Shear induced deformation twinning evolution in thermoelectric InSb

Twin boundary (TB) engineering has been widely applied to enhance the strength and plasticity of metals and alloys, but is rarely adopted in thermoelectric (TE) semiconductors. Our previous first-principles results showed that nanotwins can strengthen TE Indium Antimony (InSb) through In–Sb covalent bond rearrangement at the TBs. Herein, we further show that shear-induced deformation twinning enhances plasticity of InSb. We demonstrate this by employing large-scale molecular dynamics (MD) to follow the shear stress response of flawless single-crystal InSb along various slip systems. We observed that the maximum shear strain for the $$(111)[11\bar 2]$$ ( 111 ) [ 11 2 ¯ ] slip system can be up to 0.85 due to shear-induced deformation twinning. We attribute this deformation twinning to the “catching bond” involving breaking and re-formation of In–Sb bond in InSb. This finding opens up a strategy to increase the plasticity of TE InSb by deformation twinning, which is expected to be implemented in other isotypic III–V semiconductors with zinc blende structure.

Tetraethyl Orthosilicate-Based Hydrogels for Drug Delivery—Effects of Their Nanoparticulate Structure on Release Properties

Tetraethyl orthosilicate (TEOS)-based hydrogels, with shear stress response and drug releasing properties, can be formulated simply by TEOS hydrolysis followed by volume corrections with aqueous solvents and pH adjustments. Such basic thixotropic hydrogels (thixogels) form via the colloidal aggregation of nanoparticulate silica. Herein, we investigated the effects of the nanoparticulate building blocks on the drug release properties of these materials. Our data indicate that the age of the hydrolyzed TEOS used for the formulation impacts the nanoparticulate structure and stiffness of thixogels. Moreover, the mechanism of formation or the disturbance of the nanoparticulate network significantly affects the release profiles of the incorporated drug. Collectively, our results underline the versatility of these basic, TEOS-only hydrogels for drug delivery applications.

Characterization of the Rheological Behavior of Drilling Fluids

It is nowadays well accepted that the steady state rheological behavior of drilling fluids must be modelled by at least three parameters. One of the most often used models is the yield power law, also referred as the Herschel-Bulkley model. Other models have been proposed like the one from Robertson-Stiff, while other industries have used other three-parameter models such as the one from Heinz-Casson. Some studies have been made to compare the degree of agreement between different rheological models and rheometer measurements but in most cases, already published works have only used mechanical rheometers that have a limited number of speeds and precision. For this paper, we have taken measurements with a scientific rheometer in well-controlled conditions of temperature and evaporation, and for relevant shear rates that are representative to normally encountered drilling operation conditions. Care has been made to minimize the effect of thixotropy on measurements, as the shear stress response of drilling fluids depends on its shear history. Measurements have been made at different temperatures, for various drilling fluid systems (both water and oil-based), and with variable levels of solid contents. Also, the shear rate reported by the rheometer itself, is corrected to account for the fact that the rheometer estimates the wall shear rate on the assumption that the tested fluid is Newtonian. A measure of proximity between the measurements and a rheological model is defined, thereby allowing the ranking of different rheological behavior model candidates. Based on the 469 rheograms of various drilling fluids that have been analyzed, it appears that the Heinz-Casson model describes most accurately the rheological behavior of the fluid samples, followed by the model of Carreau, Herschel-Bulkley and Robertson-Stiff, in decreasing order of fidelity.

On the large difference between Benjamin’s and Hanratty’s formulations of perturbed flow over uneven terrain

Flow over an uneven terrain is a complex phenomenon that requires a chain of approximations in order to be studied. In addition to modelling the intricacies of turbulence if present, the problem is classically first linearized about a flat bottom and a locally parallel flow, and then asymptotically approximated into an interactive representation that couples a boundary layer and an irrotational region through an intermediate inviscid but rotational layer. The first of these steps produces a stationary Orr–Sommerfeld equation; since this is a one-dimensional problem comparatively easy for any computer, it would seem appropriate today to forgo the second sweep of approximation and solve the Orr–Sommerfeld problem numerically. However, the results are inconsistent! It appears that the asymptotic approximation tacitly restores some of the original problem’s non-parallelism. In order to provide consistent results, Benjamin’s version of the Orr–Sommerfeld equation needs to be modified into Hanratty’s. The large difference between Benjamin’s and Hanratty’s formulations, which arises in some wavenumber ranges but not in others, is here explained through an asymptotic analysis based on the concept of admittance and on the symmetry transformations of the boundary layer. A compact and accurate analytical formula is provided for the wavenumber range of maximum laminar shear-stress response. We highlight that the maximum turbulent shear-stress response occurs in the quasi-laminar regime at a Reynolds-independent wavenumber, contrary to the maximum laminar shear-stress response whose wavenumber scales with a power of the boundary-layer thickness. A numerical computation involving an eddy-viscosity model provides a warning against the inaccuracy of such a model. We emphasize that the range $k\unicode[STIX]{x1D708}/u_{\unicode[STIX]{x1D70F}}<10^{-3}$ of the spectrum remains essentially unexplored, and that the question is still open whether a fully developed turbulent regime, similar to the one predicted by an eddy-viscosity model, ever exists for open flow even in the limit of infinite wavelength.