Liquid-Liquid Equilibrium in the Water-Methyl tert-Butyl Ether-Nitromethane-Ethylene Glycol System

1993 ◽  
Vol 58 (5) ◽  
pp. 983-995
Author(s):  
Vladimír Kubíček ◽  
Josef P. Novák ◽  
Jaroslav Matouš
Keyword(s):  
Ethylene Glycol ◽  
Quaternary System ◽  
Calculated Data ◽  
Ternary Systems ◽  
Methyl Tert Butyl Ether ◽  
Liquid Equilibrium ◽  
Butyl Ether ◽  
Tert Butyl ◽  
Ternary Parameters

The liquid-liquid equilibrium was measured at 20 °C in the title quaternary system and in the three nitromethane-containing ternary subsystems. The data were compared with those predicted by a superposition of the Wilson and Redlich-Kister equations including the ternary parameters. The agreement between the observed and calculated data is very good both for the quaternary system and for the three ternary systems.

Phase Equilibria in the Water-Methyl Alcohol-Methyl tert-Butyl Ether-Ethylene Glycol System

1992 ◽  
Vol 57 (10) ◽  
pp. 2021-2041 ◽  
Author(s):  
Vladimír Kubíček ◽  
Jaroslav Matouš ◽  
Josef P. Novák
Keyword(s):  
Experimental Data ◽  
Ethylene Glycol ◽  
Phase Equilibria ◽  
Methyl Alcohol ◽  
Atmospheric Pressure ◽  
Quaternary System ◽  
Ternary Systems ◽  
Methyl Tert Butyl Ether ◽  
Butyl Ether ◽  
Good Agreement

Liquid-liquid equilibria were measured at 20 °C in the W-MeOH-MTBE-EG quaternary system (W is water, MeOH is methyl alcohol, MTBE is methyl tert-butyl ether, and EG is ethylene glycol) and in the W-MeOH-MTBE, W-MTBE-EG and MeOH-MTBE-EG ternary systems. In the W-MeOH-MTBE-EG, W-MeOH-MTBE, and MeOH-MTBE-EG systems, the vapour-liquid equilibria at atmospheric pressure were also measured. The experimental data of the quaternary system were compared with those modelled by superposition of the Wilson and Redlich-Kister equations with the ternary term, whose parameters were determined based on the corresponding binary and, in some cases, ternary systems. A very good agreement was obtained for both the liquid-liquid and vapour-liquid equilibria.

Excess enthalpies of some (1-propanol + methyl tert-butyl ether + C6-hydrocarbon) ternary systems at 298.15 K

1994 ◽  
Vol 72 (4) ◽  
pp. 1111-1115 ◽  
Author(s):  
Shemin Zhu ◽  
Shubao Shen ◽  
George C. Benson ◽  
Benjamin C.-Y. Lu
Keyword(s):  
Ternary Systems ◽  
Methyl Tert Butyl Ether ◽  
Excess Enthalpies ◽  
Butyl Ether ◽  
Tert Butyl ◽  
Calorimetric Measurements

Calorimetric measurements of excess enthalpies are reported for the three ternary systems (1-propanol + methyl tert-butyl ether + (n-hexane, or 2,3-dimethylbutane, or cyclohexane)) at 298.15 K. Smoothing equations, fitted to the results, were used to construct constant enthalpy contours on a Roozeboom diagram for each of the systems.

Vapour-liquid equilibrium in the methyl tert-butyl ether-n-hexane and methyl tert-butyl ether-toluene systems

1979 ◽  
Vol 44 (12) ◽  
pp. 3627-3631 ◽  
Author(s):  
Jiří Plura ◽  
Jaroslav Matouš ◽  
Josef P. Novák ◽  
Josef Šobr
Keyword(s):  
Methyl Tert Butyl Ether ◽  
Liquid Equilibrium ◽  
Butyl Ether ◽  
Tert Butyl ◽  
Equilibrium Data ◽  
The One ◽  
Kister Equation

Vapour-liquid equilibrium data in binary methyl tert-butyl ether-n-hexane and methyl tert-butyl ether-toluene mixtures were determined experimentally. The data were described thermodynamically by the one-constant Redlich-Kister equation.

Sign in / Sign up

Export Citation Format

Share Document