The quantum-mechanical two-level system with dissipation and feedback: application to nonlinear dielectric response
A power-series expansion for long-time solutions is obtained for the density-matrix equations of motion describing a quantum-mechanical two-level system with dissipation and feedback. The resonances in the first- and third-order dipole contributions and the second-order upper level occupation probability are shown to be significantly affected by the feedback.The results are applied to the case of a uniformly polarized, finite, crystalline dielectric made up of two-level systems. Polarizabilities relating the dipole moment to each of the applied field, the internal field, and the macroscopic field are introduced and relations between them derived. The dipole-moment – macroscopic-field polarizabilities are shown in particular to be shape independent. Susceptibilities are defined and related to the single-system polarizabilities through generalized Clausius–Mossotti relations.