Entrapment of helium ions at (100) and (110) tungsten surfaces

1970 ◽  
Vol 48 (23) ◽  
pp. 2812-2823 ◽  
Author(s):  
E. V. Kornelsen

Two (100) and two (110) tungsten surfaces have been bombarded with helium ions of selected energies between 5 and 2000 eV. The helium thermal desorption spectra obtained when the targets were subsequently heated at 40 °K/s were used to deduce the fraction of the incident particles trapped in the crystal, and their binding energies. For ion energies ≤400 eV, the fractions trapped were small (~ 1 × 10−3 on the (100) surfaces and ~ 1 × 10−2 on the (110) surfaces) and almost all the trapping occurred in surface-related sites with binding energies ≤ 2.1 eV. For ion energies >500 eV, trapping occurred predominantly in sites characteristic of the bulk material, the sites being created by the incoming ions as soon as their energy was sufficient to produce atomic displacements in the lattice (480 eV). At doses <1 × 1013 ions/cm2, four characteristic binding energies were observed: 2.65, 3.05, 3.35, and 4.15 eV. At higher doses, additional binding states were observed with energies up to 5.4 eV.The results suggest that helium diffuses rapidly in tungsten at room temperature and that it is trapped within the crystals only if it encounters lattice defects. Estimates of the ion penetration depth lead to the tentative conclusion that in the annealed crystals (ion energies < 400 eV) the fractional trap concentration is <1 × 10−9 and the helium incident at a few hundred eV energy becomes trapped at depths up to at least 1 μ.

Author(s):  
T. Baird ◽  
J.R. Fryer ◽  
S.T. Galbraith

Introduction Previously we had suggested (l) that the striations observed in the pod shaped crystals of β FeOOH were an artefact of imaging in the electron microscope. Contrary to this adsorption measurements on bulk material had indicated the presence of some porosity and Gallagher (2) had proposed a model structure - based on the hollandite structure - showing the hollandite rods forming the sides of 30Å pores running the length of the crystal. Low resolution electron microscopy by Watson (3) on sectioned crystals embedded in methylmethacrylate had tended to support the existence of such pores.We have applied modern high resolution techniques to the bulk crystals and thin sections of them without confirming these earlier postulatesExperimental β FeOOH was prepared by room temperature hydrolysis of 0.01M solutions of FeCl3.6H2O, The precipitate was washed, dried in air, and embedded in Scandiplast resin. The sections were out on an LKB III Ultramicrotome to a thickness of about 500Å.


This paper describes the measurement of charge transfer cross-sections for protons, molecular hydrogen ions and helium ions in the rare gases and hydrogen, and electron detachment cross-sections for negative atomic hydrogen ions in the rare gases. Part I describes the energy range 3 to 40 keV. In part II the energy range 100 to 4000 eV is described, and the results are discussed in terms of the pseudo-adiabatic hypothesis. Comparisons are made with other experimental results, and anomalous molecular cases are discussed in terms of reactions involving anti-bonding states.


1994 ◽  
Vol 356 ◽  
Author(s):  
K. B. Yoder ◽  
D. S. Stone ◽  
J. C. Lin ◽  
R. A. Hoffmann

AbstractIndentation creep, load relaxation, and rate-change experiments probe room temperature and 80°C creep properties of a 1.3 μm-thick molybdenum film on silicon. The film, with 0.51 GPa compressive stress, 8 GPa hardness and estimated 40 nm grain size, was deposited using steered-arc evaporation at -17V bias. Despite its small grain size and high hardness, the thin film behaves like bulk molybdenum does: the rate sensitivity of the hardness is only weakly-dependent on measurement path (as with bulk material), and activation volumes calculated based on strain rate sensitivity are consistent with those of bulk molybdenum We suspect deformation mechanisms are similar to those in bulk molybdenum under similar conditions.


1970 ◽  
Vol 55 (1) ◽  
pp. 77-88 ◽  
Author(s):  
Saul Winegrad

Radioautography has been used to localize 45Ca in isotopically labeled frog skeletal muscle fibers which had been quickly frozen during a maintained tetanus, a declining tetanus, or during the period immediately following a tetanus or a contracture. During a tetanus almost all of the myofibrillar 45Ca is localized in the region of the sarcomere occupied by the thin filaments. The amount varies with the tension being developed by the muscle. The movement of calcium within the reticulum from the tubular portion to the terminal cisternae during the posttetanic period has a half-time of about 9 sec at room temperature and a Q10 of about 1.7. Repolarization is not necessary for this movement. Evidence is given to support the notion that most calcium efflux from the cell occurs from the terminal cisternae into the transverse tubules.


1998 ◽  
Vol 536 ◽  
Author(s):  
Se-Young Seo ◽  
Jung H. Shin ◽  
Choochon Lee

AbstractThe photoluminescent properties of erbium doped silicon rich silicon oxide (SRSO) is investigated. The silicon content of SRSO was varied from 43 to 33 at. % and Er concentration was 0.4–0.7 at. % in all cases. We observe strong 1.54 μ m luminescence due to 4I13/2⇒4I15/2 Er3+ 4f transition, excited via energy transfer from carrier recombination in silicon nanoclusters to Er 4f shells. The luminescent lifetimes at the room temperature are found to be 4–7 msec, which is longer than that reported from Er in any semiconducting host material, and comparable to that of Er doped SiO2 and A12O3. The dependence of the Er3+ luminescent intensities and lifetimes on temperature, pump power and on background illumination shows that by using SRSO, almost all non-radiative decay paths of excited Er3+ can be effectively suppressed, and that such suppression is more important than increasing excitation rate of Er3+. A planar waveguide using Er doped SRSO is also demonstrated.


2017 ◽  
Vol 373 ◽  
pp. 104-107
Author(s):  
Ling Wang ◽  
Ai Hong Deng ◽  
Kang Wang ◽  
Yong Wang ◽  
Xiao Bo Lu ◽  
...  

W/Cu multilayer nanofilms and pure W nanofilms were prepared in pure Ar and He/Ar mixing atmosphere by radio frequency magnetron sputtering method. The defect evolution of the samples was characterized by Doppler broadening positron annihilation spectroscopy (DB-PAS).The results show that plenty of defects can be produced by introducing helium (He) into W/Cu multilayer nanofilms. With the natural storage time increasing, the helium located in the near surface of W/Cu multilayer nanofilm would be released gradually and induce the coalescence of the helium related defects due to the diffusion of the helium and defects. In addition, the pure W nanofilms were irradiated by 30 keV helium ions and 40 keV hydrogen (H) ions in sequence at room temperature. From the DB-PAS analysis, it can be shown that a large number of vacancy-type defects are produced due to the He and/or H irradiation. H ions would be trapped by He related defects and produced He-H-V complexes.


Author(s):  
Natascha Stroebinger ◽  
Shane M Rutherfurd ◽  
Sharon J Henare ◽  
Paul J Moughan

Abstract Background The quantification of fecal Ca-fatty acid soaps is important to understand how fatty acids behave in the gastrointestinal tract. Objective As current methods to extract Ca-fatty acid soaps from feces give low recoveries an accurate assay to determine the amount of fatty acid soaps in feces was developed. Method Ca-fatty acid soaps are determined indirectly after non-soap fatty acid compounds have been extracted from the feces. Synthetic Ca-fatty acid soaps of different chain lengths (C12–C18) and degree of saturation (C18:0–C18:2) were incubated with several solvents to find the solvents that least-solubilize the Ca-fatty acid soaps. A three-step extraction was devised using extractions with hexane, hexane-isopropanol and water either at room temperature or at 60°C, 37°C, or 80°C, respectively. Feces were spiked with free fatty acids, Ca-fatty acid soaps, Na-fatty acid salts, and phospholipids. Results All of the free fatty acids and phospholipids and almost all of the Na-fatty acid salts were removed and 98% of Ca-lauric acid soap, 99% of Ca-stearic acid soap, and 93% of oleic acid soap were recovered. Conclusions The method is suitable for determining fatty acids in the form of Ca-fatty acid soaps in feces. Highlights New method to determine fecal Ca-fatty acid soaps. Consistent and high recovery of fatty acid-soaps.


2006 ◽  
Vol 914 ◽  
Author(s):  
Hanan Assaf ◽  
E. Ntsoenzok ◽  
M-O. Ruault ◽  
S. Ashok

AbstractThermally-grown 220nm-thick silicon oxide layers were implanted at room temperature with 300keV Xe at doses ranging from 0.5 to 5x1016Xe/cm2. As-implanted samples exhibit bubbles in silicon oxide for all doses. Annealing at T≤400°C results in the disappearance of bubbles from SiO2 layer for the dose of 1x1016Xe/cm2. But for the higher doses of 3.5 and 5x1016Xe/cm2, the bubbles are very stable and remain in the sample even after very high thermal annealing. Capacitance measurements show a strong decrease in the dielectric constant k of the implanted SiO2 sample from 4 (reference sample) to 1.5.


2000 ◽  
Vol 650 ◽  
Author(s):  
A. Meldrum ◽  
K. Beaty ◽  
L. A. Boatner ◽  
C. W. White

ABSTRACTIrradiation-induced amorphization of Cd2Nb2O7 pyrochlore was investigated by means of in-situ temperature-dependent ion-irradiation experiments in a transmission electron microscope, combined with ex-situ ion-implantation (at ambient temperature) and RBS/channeling analysis. The in-situ experiments were performed using Ne or Xe ions with energies of 280 and 1200 keV, respectively. For the bulk implantation experiments, the incident ion energies were 70 keV (Ne+) and 320 keV (Xe2+). The critical amorphization temperature for Cd2Nb2O7 is ∼480 K (280 keV Ne+) or ∼620 K (1200 keV Xe2+). The dose for in-situ amorphization at room temperature is 0.22 dpa for Xe2+, but is 0.65 dpa for Ne+ irradiation. Both types of experiments suggest a cascade overlap mechanism of amorphization. The results were analyzed in light of available models for the crystalline-to-amorphous transformation and were compared to previous ionirradiation experiments on other pyrochlore compositions.


2003 ◽  
Vol 803 ◽  
Author(s):  
Stanford R. Ovshinsky ◽  
Boil Pashmakov

ABSTRACTThis paper describes a basic new scientific and technological approach for information and computing use. It is based on Ovonic cognitive devices that utilize an atomically engineered Ovonic chalcogenide material as the active medium. We demonstrate how such a device possesses many unique functions including an intrinsic neurosynaptic functionality that permits the processing of information in a manner analogous to that of biological neurons and synapses. Our Ovonic cognitive devices can not only accomplish conventional binary computing, but are capable of non-binary generation of information, storage, encryption, higher mathematics, modular arithmetic and factoring. Uniquely, almost all of these functions can be accomplished in a single nanosized device. These devices and systems are robust at room temperature (and above). They are non-volatile and also can include other volatile devices such as the Ovonic Threshold Switch and Ovonic multi-terminal threshold and memory devices that can replace transistors.


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