IRRADIATION OF ONE MOLAR AQUEOUS CHLORAL HYDRATE SOLUTION WITH Co60-GAMMA-RAYS AND BETATRON X RAYS

1953 ◽  
Vol 31 (12) ◽  
pp. 1164-1172 ◽  
Author(s):  
G. R. Freeman ◽  
A. B. Van Cleave ◽  
J. W. T. Spinks

The production of acid by irradiation of 1 M chloral hydrate solutions is proportional to the dose at a given dose rate. The specific yield is the same for Co60 γ-rays as for 23 Mev. peak energy X rays and is a linear function of the inverse of the square root of the close rate. The reaction is apparently a chain reaction.

1954 ◽  
Vol 32 (3) ◽  
pp. 322-326 ◽  
Author(s):  
G. R. Freeman ◽  
A. B. Van Cleave ◽  
J. W. T. Spinks

When aqueous one molar chloral hydrate solutions are irradiated with X rays or gamma-rays, hydrochloric acid is produced. The reaction appears to be a chain reaction. The average free radical chain lifetime, as determined using a rotating sector, is approximately 0.1 sec.


1954 ◽  
Vol 32 (5) ◽  
pp. 522-531 ◽  
Author(s):  
R. W. Hummel ◽  
A. B. Van Cleave ◽  
J. W. T. Spinks

The production of acid from two commercial brands of chloroform, on exposure to Co60 gamma-rays and high energy X rays from a betatron, has been measured. Inhibitor-free chloroform liberates acid in amounts varying linearly with the radiation dose. The specific yield, in micromoles of acid produced per liter of chloroform per kiloroentgen, varies inversely as the square root of the dose rate. The specific yields are slightly less for betatron radiations, compared with Co60 gamma-rays. The average lifetime of the free radical chains is about one second.


1957 ◽  
Vol 35 (12) ◽  
pp. 1475-1486 ◽  
Author(s):  
R. J. Woods ◽  
J. W. T. Spinks

Aqueous bromal hydrate solutions have been irradiated with Co60 gamma rays and the production of acid measured. The effect of bromal hydrate concentration, dose rate, pH, and temperature upon the yield of acid has been determined. Major products of the radiolysis have been identified and are compared with those formed when aqueous bromal hydrate solutions are treated with Fenton's reagent, a mixture of hydrogen peroxide and ferrous sulphate solutions. It has been shown that Fenton's reagent will initiate a chain reaction in aqueous bromal hydrate solutions which produces hydrobromic acid.


1937 ◽  
Vol 15a (5) ◽  
pp. 67-78 ◽  
Author(s):  
G. C. Laurence

The intensity in roentgens per second of X-rays or γ-rays harder than 0.03 Å may be measured with a small thimble chamber with homogeneous walls of elements below atomic number 13 and thick enough to be impermeable to the fastest secondary β-rays. The ionization current measured under saturation conditions at standard temperature and pressure is divided by BV, and correction is made for the apparent absorption of the X-rays m the walls. V is the volume of the chamber and B is given by[Formula: see text]A table (Table IV) of the values of 2 loge (Zw/Za) for different wall materials is given, and J, K, and L are plotted (Fig. 2) as functions of the quality of the radiation.The absolute intensity of radiation in quanta per square centimetre per second may be obtained from[Formula: see text]in which c is the ionization current per unit volume in the chamber, at standard temperature and pressure, produced by one quantum per square centimetre per second.The intensity of the radiation from one milligram of radium in equilibrium, and covered by platinum of wall thickness t, at one centimetre distance is (8.98 − 1.17 mm.−1 × t) roentgens per hour approximately, it t is not less than 0.3 mm.


1960 ◽  
Vol 38 (12) ◽  
pp. 2315-2318 ◽  
Author(s):  
C. C. Lee ◽  
D. G. Lee

The irradiation of aqueous solutions of ethanol-1-C14, containing about 2% ethanol by weight, with up to 58.0 million rads of Co60 γ-rays led to the formation of up to 0.49% ethanol-2-C14 in the alcohol recovered after irradiation. The G value of this isotope position rearrangement was about 0.04 and amounted to approximately 2% of the G value for the total amount of ethanol decomposed. Possible mechanisms for the rearrangement are discussed.


1953 ◽  
Vol 31 (12) ◽  
pp. 1203-1210 ◽  
Author(s):  
R. W. Hummel ◽  
A. B. Van Cleave ◽  
J. W. T. Spinks

Ceric ions, from ceric ammonium sulphate dissolved in aerated 0.8 N sulphuric acid solution, are reduced by Co60 γ-rays and betatron X-rays of 23 Mev. peak energy. G values were calculated on the basis of calculated electron distributions.


1959 ◽  
Vol 37 (1) ◽  
pp. 79-90 ◽  
Author(s):  
J. W. Sutherland ◽  
J. W. T. Spinks

When tetrachloroethylene is irradiated with Co60 gamma rays in the presence of oxygen or air, the main products are trichloroacetyl chloride, phosgene, and oxalyl chloride. The reaction is a chain reaction. Possible reaction mechanisms are discussed.


2011 ◽  
Vol 7 (S279) ◽  
pp. 274-281 ◽  
Author(s):  
Boaz Katz ◽  
Nir Sapir ◽  
Eli Waxman

AbstractSome of the observed bursts of X-rays/Gamma-rays associated with supernovae (SNe) as well as very luminous SNe may result from the breakout of the SN shock from an optically thick wind surrounding the progenitor. We show that in such scenarios a collisionless shock necessarily forms during the shock breakout. An intense non-thermal flash of ≲1 MeV gamma rays, hard X-rays and multi-TeV neutrinos is produced simultaneously with and following the typical soft X-ray breakout emission, carrying similar or larger energy than the soft emission. The non-thermal flash is detectable by current X-ray telescopes and may be detectable out to 10's of Mpc by km-scale neutrino telescopes.


2021 ◽  
pp. 219-222
Author(s):  
Rubina Rubina ◽  
Baig M.Q ◽  
Kumar Dev

Many years after the discovery of X-ray's and gamma rays. They have been used empirically in medicine, later on realized that this approach was dangerous mainly in radiotherapy and up to some extent in diagnostic radiology. Thus Means of measuring x-ray/γ-rays had to be found in terms of unit of x-rays quantity dened and accepted. The magnitude of the biological effect desirable in case therapy and undesirable in case of diagnosis. It depends upon how much radiation energy is absorbed by irradiated material. X-ray dosimetry is the measurement of energy absorbed in any material particularly in different tissues of the body.


1953 ◽  
Vol 31 (3) ◽  
pp. 250-261 ◽  
Author(s):  
R. W. Hummel ◽  
J. W. T. Spinks

The oxidation of aerated aqueous solutions of ferrousammonium sulphate has been studied using radium gamma rays and X rays of 24.5 Mev. peak energy from a betatron. The behavior at high photon energies has been shown to be closely similar to that at lower photon energies.


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