scholarly journals Electrochemical Behavior of Some Lanthanides in Imide Room-Temperature Molten Salt Systems

2002 ◽  
Vol 2002-19 (1) ◽  
pp. 640-648 ◽  
Author(s):  
Masaki Yamagata
Keyword(s):  
Molten Salt ◽  
Electrochemical Behavior ◽  
Room Temperature ◽  
Salt Systems

Electrochemical Behavior of Iron(II) Species in a Hydrophobic Room-temperature Molten Salt

2005 ◽  
Vol 73 (8) ◽  
pp. 564-566 ◽  
Author(s):  
Masaki YAMAGATA ◽  
Naoki TACHIKAWA ◽  
Yasushi KATAYAMA ◽  
Takashi MIURA
Keyword(s):  
Molten Salt ◽  
Electrochemical Behavior ◽  
Room Temperature

Conductivities of Room Temperature Molten Salts Containing AlCl3, Measured by a Computerized Direct Current Method

2001 ◽  
Vol 56 (9-10) ◽  
pp. 670-676
Author(s):  
Hsin-Yi Hsu ◽  
Chao-Cheng Yang
Keyword(s):  
Molten Salt ◽  
Direct Current ◽  
Molten Salts ◽  
Room Temperature ◽  
Current Method ◽  
Activation Energies ◽  
Nium Chloride ◽  
Temperature Range ◽  
Different Temperatures ◽  
Salt Systems

Abstract The conductivities of the binary room-temperature molten salt systems AlCl3-N-n-butylpyridinium chloride (BPC), AlCl3-l-ethyl-3-methylimidazolium chloride (EMIC) and AlCl3-benzyltriethylammo-nium chloride (BTEAC) have been measured at different temperatures and compositions by a d.c. four-probes method. There is a maximum of the conductivity at 50 mol% AlCl3 in the AlCl3-BPC and AlCl3-EMIC systems at 40 to 80 °C, their activation energies being relatively low (20.79 and 14.76 kJ/mol, respec­ tively). As to the A1C13-BTEAC system, there is an irregular change in the conductivity at 40-70 mol% AlCl3 in the temperature range 50 to 80 °C. The conductivities of the three RTMS are in the order AlCl3-EMIC > AlCl3-BPC > AlCl3-BTEAC, the reason being discussed.

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