CANADIAN LINSEED: II. RELATIONS BETWEEN IODINE VALUE AND FATTY ACID COMPOSITION OF LINSEED OIL

1944 ◽  
Vol 22f (5) ◽  
pp. 132-145 ◽  
Author(s):  
H. R. Sallans ◽  
G. D. Sinclair

Analyses were made for non-saponifiable matter, iodine value, thiocyanogen value, and saturated acids on 54 samples of linseed oil from three varieties of flax grown in Saskatchewan. From these data the percentages of oleic, linoleic, and linolenic acids in the oils were computed. Analysis of variance showed that varietal differences exist for all these properties with the exception of non-saponifiable matter, and environmental effects cause significant differences in all properties.Highly significant total correlation coefficients were obtained between iodine value and:—thiocyanogen value, r =.962**; saturated acids, r = −.596**; unsaturated acids, r =.692**; oleic acid, r = −.912**; and linolenic acid, r =.940**. Relations between iodine value and thiocyanogen value, linolenic acid, linoleic acid, and oleic acid proved to be homogeneous with respect to regression coefficients and centroids. From these relations the following prediction equations wrere derived:Thiocyanogen value = 0.44 iodine value + 38.59 (S.e. = 0.63 units);Linolenic acid, % = 0.49 iodine value − 37.93 (S.e. = 0.88%);Linoleic acid, % = 0.055 iodine value + 0.73 (S.e. = 1.80%);Oleic acid, % = −0.48 iodine value + 113.08 (S.e. = 1.06%).** Indicates that the 1% level of significance was attained.

2021 ◽  
Vol 5 (5) ◽  
pp. 01-02
Author(s):  
Hayriye Alp

Flax sed also known as flax oil and linseed oil, is derived from the seeds of the plant Linium usitatissimum. Flax seed oil is a very rich source of alpha-linolenic acid. Alpha-linolenic acid concentration in flaxseed oil ranges from approximately 40 to 60%.lower amounts of linoleic acid and oleic acid (each about 15%) are also present in flaxseed oil.ın addition, flaxseed contains varying amounts of the lignan, secoisolariciresinol diglycoside (SDG).


1944 ◽  
Vol 22f (6) ◽  
pp. 191-198 ◽  
Author(s):  
H. W. Lemon

Linseed oil that has been hydrogenated to a plastic consistency is subject to a type of deterioration termed "flavour reversion" when heated to temperatures used in baking or frying. Investigation of the course of hydrogenation of linseed oil by the spectral method of Mitchell, Kraybill, and Zscheile (11) has indicated that linolenic acid is converted to an isomeric linoleic acid; this acid differs from naturally occurring linoleic acid in that the double bonds are in such positions that diene conjugation is not produced by high-temperature saponification. In a typical hydrogenation, the concentration of the isomeric acid increased to a maximum, at about iodine number 120, of 18% of the total fatty acids, and at iodine number 80, at which point the plasticity was similar to that of a commercial shortening, the concentration of the isomer was 13%. Evidence is presented that the isomeric linoleic acid in partially hydrogenated linseed oil is responsible for the unpleasant flavour that develops when the oil is heated.


1992 ◽  
Vol 285 (2) ◽  
pp. 557-562 ◽  
Author(s):  
T Liang ◽  
S Liao

Human or rat microsomal 5 alpha-reductase activity, as measured by enzymic conversion of testosterone into 5 alpha-dihydrotestosterone or by binding of a competitive inhibitor, [3H]17 beta-NN-diethulcarbamoyl-4-methyl-4-aza-5 alpha-androstan-3-one ([3H]4-MA) to the reductase, is inhibited by low concentrations (less than 10 microM) of certain polyunsaturated fatty acids. The relative inhibitory potencies of unsaturated fatty acids are, in decreasing order: gamma-linolenic acid greater than cis-4,7,10,13,16,19-docosahexaenoic acid = cis-6,9,12,15-octatetraenoic acid = arachidonic acid = alpha-linolenic acid greater than linoleic acid greater than palmitoleic acid greater than oleic acid greater than myristoleic acid. Other unsaturated fatty acids such as undecylenic acid, erucic acid and nervonic acid, are inactive. The methyl esters and alcohol analogues of these compounds, glycerols, phospholipids, saturated fatty acids, retinoids and carotenes were inactive even at 0.2 mM. The results of the binding assay and the enzymic assay correlated well except for elaidic acid and linolelaidic acid, the trans isomers of oleic acid and linoleic acid respectively, which were much less active than their cis isomers in the binding assay but were as potent in the enzymic assay. gamma-Linolenic acid had no effect on the activities of two other rat liver microsomal enzymes: NADH:menadione reductase and glucuronosyl transferase. gamma-Linolenic acid, the most potent inhibitor tested, decreased the Vmax. and increased Km values of substrates, NADPH and testosterone, and promoted dissociation of [3H]4-MA from the microsomal reductase. gamma-Linolenic acid, but not the corresponding saturated fatty acid (stearic acid), inhibited the 5 alpha-reductase activity, but not the 17 beta-dehydrogenase activity, of human prostate cancer cells in culture. These results suggest that unsaturated fatty acids may play an important role in regulating androgen action in target cells.


Author(s):  
Vilcacundo E ◽  
Alvarez M ◽  
Silva M ◽  
Carpio C ◽  
Morales D ◽  
...  

 Objective: The aim of this study was to determine the fatty acids composition in a tocte seeds oil (Juglans neotropica Diels) sample cultivated in Ecuador.Methods: Tocte oil was obtained from tocte seeds using the cold pressing method. Fatty acids analysis was carried out using the gas chromatography method with a mass selective detector (GC/MSD) and using the database Library NIST14.L to identify the compounds.Results: Methyl esters fatty acids were identified from tocte (J. neotropica Diels) walnut using the GC–MS analytical method. The total lipid content of tocte walnuts seeds of plants cultivated in Ecuador was of 49.01% of the total lipid content on fresh weight. Fatty acids were analyzed as methyl esters on a capillary column DB-WAX 122-7062 with a good separation of palmitic acid, stearic acid, oleic acid, linoleic acid, and linolenic acid. The structure of methyl esters fatty acids was determined using the GC–MS. Tocte walnut presents 5.05% of palmitic acid, 2.26% of stearic acid, 19.50% of oleic acid, 65.81% of linoleic acid, and 2.79% linolenic acid of the total content of fatty acids in tocte oil. Fatty acids content reported in this study were similar to the data reported for other walnuts seeds.Conclusions: Tocte seeds are a good source of monounsaturated and polyunsaturated fatty acids. Tocte oil content oleic acid and with a good content of ɷ6 α-linoleic and ɷ3 α-linolenic. Tocte walnut can help reduce risk cardiovascular diseases in Ecuador for their good composition of fatty acids.


2015 ◽  
Vol 6 (9) ◽  
pp. 2930-2938 ◽  
Author(s):  
Jianhui Su ◽  
Hongxin Wang ◽  
Caoyang Ma ◽  
Zaixiang Lou ◽  
Chengxiang Liu ◽  
...  

Peony seed oil rich in α-linolenic acid (38.66%), linoleic acid (26.34%) and oleic acid (23.65%) reduced fasting blood glucose of diabetic mice induced by STZ.


2013 ◽  
Vol 3 (1) ◽  
pp. 32
Author(s):  
Mateus Gonzales Domiciano ◽  
Ailey Aparecida Coelho ◽  
Regiane Da Silva

<p>3D gels are polymeric networks, able to absorb solvents. In this work, starch and PVA gels were developed to act removing oil from water. The oil absorbing capacity can be suitable along with their composition through the synthesis process. Starch and PVA gels were grafted with palmitoleic acid, oleic acid, linoleic acid, linolenic acid, eicosenoic acid, erucic acid and nervonic acid, showing ability to absob up to 50% of weight in oil. When dried or swollen, the gels presented a handling resistance, considered important for using and removal of oil in water.</p><p>&nbsp;</p><p>DOI: http://dx.doi.org/10.14685/rebrapa.v3i1.81</p>


2016 ◽  
Vol 69 (4) ◽  
Author(s):  
Józef Klocek ◽  
Magdalena Szwed ◽  
Danuta Koczkodaj ◽  
Joanna Mitrus ◽  
Marian Saniewski ◽  
...  

The effect of methyl jasmonate (MJ) vapors on the composition and peroxidation of major fatty acids in the organs of common buckwheat seedlings was investigated. The composition of fatty acids in the hypocotyl and cotyledons of seedlings changed significantly under exposure to MJ vapors in closed jars. Four-day exposure to MJ led to a significant reduction in the concentrations of stearic, linoleic, and linolenic acids in the hypocotyl, whereas oleic acid levels increased approximately 3.5-fold. A decrease in stearic acid levels and an increase in the content of linolenic acid were noted in cotyledons, whereas oleic acid levels decreased in roots. Seven-day exposure to MJ vapor caused a further reduction in stearic acid content and an increase in oleic acid and linoleic acid levels in the hypocotyl. At the same time, the linoleic acid content of roots and linolenic acid levels in cotyledons were doubled, but a 5-fold reduction in linolenic acid concentrations was observed in roots. Methyl jasmonate intensified fatty acid peroxidation in cotyledons after 4 and 7 days and in roots after 4 days of exposure. Peroxidation was inhibited in the hypocotyl and roots after 7 days. The noted changes in the composition and peroxidation of fatty acids are probably indicative of senescence in buckwheat seedlings under the influence of MJ. Senescence seems to proceed faster in cotyledons than in other organs of buckwheat seedlings.


HortScience ◽  
2006 ◽  
Vol 41 (4) ◽  
pp. 1082D-1082 ◽  
Author(s):  
Kyoung-Shim Cho ◽  
Hyun-Ju Kim ◽  
Jae-Ho Lee ◽  
Jung-Hoon Kang ◽  
Young-Sang Lee

Fatty acid is known as a physiologically active compound, and its composition in rice may affect human health in countries where rice is the major diet. The fatty acid composition in brown rice of 120 Korean native cultivars was determined by one-step extraction/methylation method and GC. The average composition of 9 detectable fatty acids in tested rice cultivars were as followings: myristic acid; 0.6%, palmitic acid; 21.2%, stearic acid; 1.8%, oleic acid; 36.5%, linoleic acid; 36.3%, linolenic acid; 1.7%, arachidic acid; 0.5%, behenic acid; 0.4%, and lignoceric acid; 0.9%. Major fatty acids were palmitic, oleic and linoleic acid, which composed around 94%. The rice cultivar with the highest linolenic acid was cv. Jonajo (2.1%), and cvs. Pochoenjangmebye and Sandudo showed the highest composition of palmitic (23.4%) and oleic acid (44.8%), respectively. Cultivar Pochuenjangmebye exhitibed the highest composition of saturated fatty acid (28.1%), while cvs. Sandudo and Modo showed the highest mono-unsaturated (44.8%) and poly-unsaturated (42.4%) fatty acid composition, respectively. The oleic acid showed negative correlation with palmitic and linoleic acid, while positive correlation between behenic and lignoceric acids was observed.


1945 ◽  
Vol 23f (2) ◽  
pp. 91-103
Author(s):  
H. R. Sallans ◽  
M. Berenbom ◽  
R. K. Larmour

To determine the importance of bushel weight as a factor in grading, 51 samples of Sunrise and 34 samples of Mennonite seed were examined for associations between bushel weight and other properties of commercial sunflower seed.Highly significant correlations of bushel weight with total oil content of the seed, r =.867**; percentage kernel, r =.740**; percentage oil in the kernel, r =.795**; and percentage nitrogen in the kernels, r = −.467** were obtained. Oil yield, estimated on the basis of a cake containing 5% oil and 10% moisture, was also associated with bushel weight, r =.871**. The correlation coefficients of bushel weight with iodine value, acid value, and refractive index were not significant.The present grade specifications fail to take full advantage of bushel weight as a factor in grading sunflower seed since the levels were set too low to be effective. It is suggested that the levels might well be 30 lb. for No. 1, 26 lb. for No. 2, and 22 lb. for No. 3 instead of 24 lb. for No. 1 and 21 lb. for No. 2 and No. 3. The effects of this change are discussed in relation to grading of the two varieties and the establishment of appropriate price spreads between grades.** Indicates that the 1% level of significance was attained.


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