scholarly journals Application of Carboxymethyl Chitosan-Benzaldehyde as Anticorrosion Agent on Steel

2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Handoko Darmokoesoemo ◽  
Suyanto Suyanto ◽  
Leo Satya Anggara ◽  
Andrew Nosakhare Amenaghawon ◽  
Heri Septya Kusuma
Keyword(s):  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Daily Life ◽  
Steel Corrosion ◽  
Carboxymethyl Chitosan ◽  
Polarization Method ◽  
Gas Industry ◽  
Potentiostatic Polarization

Corrosion is one of the problems that is often found in daily life especially in petroleum and gas industry. Carboxymethyl chitosan- (CMC-) benzaldehyde was synthesized as corrosion inhibitor for steel. Corrosion rate was determined by potentiostatic polarization method in HCl 1 M. Dripping and coating, two different treatment, were used to drop and coat steel by CMC-benzaldehyde. The results showed that CMC-benzaldehyde could inhibit the corrosion rate of steel with concentration of 1 g, 3 g, 5 g, and 7 g in 60 mL of solvent. Coating steel with CMC-benzaldehyde with concentration of 7 g/60 mL of solvent and starch of 0.1 g/mL showed the highest efficiency to inhibit corrosion rate of steel. These treatments give corrosion efficiency of 99.8%.

Influence of Corrosion Inhibitor on Marine Concrete Corrosion Rate

2012 ◽  
Vol 446-449 ◽  
pp. 3508-3512
Author(s):  
Xian Ming Qin ◽  
Chao Yan ◽  
Yue Li ◽  
Juan Zhao
Keyword(s):  
Mechanical Properties ◽  
Reinforced Concrete ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Steel Corrosion ◽  
Polarization Method ◽  
Cement Ratio ◽  
Concrete Corrosion ◽  
Marine Concrete ◽  
Content Range

Corrosion inhibitor have a significant influence on corrosion rate of marine concrete. In this paper, linear polarization method is used in reinforced concrete that under marine environment, and reinforced concrete is mixed with corrosion inhibitor. The results show that: corrosion inhibitor has a little influence on the basic mechanical properties of reinforced concrete, and it can effectively improve the corrosion resistance ability of reinforced concrete. For reinforced concrete of the same corrosion inhibitor content, with the decline of water-cement ratio, the steel corrosion rate descends; in a certain content range , with the increase of corrosion inhibitor content, the corrosion rate of reinforced concrete decreases evidently.

Rhizophora apiculata Extract as Corrosion Inhibitor in 3.5% NaCl for API 5L Steel

2018 ◽  
Vol 791 ◽  
pp. 83-87
Author(s):  
Femiana Gapsari ◽  
Putu Hadi Setyarini ◽  
Andita N.F. Ganda
Keyword(s):  
Weight Loss ◽  
Fourier Transform ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Functional Groups ◽  
Inhibition Efficiency ◽  
Steel Corrosion ◽  
Polarization Method ◽  
Infra Red ◽  
Corrosion Inhibition Efficiency

The corrosion inhibition efficiency of Rhizophora acipulata(RA) extract was investigated for API 5L Steel corrosion in 3.5% NaCl using weight loss and polarization method. Fourier Transform Infra-Red (FTIR) was used toanalyze the characteristics of extract RA functional groups. The weight loss and polarization result indicated that extract RA inhibited API 5L steel corrosion rate. Based on the polarization result, the inhibition efficiency reached up 97.52% with addition 100ppm of RA extract.

scholarly journals Sintesis dan Aplikasi Karboksimetil Kitosan sebagai Inhibitor Korosi pada Baja Karbon dalam Air

2012 ◽  
Vol 12 (1) ◽  
pp. 87
Author(s):  
Maria Erna ◽  
Emriadi Emriadi ◽  
Admin Alif ◽  
Syukri Arief ◽  
Mohd Jain Noordin
Keyword(s):  
Infrared Spectroscopy ◽  
Corrosion Rate ◽  
Potentiodynamic Polarization ◽  
Langmuir Isotherm ◽  
Steel Surface ◽  
Inhibition Efficiency ◽  
Carboxymethyl Chitosan ◽  
Polarization Method ◽  
Wide Range ◽  
Water Ph

Carboxymethyl chitosan (CMC) was synthesized with different methods by reacting chitosan with monochloroaceticacid in the presence of sodium hydroxide under variation conditions. The above samples were characterized byFourier transform infrared spectroscopy (FTIR) and soluble in water in range of pH. The CMc were soluble in watera wide range of pH and applied as corrosion inhibitor for steel in water. The inhibiting influence of CMC was studiedby potentiodynamic polarization method. It was found thad corrosion rate was dependent on water pH and CMCconcentration. The results show that optimum the inhibition efficiency at pH 5 and 1 ppm concentration CMC, i.e.,77%. The adsorption of used compound on the steel surface obeys modified Langmuir isotherm. Polarizationmeasurement show that the CMC acts essentially as a anodic-type inhibitor.

scholarly journals Kinerja kalium metavanadat sebagai inhibitor korosi baja karbon rendah dalam lingkungan klorida dan sulfida

2018 ◽  
Vol 7 (3) ◽  
pp. 828
Author(s):  
Isdiriayani Nurdin ◽  
R Asri Pratiwi ◽  
Aditya Farhan A ◽  
Fikri Anggara P ◽  
Rennie Sari
Keyword(s):  
Carbon Steel ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Low Carbon Steel ◽  
Chloride Concentration ◽  
Steel Corrosion ◽  
Low Carbon ◽  
Cyclic Voltammetry Method ◽  
The Common ◽  
Chloride Environment

Inhibitor addition is one of the common corrosion control methods. Potassium metavanadate (KVO3) is the common corrosion inhibitor for Benfield solution in CO2 absorber. Former research shows that KVO3 is also able to inhibit the corrosion in seawater containing Sulphate Reducing Bacteria (SRB) due to its capacity as biocide. Chloride and Sulfide are common corrosive ions found in process fluids in industries. Therefore, this research is carried out to study the performance of KVO3 as a corrosion inhibitor for low- carbon steel in chloride and sulfide contaminated environment. The objective of this research was achieved by measuring low-carbon steel corrosion rate in various concentrations of contaminants. The corrosion rate was measured by Tafel method. The corrosion inhibition mechanisms were studied using cyclic voltammetry method. Meanwhile the corrosion products were identified by X - ray diffraction spectrometry (XRD). This research results that KVO3 is an effective corrosion inhibitor in chloride environment when the chloride concentration ranges between 20 g/L and 30 g/L. In this range of concentration, KVO3 performs more than 99% efficiency. While in sulfide environment, KVO3 is an ineffective corrosion inhibitor. On the other hand, the addition of KVO3 reduces the corrosion rate of carbon steel in seawater containing sulfide, although its performance does not meet the effective inhibitor criteria. Higher concentration of sulfide results the higher inhibition efficiency of KVO3.Keywords: Potassium metavanadate, low - carbon steel, corrosion inhibitor AbstrakPenambahan inhibitor merupakan salah satu metode pengendalian korosi. Kalium metavanadat (KVO3) sering digunakan sebagai inhibitor korosi pada absorber CO2 yang menggunakan larutan Benfield. Hasil penelitian sebelumnya menunjukkan bahwa KVO3 mampu menginhibisi korosi baja karbon rendah dalam air laut yang mengandung bakteri pereduksi sulfat (SRB) dengan bertindak sebagai biosida. Klorida dan sulfida merupakan ion-ion korosif yang umum ditemui dalam fluida proses di industri. Penelitian ini dilakukan untuk mempelajari kinerja KVO3 sebagai inhibitor korosi baja karbon rendah dalam lingkungan akuatik yang terkontaminasi klorida, ataupun sulfida. Untuk mencapai tujuan tersebut dilakukan pengukuran laju korosi baja karbon rendah dengan jenis dan konsentrasi kontaminan bervariasi. Pengukuran laju korosi dilakukan dengan metode Tafel. Mekanisme inhibisi diprediksi dengan metode voltametri siklik. Sedangkan produk korosi diidentifikasi dengan menggunakan spektrometri difraksi sinar X (XRD). Dari penelitian ini, diperoleh hasil bahwa KVO3 efektif sebagai inhibitor korosi baja karbon rendah pada lingkungan klorida berkonsentrasi antara 20 g/L hingga 30 g/L dengan efisiensi di atas 99%. Pada lingkungan sulfida, KVO3 kurang efektif menginhibisi korosi baja karbon rendah. Sedangkan pada air laut sintetik yang mengandung sulfida, walaupun belum termasuk kategori inhibitor efektif, namun KVO3 dapat menurunkan laju korosi baja karbon dengan efisiensi inhibisi yang meningkat seiring dengan kenaikan konsentrasi sulfida.Kata kunci: kalium metavanadat, baja karbon rendah, inhibitor korosi

Performance Evaluation of the Carbon Dioxide Corrosion Inhibitor IMC-1

2014 ◽  
Vol 490-491 ◽  
pp. 150-154
Author(s):  
Zhen Zhong Fan ◽  
Hui Ming An ◽  
Shu Yi Wang ◽  
Jun Feng Yang
Keyword(s):  
Carbon Dioxide ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Caprylic Acid ◽  
Acid Amide ◽  
Steel Corrosion ◽  
Electrode Reaction ◽  
Carbon Dioxide Corrosion ◽  
Electrochemical Polarization ◽  
N80 Steel

The carbon dioxide corrosion inhibitor IMC-1 was composed by caprylic acid amide polyoxyethylene ethers (n=4-5) and a small amount of the TX-10(5%). When the concentration was 200 mg/L, N80 steel corrosion rate was less than 0.125mm/a. With the CO2 partial pressure and temperature increased, N80 steel corrosion rate was decreased. From the electrochemical polarization curve, the adding corrosion inhibitor prevented the electrode reaction. The corrosion inhibitor IMC-1 was anodic inhibitor.

scholarly journals EXTRACT OF COCOR BEBEK (KALANCHOE PINNATA) AS A CORROSION INHIBITOR

2017 ◽  
Vol 6 (2) ◽  
pp. 112-116
Author(s):  
Tri Reksa Saputra ◽  
Agustinus Ngatin
Keyword(s):  
Carbon Steel ◽  
Corrosion Rate ◽  
Ethyl Acetate ◽  
Corrosion Inhibitor ◽  
Steel Corrosion ◽  
Metal Corrosion ◽  
Sharp Decline ◽  
Kalanchoe Pinnata ◽  
Rate Test ◽  
Corrosion Time

In this study, Cocor Bebek leaves (Kalanchoe pinnata) extract is studied for metal corrosion inhibitor. 10.3 kg of K. Pinnata leaves produce concentrated extract of methanol, n-hexane and ethyl acetate as much as 65.7442, 36.1452, and 15.2711 g respectively. The concentrated extracts were then used to determine the rate of corrosion. Corrosion rate test showed that extract of ethyl acetate can reduce corrosion rate of carbon steel in NaCl 3.5% from 2.954 mpy to 0.963 and 0.923 mpy using 500 ppm and 1000 ppm of extract consecutively. Corrosion rate of Cocor Bebek extract at addition of 500 ppm ethyl acetate in the solution of NaCl 3.5% is decreasing immediately. It was found that the carbon steel corrosion rate decrease as much 4.857 for 6 hours and continuously shows sharp decline until 24 hours of corrosion time. Corrosion rate is slowly decreasing till reach 1.694 mpy at corrosion time of 168 hours.

scholarly journals Investigation of pumpkin pod extract as corrosion inhibitor for carbon steel in HCl Solution

2020 ◽  
Vol 39 (1) ◽  
pp. 173-181
Author(s):  
A.O. Okewale ◽  
T. Adebayo
Keyword(s):  
Response Surface Methodology ◽  
Carbon Steel ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Response Surface ◽  
Steel Corrosion ◽  
Optimal Conditions ◽  
Extract Concentration ◽  
Process Factors ◽  
Hcl Solution

This work focused on the use of natural, and eco-friendly waste material as an inhibitor for inhibiting carbon steel corrosion. In order to obtain minimum rate of corrosion on carbon steel, optimization of the process factors that affect carbon steel corrosion was undertaken using the Response Surface Methodology (RSM). Three parameters were fluctuated viz; temperature, pumpkin pod extract concentration and time of exposure and their corresponding effects on rate of corrosion of carbon steel were ascertained. The data obtained was fitted to a model that is quadratic which was subsequently validated. The predicted lowest rate of corrosion by the model is 2.5427mm/yr with optimal conditions of 178.07ppm of pumpkin extract concentration, exposure time of 2.26hrs, and 35.28oC of temperature. The conditions were validated in three replicates and corrosion rate of 2.75mm/yr was obtained. Keywords: corrosion, optimization, pumpkin pod, response surface methodology.

scholarly journals Inhibisi korosi baja dalam air kondensat terkontaminasi CuCl2 menggunakan natrium fosfat

2018 ◽  
Vol 6 (1) ◽  
pp. 589
Author(s):  
Isdiriayani Nordin ◽  
Ismail Marzuki ◽  
Larisa Deviyani ◽  
M Irfan S
Keyword(s):  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Copper Ion ◽  
Steel Corrosion ◽  
Trisodium Phosphate ◽  
Experimental Result ◽  
Irreversible Reaction ◽  
Disodium Phosphate ◽  
Corrosion Reaction ◽  
Sodium Phosphates

Steel corrosion inhibition in CuCl2-contaminated condensate water using natrium fosfatCorrosion in condenser system, boiler or condensate line caused by reaction between inside surface of pipe and tube with condensate water contamined by copper ion (Cu2+) as corrosion product of heat exchanger. Additon of sodium phospate in Trisodium Phosphate (TSP) and Disodium Phosphate (DSP) form as corrosion inhibitor for controlling this corrosion. This research is aim to find out the influence of CuCl2 contaminant to steel corrosion rate in condensate water, and the efectiveness of TSP and DSP as corrosion inhibitor in such system. In this research, the corrosion rate measurement in artificial condensate water with tafel method, The corrosion inhibitions mechanism was studied using cyclic voltametry method. The experimental result shows that corrosion rate is increases in artificial condensate water had contaminated by CuCl2. DSP-TSP combination is effective as a steel corrosion inhibitor in condensate water contaminated by CuCl2. The highest effectiveness achieved in ratio DSP:TSP 35:65. Corrosion reaction of steel in artificial condensate water contaminated by CuCl2 with inhibitor addition is an irreversible reaction and occurs in one-step reaction.Keywords: Condensate Water, CuCl2, Sodium Phosphates, Steels Corrosion  AbstrakKorosi pada sistem kondensor dan  boiler atau jalur kondensat diakibatkan oleh reaksi antara permukaan dalam pipa dan tube dengan air boiler atau air kondensat yang terkontaminasi ion tembaga (Cu2+), yang berasal dari produk korosi alat-alat penukar panas. Untuk mengendalikan korosi tersebut ditambahkan natrium fosfat dalam bentuk Trisodium Phosphate (TSP) dan Disodium Phosphate (DSP) sebagai inhibitor korosi. Penelitian ini bertujuan untuk mengetahui pengaruh kontaminan CuCl2 terhadap korosi baja dalam air kondensat, dan efektivitas inhibisi korosi DSP dan TSP Pada penelitian ini, pengukuran laju korosi baja dalam air kondensat buatan yang ditambah dengan CuCl2 dan variasi konsentrasi inhibitor dilakukan dengan metode Tafel. Mekanisme inhibisi diprediksi berdasarkan metoda voltametri siklik. Hasil percobaan menunjukkan bahwa laju korosi baja dalam air kondensat tiruan meningkat dengan kehadiran kontaminan CuCl2. Kombinasi DSP­ TSP efektif sebagai inhibitor korosi baja dalam air kondensat terkontaminasi CuCl2, dengan keefektifan inhibisi korosi tertinggi didapat pada nisbah DSP:TSP 35:65. Reaksi korosi baja dalam air kondensat tiruan terkontaminasi CuCl2 dengan penambahan inhibitor adalah oksidasi besi (Fe) menjadi besi(II) yang irreversibel dan berlangsung dalam satu tahap.Kata kunci: Air Kondensat, CuCl2, Korosi Baja, Natrium Fosfat

scholarly journals Inhibisi korosi baja dalam air laur mengandung sulfida menggunakan glutaraldehida

2018 ◽  
Vol 5 (1) ◽  
pp. 341
Author(s):  
Larisa Deviyani ◽  
Isdiriayani Nurdin
Keyword(s):  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Steel Corrosion ◽  
Artificial Seawater ◽  
Experimental Result ◽  
Process Equipment ◽  
Inhibition Mechanism ◽  
Irreversible Reaction ◽  
Corrosion Reaction ◽  
Sulfide Corrosion

Most of steel corrosion on process equipment using seawater as utilities is due to corrosive seawater contaminants; one of which is sulfide. Corrosion control, which is commonly applied to steel in sulfide containing seawater, is chemical inhibition. In this research, the influence of H2S concentration on corrosion of steel in artificial seawater, and determination of the optimum doses of glutaraldehyde as corrosion inhibitor, are carried out by corrosion rate measurement according Tafel method; while prediction of inhibition mechanism is studied according to cyclic voltammetry method. The experimental result shows that steel is readily corroded in artificial seawater. Addition of H2S to artificial seawater increases corrosion rate. Glutaraldehiyde is an effective corrosion inhibitor for steel in seawater contaminated by H2S. The highest inhibition effectiveness on steel corrosion in seawater contaminated by 250 ppm H2S is 99.99%, which is obtained by adding of 80 ppm glutaraldehiyde. Generally, the oxidation reaction of steel in artificial seawater contaminated by H2S and inhibited with glutaraldehyde, is a one step irreversible reaction giving unstable product. Glutaraldehyde inhibits corrosion reaction through adsorption on steel surface, proven by reduction of corrosion product quantity.Keywords: Corrosion Inhibitor, Steel, Glutaraldehyde, Sulfide. AbstrakKorosi peralatan proses terbuat dari bajayang menggunakan air laut sebagai air utilitas disebabkan oleh kontaminan air laut yang bersifat korosif, salah satunya adalah sulfida. Pengendalian korosi baja dalam air laut mengandung sulfida dilakukan dengan penambahan inhibitor. Pada penelitian ini, untuk mengetahui pengaruh konsentrasi H2S dalam air laut terhadap korosi baja, serta menentukan dosis optimum glutaraldehida sebagai inhibitor korosi, dilakukan pengukuran  laju korosi baja dengan metoda Tafel, dan perkiraan mekanisme inhibisi dengan metode voltameri siklik. Hasil percobaan menunjukkan bahwa baja terkorosi dalam air laut tiruan. Penambahan H2S dalam air laut tiruan meningkatkan laju korosi baja. Glutaraldehida efektif sebagai inhibitor korosi baja dalam air laut terkontaminasi H2S, dengan keefektifan inhibisi tertinggi adalah 99,99%, yang diperoleh dengan penambahan 80 ppm glutaraldehida ke dalam air laut tiruan yang mengandung 250 ppm H2S. Secara umum reaksi oksidasi baja dalam air laut tiruan terkontaminasi H2S dengan penambahan glutaraldehida berlangsung dalam satu tahap, merupakan reaksi irreversibel dengan produk reaksi yang bersifat tidak stabil. Inhibitor glutaraldehida menghambat korosi dengan cara teradsorbsi dipermukaan pelat baja, terbukti dengan penurunan kuantitas produk korosi.Kata Kunci: Inhibitor Korosi, Baja, Glutaraldehida, Sulfida

scholarly journals THE EFFICIENCY OF CRUDE CORROSION INHIBITOR AND GAS CORROSION INHIBITOR BY USING CARBON STEEL 1018 WITH POLARIZATION METHOD

2020 ◽  
Vol 4 (2) ◽  
Author(s):  
Puji Astuti Ibrahim
Keyword(s):  
Carbon Steel ◽  
Corrosion Inhibitor ◽  
Corrosion Inhibitors ◽  
Inhibition Efficiency ◽  
Low Carbon Steel ◽  
Steel Corrosion ◽  
Low Carbon ◽  
Polarization Method ◽  
Corrosive Media ◽  
Gas Corrosion

Carbon Steel 1018 is a low carbon steel having a carbon content (C) of 0.14-0.20% (<0.30% C). Low carbon steel is commercially known as mild steel. Corrosion is one way to prevent corrosion caused by the environment. Corrosion inhibitor are taken between the Crude Corrosion Inhibitor and Gas Corrosion inhibitor on Carbon Steel 1018 using the polarization method. Corrosion inhibitors work by making passive layers in the form of thin films or films on the surface of the material used as a barrier between metals and corrosive media. The analysis method used is polarization. Inhibition Efficiency Results obtained for Gas Corrosion Inhibitors (1A) at 10 ppm 96.86%, 20 ppm 59.74%, 30 ppm 74.48%. The Crude Corrosion Inhibitor (2A) results obtained inhibition efficiency for 10 ppm 99.57%, 20 ppm 77.69%, and 30 ppm 12.63%. The optimum value for the Gas Corrosion Inhibitor and Crude Corrosion Inhibitor is at 10 ppm at 96.86% and 99.57%. Keywords: carbon steel,crude corrosion inhibitor, corrosion , gas corrosion inhibitor, inhibitor

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