has a chain like structure and offers enormous surface area and increased reactivity was tested in different sizes that were chemically and mechanically milled. Bentonite which is a commonly used drilling fluid additive was also tested in different particle size distribution (PSD) and rheological properties were tested. Significant reduction in viscosity with small sized particles was recorded. The tested material called ATR throughout this paper is shown to offer better functionality than bentonite without the requirement of other expensive additives. Experiments were performed with different size distributions and compositions and drastic changes in rheological properties are observed. A detailed investigation of the shear thinning behavior was also carried out with ATR samples in order to confirm its functionality for eliminating the problem of mechanical and differential pipe sticking, while retaining suitable viscosity and density for avoidance of problems like lost circulation, poor hole cleaning and inappropriate operating hydrostatic pressures.


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