On the absence of triplet ketene in ketene excited in the region 2800–3660 Å

1969 ◽  
Vol 47 (16) ◽  
pp. 3079-3081 ◽  
Author(s):  
M. Grossman ◽  
G. P. Semeluk ◽  
I. Unger
Keyword(s):  
Wavelength Region ◽  
Exciting Wavelength

The sensitized biacetyl emission technique was used in an attempt to detect triplet ketene molecules, which might be formed when ketene is excited by light ranging in wavelength from 2800 to 3600 Å. No sensitized emission was observed in this exciting wavelength region thus confirming the recent results of Voisey (1) which also show that triplet ketene is not produced when ketene is excited by light between 2800 and 3200 Å, and that the triplet CH2 found in such systems must arise from some source other than triplet ketene.

scholarly journals Planetary Nebulae in M31: Abundances, and comparison with bright Planetary Nebulae in the LMC

1997 ◽  
Vol 180 ◽  
pp. 475-476
Author(s):  
M. G. Richer ◽  
G. Stasińska ◽  
M. L. McCall
Keyword(s):  
Planetary Nebula ◽  
Luminosity Function ◽  
Large Population ◽  
Wavelength Region ◽  
Planetary Nebulae ◽  
Surprising Result ◽  
Population Synthesis ◽  
Abundance Distribution ◽  
Wide Range ◽  
The Mean

We have obtained spectra of 28 planetary nebulae in the bulge of M31 using the MOS spectrograph at the Canada-France-Hawaii Telescope. Typically, we observed the [O II] λ3727 to He I λ5876 wavelength region at a resolution of approximately 1.6 å/pixel. For 19 of the 21 planetary nebulae whose [OIII]λ5007 luminosities are within 1 mag of the peak of the planetary nebula luminosity function, our oxygen abundances are based upon a measured [OIII]λ4363 intensity, so they are based upon a measured electron temperature. The oxygen abundances cover a wide range, 7.85 dex < 12 + log(O/H) < 9.09 dex, but the mean abundance is surprisingly low, 12 + log(O/H)–8.64 ± 0.32 dex, i.e., roughly half the solar value (Anders & Grevesse 1989). The distribution of oxygen abundances is shown in Figure 1, where the ordinate indicates the number of planetary nebulae with abundances within ±0.1 dex of any point on the x-axis. The dashed line indicates the mean abundance, and the dotted lines indicate the ±1 σ points. The shape of this abundance distribution seems to indicate that the bulge of M31 does not contain a large population of bright, oxygen-rich planetary nebulae. This is a surprising result, for various population synthesis studies (e.g., Bica et al. 1990) have found a mean stellar metallicity approximately 0.2 dex above solar. This 0.5 dex discrepancy leads one to question whether the mean stellar metallicity is as high as the population synthesis results indicate or if such metal-rich stars produce bright planetary nebulae at all. This could be a clue concerning the mechanism responsible for the variation in the number of bright planetary nebulae observed per unit luminosity in different galaxies (e.g., Hui et al. 1993).

scholarly journals A coma-free super-high resolution optical spectrometer using 44 high dispersion sub-gratings

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Hua-Tian Tu ◽  
An-Qing Jiang ◽  
Jian-Ke Chen ◽  
Wei-Jie Lu ◽  
Kai-Yan Zang ◽  
...  
Keyword(s):  
High Resolution ◽  
Spectral Resolution ◽  
Wavelength Region ◽  
Ultra Violet ◽  
High Spectral Resolution ◽  
Visible Range ◽  
High Dispersion ◽  
Charge Coupled Device ◽  
Wide Range ◽  
High Resolution Spectrometer

AbstractUnlike the single grating Czerny–Turner configuration spectrometers, a super-high spectral resolution optical spectrometer with zero coma aberration is first experimentally demonstrated by using a compound integrated diffraction grating module consisting of 44 high dispersion sub-gratings and a two-dimensional backside-illuminated charge-coupled device array photodetector. The demonstrated super-high resolution spectrometer gives 0.005 nm (5 pm) spectral resolution in ultra-violet range and 0.01 nm spectral resolution in the visible range, as well as a uniform efficiency of diffraction in a broad 200 nm to 1000 nm wavelength region. Our new zero-off-axis spectrometer configuration has the unique merit that enables it to be used for a wide range of spectral sensing and measurement applications.

scholarly journals Spectroscopic Studies of Laser-Based Far-Ultraviolet Plasma Light Source

2021 ◽  
Vol 11 (15) ◽  
pp. 6919
Author(s):  
Majid Masnavi ◽  
Martin Richardson
Keyword(s):  
Dense Plasma ◽  
Wavelength Region ◽  
Spectroscopic Studies ◽  
Radiation Hydrodynamics ◽  
Full Width ◽  
Half Maximum ◽  
Laser Plasmas ◽  
Series Of Experiments ◽  
Far Ultraviolet ◽  
Radiation Conversion

A series of experiments is described which were conducted to measure the absolute spectral irradiances of laser plasmas created from metal targets over the wavelength region of 123–164 nm by two separate 1.0 μm lasers, i.e., using 100 Hz, 10 ns, 2–20 kHz, 60–100 ns full-width-at-half-maximum pulses. A maximum radiation conversion efficiency of ≈ 3%/2πsr is measured over a wavelength region from ≈ 125 to 160 nm. A developed collisional-radiative solver and radiation-hydrodynamics simulations in comparison to the spectra detected by the Seya–Namioka-type monochromator reveal the strong broadband experimental radiations which mainly originate from bound–bound transitions of low-ionized charges superimposed on a strong continuum from a dense plasma with an electron temperature of less than 10 eV.

scholarly journals Frequency-Tunable Terahertz Plasmonic Structure Based on the Solid Immersed Method for Sensing

Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1419
Author(s):  
Toshio Sugaya ◽  
Yukio Kawano
Keyword(s):  
Electric Field ◽  
Field Intensity ◽  
Electric Field Intensity ◽  
Wavelength Region ◽  
Diffraction Limit ◽  
Field Analysis ◽  
Plasmonic Structure ◽  
Sensing Applications ◽  
Frequency Tunable ◽  
Bull's Eye

Terahertz waves are located in the frequency band between radio waves and light, and they are being considered for various applications as a light source. Generally, the use of light requires focusing; however, when a terahertz wave is irradiated onto a small detector or a small measurement sample, its wavelength, which is much longer than that of visible light, causes problems. The diffraction limit may make it impossible to focus the terahertz light down to the desired range by using common lenses. The Bull’s Eye structure, which is a plasmonic structure, is a promising tool for focusing the terahertz light beyond the diffraction limit and into the sub-wavelength region. By utilizing the surface plasmon propagation, the electric field intensity and transmission coefficient can be enhanced. In this study, we improved the electric field intensity and light focusing in a small region by adapting the solid immersion method (SIM) from our previous study, which had a frequency-tunable nonconcentric Bull’s Eye structure. Through electromagnetic field analysis, the electric field intensity was confirmed to be approximately 20 times higher than that of the case without the SIM, and the transmission measurements confirmed that the transmission through an aperture had a gap of 1/20 that of the wavelength. This fabricated device can be used in imaging and sensing applications because of the close contact between the transmission aperture and the measurement sample.

scholarly journals Electrically Conductive Networks from Hybrids of Carbon Nanotubes and Graphene Created by Laser Radiation

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1875
Author(s):  
Alexander Yu. Gerasimenko ◽  
Artem V. Kuksin ◽  
Yury P. Shaman ◽  
Evgeny P. Kitsyuk ◽  
Yulia O. Fedorova ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Laser Irradiation ◽  
Flexible Electronics ◽  
Threshold Energy ◽  
Wavelength Region ◽  
Hybrid Nanostructures ◽  
Graphene Sheets ◽  
Electrically Conductive ◽  
Walled Carbon Nanotubes

A technology for the formation of electrically conductive nanostructures from single-walled carbon nanotubes (SWCNT), multi-walled carbon nanotubes (MWCNT), and their hybrids with reduced graphene oxide (rGO) on Si substrate has been developed. Under the action of single pulses of laser irradiation, nanowelding of SWCNT and MWCNT nanotubes with graphene sheets was obtained. Dependences of electromagnetic wave absorption by films of short and long nanotubes with subnanometer and nanometer diameters on wavelength are calculated. It was determined from dependences that absorption maxima of various types of nanotubes are in the wavelength region of about 266 nm. It was found that contact between nanotube and graphene was formed in time up to 400 fs. Formation of networks of SWCNT/MWCNT and their hybrids with rGO at threshold energy densities of 0.3/0.5 J/cm2 is shown. With an increase in energy density above the threshold value, formation of amorphous carbon nanoinclusions on the surface of nanotubes was demonstrated. For all films, except the MWCNT film, an increase in defectiveness after laser irradiation was obtained, which is associated with appearance of C–C bonds with neighboring nanotubes or graphene sheets. CNTs played the role of bridges connecting graphene sheets. Laser-synthesized hybrid nanostructures demonstrated the highest hardness compared to pure nanotubes. Maximum hardness (52.7 GPa) was obtained for MWCNT/rGO topology. Regularity of an increase in electrical conductivity of nanostructures after laser irradiation has been established for films made of all nanomaterials. Hybrid structures of nanotubes and graphene sheets have the highest electrical conductivity compared to networks of pure nanotubes. Maximum electrical conductivity was obtained for MWCNT/rGO hybrid structure (~22.6 kS/m). Networks of nanotubes and CNT/rGO hybrids can be used to form strong electrically conductive interconnections in nanoelectronics, as well as to create components for flexible electronics and bioelectronics, including intelligent wearable devices (IWDs).

scholarly journals Does Green Really Mean Go? Increasing the Fraction of Green Photons Promotes Growth of Tomato but Not Lettuce or Cucumber

Plants ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 637
Author(s):  
Paul Kusuma ◽  
Boston Swan ◽  
Bruce Bugbee
Keyword(s):  
Leaf Area ◽  
Stem Elongation ◽  
Wavelength Region ◽  
Sole Source ◽  
Dry Mass ◽  
Leaf Expansion ◽  
Photon Flux ◽  
Shade Avoidance ◽  
Crop Species ◽  
Blue Region

The photon flux in the green wavelength region is relatively enriched in shade and the photon flux in the blue region is selectively filtered. In sole source lighting environments, increasing the fraction of blue typically decreases stem elongation and leaf expansion, and smaller leaves reduce photon capture and yield. Photons in the green region reverse these blue reductions through the photoreceptor cryptochrome in Arabidopsis thaliana, but studies in other species have not consistently shown the benefits of photons in the green region on leaf expansion and growth. Spectral effects can interact with total photon flux. Here, we report the effect of the fraction of photons in the blue (10 to 30%) and green (0 to 50%) regions at photosynthetic photon flux densities of 200 and 500 µmol m−2 s−1 in lettuce, cucumber and tomato. As expected, increasing the fraction of photons in the blue region consistently decreased leaf area and dry mass. By contrast, large changes in the fraction of photons in the green region had minimal effects on leaf area and dry mass in lettuce and cucumber. Photons in the green region were more potent at a lower fraction of photons in the blue region. Photons in the green region increased stem and petiole length in cucumber and tomato, which is a classic shade avoidance response. These results suggest that high-light crop species might respond to the fraction of photons in the green region with either shade tolerance (leaf expansion) or shade avoidance (stem elongation).

Optical and Mechanical Properties of Aluminum Film Deposited on Glass Substrate

2010 ◽  
Vol 297-301 ◽  
pp. 444-449 ◽  
Author(s):  
Shiuh Chuan Her ◽  
Yi Hsia Wang
Keyword(s):  
Wavelength Region ◽  
Aluminum Film ◽  
Surface Topology ◽  
Aluminum Films ◽  
Glass Substrates ◽  
Atomic Force ◽  
Environmental Test ◽  
Optical Applications ◽  
Optical And Mechanical Properties ◽  
Al Thin Film

The aluminum film with high reflectivity and low absorption in the visible wavelength region has been widely used in optical applications. In this investigation, aluminum films were prepared on glass substrates by electron-beam vapor deposition. The reflectivity of the Al thin film was measured by a Perkin-Elmer Lambda spectrophotometer in the wavelength region of 450-680 nm. The experimental measurements of reflectivity were validated with the numerical results using the Essential Macleod software. The surface topology and microstructure of the film were examined by means of atomic force microscope (AFM). The effects of the temperature and humidity on the reflectivity of the Al film were examined by the environmental test. Nanoindentation tests were employed to determine the hardness and Young’s modulus of the film. The measured hardness of the Al thin films were found to depend on the penetration depth.

Broadband multilayer-coated normal incidence blazed grating with ~10% diffraction efficiency through the 13-16 nm wavelength region

2009 ◽  
Vol 34 (6) ◽  
pp. 818 ◽  
Author(s):  
Lichao Zhang ◽  
Hui Lin ◽  
Chunshui Jin ◽  
Hongjun Zhou ◽  
Tonglin Huo
Keyword(s):  
Diffraction Efficiency ◽  
Wavelength Region ◽  
Normal Incidence ◽  
Blazed Grating

Revised and extended analysis of the 3d10nl configurations in As V, Se VI, and Br VII

1986 ◽  
Vol 64 (3) ◽  
pp. 330-333 ◽  
Author(s):  
Y. N. Joshi ◽  
Th. A. M. Van Kleef
Keyword(s):  
Wavelength Region ◽  
Normal Incidence ◽  
Extended Analysis

The spectra of arsenic, selenium, and bromine were photographed in the wavelength region 450–2000 Å on 6.65- and 3-m normal-incidence spectrographs using a triggered spark source. The new observations have led us to revise and extend the As V, Se VI, and Br VII spectra.

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