scholarly journals Production of Monomeric Aromatic Compounds from Oil Palm Empty Fruit Bunch Fiber Lignin by Chemical and Enzymatic Methods

2015 ◽  
Vol 2015 ◽  
pp. 1-14 ◽  
Author(s):  
Pei-Ling Tang ◽  
Osman Hassan ◽  
Mohamad Yusof Maskat ◽  
Khairiah Badri
Keyword(s):  
Ferulic Acid ◽  
Sodium Hydroxide ◽  
Oil Palm ◽  
Aromatic Compounds ◽  
Hydroxybenzoic Acid ◽  
Empty Fruit Bunch ◽  
Coumaric Acid ◽  
Oxidation Condition ◽  
Sodium Hydroxide Concentration ◽  
Nitrobenzene Oxidation

In this study, oil palm empty fruit bunch (OPEFBF) was pretreated with alkali, and lignin was extracted for further degradation into lower molecular weight phenolic compounds using enzymes and chemical means. Efficiency of monomeric aromatic compounds production from OPEFBF lignin via chemical (nitrobenzene versus oxygen) and enzymatic [cutinase versus manganese peroxidase (MnP)] approaches was investigated. The effects of sodium hydroxide concentration (2, 5, and 10% wt.) and reaction time (30, 90, and 180 minutes) on the yield of aromatic compounds were studied. The results obtained indicated that nitrobenzene oxidation produced the highest yield (333.17±49.44 ppm hydroxybenzoic acid,5.67±0.25 ppmp-hydroxybenzaldehyde,25.57±1.64 ppm vanillic acid,168.68±23.23 ppm vanillin,75.44±6.71 ppm syringic acid,815.26±41.77 ppm syringaldehyde,15.21±2.19 ppmp-coumaric acid, and44.75±3.40 ppm ferulic acid), among the tested methods. High sodium hydroxide concentration (10% wt.) was needed to promote efficient nitrobenzene oxidation. However, less severe oxidation condition was preferred to preserve the hydroxycinnamic acids (p-coumaric acid and ferulic acid). Cutinase-catalyzed hydrolysis was found to be more efficient than MnP-catalyzed oxidation in the production of aromatic compounds. By hydrolyzed 8% wt. of lignin with 0.625 mL cutinase g−1lignin at pH 8 and 55°C for 24 hours, about642.83±14.45 ppm hydroxybenzoic acid,70.19±3.31 ppm syringaldehyde,22.80±1.04 ppm vanillin,27.06±1.20 ppmp-coumaric acid, and50.19±2.23 ppm ferulic acid were produced.

scholarly journals Tensile Characterizations of Oil Palm Empty Fruit Bunch (OPEFB) Fibres Reinforced Composites in Various Epoxy/Fibre Fractions

2021 ◽  
Vol 12 (5) ◽  
pp. 6148-6163
Keyword(s):  
Sodium Hydroxide ◽  
Oil Palm ◽  
Fiber Composite ◽  
Tensile Tests ◽  
Empty Fruit Bunch ◽  
Reinforced Composites ◽  
Soaking Time ◽  
Single Fibers ◽  
The Matrix ◽  
Treated Fiber

Oil palm empty fruit bunch (OPEFB) single fibers and reinforced composites were comprehensively characterized through tensile tests to assess their performance as potential reinforcing materials in polymer composites. The performances of OPEFB single fibers and reinforced composites with untreated and treated fibers conditions were compared. The fibers were variously treated with 3% sodium hydroxide, 2% silane, 3% sodium hydroxide mixed with 2% silane, and 3% sodium hydroxide prior to 2% silane for 2 hours soaking time. The highest toughness of the single fibers test was then selected to proceed with composites fabrication. The OPEFB composites were fabricated in 90:10, 80:20, 70:30, and 60:40 epoxy-fibre fractions. The result shows that the selected treated fiber composite exhibits better performance. The selected treated fiber composite increased the highest ultimate tensile strength by 145.3% for the 90:10 fraction. The highest Young’s Modulus was increased by about 166.7% for 70:30 fraction. Next, the highest toughness was increased by 389.5% for the 30:70 fraction. The treated fibers provided a better interlocking mechanism between the matrix and fibers in reinforced composites, thus improving their interfacial bonding.

scholarly journals Sodium Hydroxide-Steam Explosion Treated Oil Palm Empty Fruit Bunch: Ethanol Production and Co-Fermentation with Cane Molasses

BioResources ◽  
2016 ◽  
Vol 11 (3) ◽  
Author(s):  
Trinset Weeraphan ◽  
Vasana Tolieng Tolieng ◽  
Vichien Kitpreechavanich ◽  
Somboon Tanasupawat ◽  
Ancharida Akaracharanya
Keyword(s):  
Ethanol Production ◽  
Sodium Hydroxide ◽  
Oil Palm ◽  
Steam Explosion ◽  
Empty Fruit Bunch ◽  
Cane Molasses

COUMARINS AND PHENOLIC ACIDS IN THE UREDOSPORES OF WHEAT STEM RUST

1957 ◽  
Vol 3 (6) ◽  
pp. 847-862 ◽  
Author(s):  
C. F. van Sumere ◽  
C. van Sumere-de Preter ◽  
L. C. Vining ◽  
G. A. Ledingham
Keyword(s):  
Ferulic Acid ◽  
Caffeic Acid ◽  
Phenolic Acids ◽  
Stem Rust ◽  
Vanillic Acid ◽  
Protocatechuic Acid ◽  
Hydroxybenzoic Acid ◽  
Coumaric Acid ◽  
Wheat Stem Rust ◽  
Stimulation Of

A paper chromatographic method suitable for identification of the small amounts of coumarins and phenolic acids present in the uredospores of wheat stem rust was developed. By the use of the circular technique and a combination of three different solvent systems an adequate separation of all the substances was achieved. A preliminary development of the chromatogram with a solvent in which the test compounds were non-mobile facilitated identification and avoided the need for extensive preliminary fractionation of the extracts.Using this method the following compounds were identified in spore extracts: coumarin, umbelliferone, daphnetin, aesculetin, p-hydroxybenzoic acid, vanillic acid, protocatechuic acid, o-coumaric acid, p-coumaric acid, ferulic acid, and caffeic acid; coumarin, p-hydroxybenzoic acid, vanillic acid, protocatechuic acid, o-coumaric acid, and ferulic acid were also present as glycosides; in addition scopoletin, gallic acid, syringic acid, and sinapic acid were detected after hydrolysis and are assumed to be present only in a bound form.In order to obtain some information about the role of these substances in the physiology of wheat stem rust, uredospores were germinated by being floated en masse on dilute aqueous solutions. Of the compounds tested, indoleacetic acid, coumarin, o-coumaric acid, protocatechuic acid, umbelliferone, and daphnetin gave a marked stimulation of germination at concentrations of 10–200 μg./ml. Caffeic acid, vanillic acid, p-hydroxybenzoic acid, ferulic acid, and ferulic acid β-glucoside had little effect or were strongly inhibitory.The stimulation of germination is attributed to the counteraction of a self-inhibitor released from the spores, and the possible significance of the compounds on the physiology of the rust and the host–parasite relationship is discussed.

scholarly journals Oxidation of Cellulose from Oil Palm Empty Fruit Bunch Using Hydrogen Peroxide in Alkaline Condition

2018 ◽  
Vol 8 (02) ◽  
pp. 51 ◽  
Author(s):  
Isroi Isroi ◽  
Adi Cifriadi
Keyword(s):  
Hydrogen Peroxide ◽  
Sodium Hydroxide ◽  
Sodium Hypochlorite ◽  
Oil Palm ◽  
Visual Analysis ◽  
Alkaline Condition ◽  
Cellulose Content ◽  
Empty Fruit Bunch ◽  
Cellulose Oxidation ◽  
Oxidation Effect

There are growing interest to use cellulose as renewable material in order to replace non-renewable polymeric materials. Alteration and chemical modifications of the cellulose by oxidation is needed to improve its properties and functionality. The aim of this study was to evaluate oxidation effect of the cellulose from oil palm empty fruit bunch (OPEFB) using hydrogen peroxide in alkaline condition. Cellulose has been isolated and purified by sodium hydroxide method followed by sodium hypochlorite bleaching. The oxidation effect of the cellulose by hydrogen peroxide was investigated by component analysis of the lignocelluloses, visual analysis, physical and chemical properties. Fourier transform infrared spectroscopy was employed to evaluate the changes of functional groups. Digesting of the OPEFB by sodium hydroxide at temperature 160oC for 4 hours reduced lignin content from 22.58% to 16.60%, increase cellulose and hemicelluloses content from 60.76% to 73.87% and 25.86% to 30.95%, respectively. Treatment of the OPEFB pulp using sodium hypochlorite removed all residual lignin. Cellulose content was increased up to 90.86%. Degree of polymerization of the oxidized cellulose was reduced from 1997 to 658. Carboxyl groups of celluloses was significantly increased and confirmed by titration analysis. OPEFB cellulose fiber was damage and broken, meanwhile crystallinity of the cellulose was reduced.Keywords: cellulose, oxidation, oil palm empty fruit bunch, carboxyl group, crystallinity, physical properties Oksidasi Selulosa dari Tandan Kosong Kelapa Sawit menggunakan Hidrogen Peroksida dalam Kondisi BasaAbstrakPerhatian untuk memanfaatkan selulosa sebagai polimer terbarukan untuk menggantikan polimer tidak terbarukan mengalami peningkatan. Perubahan dan modifikasi kimia selulosa melalui proses oksidasi diperlukan untuk meningkatkan sifat dan fungsi selulosa. Penelitian ini bertujuan untuk mempelajari pengaruh oksidasi selulosa dari tandan kosong kelapa sawit (TKKS) menggunakan hidrogen peroksida dalam suasana basa. Selulosa diisolasi dan dimurnikan dengan metode natrium hidroksida dan dilanjutkan dengan pemutihan natrium hipoklorit. Efek oksidasi selulosa oleh hidrogen peroksida dievaluasi menggunakan analisis komponen lignoselulosa, analisis visual, sifat fisik dan kimia. Analisis spektroskopi inframerah (FTIR) digunakan untuk mengevaluasi perubahan gugus fungsional selulosa. Pemasakan TKKS dengan natrium hidroksida pada suhu160oC selama 4 jam mengurangi kandungan lignin dari 22,58% menjadi 16,60%, meningkatkan kandungan selulosa dari 60,76% menjadi 73,87% dan hemiselulosa dari 25,86% menjadi 30,95%. Perlakuan pulp TKKS menggunakan natrium hipoklorit menghilangkan semua sisa lignin. Kandungan selulosa meningkat hingga 90,86%. Oksidasi selulosa dengan hidrogen peroksida menurunkan derajat polimerisasi selulosa dari 1997 menjadi 658. Gugus karboksil selulosa meningkat secara signifikan dan dikonfirmasi dengan analisis titrasi. Analisis visual menunjukkan kerusakan serabut selulosa, sesuai dengan pengurangan kristalinitas selulosa.Kata kunci: selulosa, oksidasi, tandan kosong kelapa sawit, gugus karboksil, kristalinitas, sifat fisik 

Notizen: Phenolics from Larix Needles XIV. Flavonoids and Phenolic Glucosides and Ester of L. decidua

1978 ◽  
Vol 33 (9-10) ◽  
pp. 780-782 ◽  
Author(s):  
Gerard J. Niemann ◽  
Wim J. Baas
Keyword(s):  
Ferulic Acid ◽  
Vanillic Acid ◽  
Larix Decidua ◽  
Hydroxybenzoic Acid ◽  
Coumaric Acid ◽  
Sugar Ester ◽  
Glucose Ester ◽  
Phenolic Glucosides

Abstract Eleven flavonoids, four phenolic glucosides and one sugar ester were isolated from needles of Larix decidua and identified as: kaempferol, its 3-arabinoside and 3-rutino-side, quercetin-3-arabinoside, isorhamnetin-3-arabinoside and 3-(p-coumarylglucoside), laricitrin-3-glucoside and -3-rutino-side, myricetin-3-glucoside, syringetin-3-glucoside and apigenin-7-glucoside; the β-glucosides of p-hydroxybenzoic acid, vanillic acid, p-coumaric acid and ferulic acid, and the glucose ester of vanillic acid.

Fractional Isolation and Characterization of Polysaccharides from Oil Palm Trunk and Empty Fruit Bunch Fibres

Holzforschung ◽  
1999 ◽  
Vol 53 (3) ◽  
pp. 253-260 ◽  
Author(s):  
R. Sun ◽  
J.M. Fang ◽  
L. Mott ◽  
J. Bolton
Keyword(s):  
Oil Palm ◽  
Cell Walls ◽  
Cold Water ◽  
Syringic Acid ◽  
Hot Water ◽  
Empty Fruit Bunch ◽  
Coumaric Acid ◽  
Oil Palm Trunk ◽  
Isolation And Characterization

Summary The polysaccharides in oil palm trunk fibre and empty fruit bunch (EFB) fibre were fractionated into cold water solubles, hot water solubles, 1% NaOH solubles, and 17.5% NaOH soluble fractions. Cellulose (approximately 42%) and hemicelluloses (approximately 33%) were the major polysaccharides in the palm trunk fibre and EFB fibre. Extractions of the lignified fibres with cold water, hot water, and 1% NaOH produced the hemicellulosic fractions, which were enriched in xylose and glucose and to a lesser extent, arabinose-, galactose-, mannose-, rhamnose-, and ribose-containing polysaccharides, together with noticeable amounts of associated lignin (4.5–31.2%). Further extraction of the delignified fibre residues with aqueous 17.5% NaOH removed the hemicellulosic fractions, which were strongly enriched in xylose-containing polysaccharides and relatively free of associated lignin (0.3–0.7%). Eight phenolic acids and aldehydes, including p-hydroxybenzoic acid, p-hydroxybenzaldehyde, vanillic acid, syringic acid, vanillin, syringaldehyde, p-coumaric acid, and ferulic acid, were detected in the mixtures of alkaline nitrobenzene oxidation of associated lignin in all the sixteen polysaccharide fractions. The results obtained showed that hemicelluloses in the cell walls of oil palm trunk and EFB fibres, are mainly bonded with lignin by syringyl units.

scholarly journals BIODEGRADABILITY OF BIOPLASTIC IN NATURAL ENVIRONMENT

2019 ◽  
Vol 9 (2) ◽  
pp. 258-263
Author(s):  
Anggun Rahman Rahman ◽  
Khaswar Syamsu Syamsu ◽  
Isroi Isroi Isroi
Keyword(s):  
Sodium Hydroxide ◽  
Natural Environment ◽  
Oil Palm ◽  
Co2 Production ◽  
Empty Fruit Bunch ◽  
Biodegradation Rate ◽  
Empty Fruit Bunches ◽  
Top Soil ◽  
Biodegradation Process ◽  
Biodegradation Test

Biodegradation of the bioplastic composite based on cellulose from oil palm empty fruit bunches was investigated in this study. Microbes consortium from landfill soil collected from top soil were used as the inoculums for the biodegradation process. Biodegradation test of the bioplastic from oil palm empty fruit bunch samples compared with oxodegradation and conventional plastic samples were conducted in the glass jar. The biodegradation rate was evaluated from CO2 generated from the biodegradation process and absorbed by 0.1 N sodium hydroxide solutions. The generated CO2 was titrated with 0.1 N HCl and using phenolphthalein (PP) followed by methyl oranges indicator. The results showed that the highest CO2 production on landfill soil indicating the highest rate of biodegradation was found on bioplastic from oil palm empty fruit bunch followed by oxodegradable plastic and conventional plastic. The rate of biodegradation for bioplastic from oil palm empty fruit bunch, oxodegradable plastic and conventional plastic were 0.067mg CO2/day, 0.052 mg CO2/day and 0 mg CO2/day, respectively.

scholarly journals Characterization of Lignin Precipitated From The Soda Black Liquor of Oil Palm Empty Fruit Bunch Fibers by Various Mineral Acids

2017 ◽  
Vol 21 (1) ◽  
pp. 57 ◽  
Author(s):  
M.N Mohamad Ibrahim ◽  
S.B Chuah ◽  
W.D. Wan Rosli
Keyword(s):  
Phosphoric Acid ◽  
Oil Palm ◽  
Black Liquor ◽  
Structural Features ◽  
Empty Fruit Bunch ◽  
Nitrobenzene Oxidation ◽  
Significant Difference ◽  
Mineral Acids ◽  
Ft Ir ◽  
Soda Lignin

Soda lignin from oil palm empty fruit bunch was directly isolated by various mineral acids i.e. sulfuric acid, hydrochloric acid, phosphoric acid and nitric acid at three levels of concentration (20% v/v, 60%v/v and concentrated). A comparison study was performed through physicochemical properties and structural features using FT-IR, UV, 13C-NMR and nitrobenzene oxidation. The FT-IR results showed that there is no significant difference between the main structures of the lignin isolated by various acids. However, low concentration of phosphoric acid is preferable because of its highest yield. The S: V: H ratio of 7-15:6-11:1 as evaluated by the nitrobenzene oxidation procedure suggests that soda lignin can be classified as belonging to either the cereal straw on grass type. The UV results indicate that phosphoric acid consistently gave the highest absorbance value among the four acids tested in this study regardless of its concentration level. The C13-FTNMR spectra, suggest that the lignin structure is independent of the type of acid used for precipitation.

scholarly journals Metabolic Analysis of Carotenoids and Phenolic Compounds Found in Green and Purple Kenaf

2020 ◽  
Vol 15 (11) ◽  
pp. 1934578X2097113
Author(s):  
Chang Ha Park ◽  
Soon-Jae Kwon ◽  
Nam Su Kim ◽  
Seung-A Baek ◽  
Hyeon Ji Yeo ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Phenolic Compounds ◽  
Benzoic Acid ◽  
Ferulic Acid ◽  
Total Phenolics ◽  
Hydroxybenzoic Acid ◽  
Coumaric Acid ◽  
Plant Parts ◽  
Β Carotene ◽  
Different Parts

The chemical composition of the different plant parts of green ( Hibiscus cannabinus L. cv. Jangdae) and purple ( H. cannabinus L. cv. Jeokbong) kenaf cultivars were investigated using high-performance liquid chromatography. Ten carotenoid and phenolic compounds were quantified in the different parts of green and purple kenaf. The accumulation of carotenoids and phenolic compounds in the different parts of both cultivars was slightly different. The total carotenoid content in all parts of purple kenaf was higher than that in green kenaf. In particular, lutein, β-carotene, and 9Z-β-carotene were found in all the plant parts of both purple and green kenaf. Most levels of these 3 carotenoids were higher in all parts of the purple cultivar than those found in the green cultivar. According to the detected phenolic compound content, the leaves of the green cultivar contained a higher level of total phenolics, even though the most levels of the individual phenolic compounds were higher in the purple cultivar due to the level of kaempferitrin, a major compound found in kenaf, being much higher than the levels observed for the other phenolic compounds. However, the flowers and stems of the purple cultivar had a higher level of total phenolics. Among the 10 different phenolic compounds, 7 (4-hydroxybenzoic acid, chlorogenic acid, p-coumaric acid, ferulic acid, benzoic acid, rutin, and kaempferol) were present in all the plant parts of both kenaf cultivars. Purple kenaf leaves contain higher levels of 4-hydroxybenzoic acid, chlorogenic acid, and rutin, whereas the purple cultivar flowers have higher levels of p-coumaric acid, ferulic acid, and benzoic acid. This study provides valuable information on the chemical composition of different plant parts of green and purple kenaf cultivars.

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