Prediction of isobaric vapour–liquid equilibrium from excess enthalpies for (methyl tert -butyl ether + alkane(s)) mixtures

2000 ◽  
Vol 32 (2) ◽  
pp. 175-186 ◽  
Author(s):  
Zhaohui Wang ◽  
Benjamin C.-Y. Lu
1994 ◽  
Vol 94 ◽  
pp. 217-226 ◽  
Author(s):  
Shemin Zhu ◽  
Shubao Shen ◽  
George C. Benson ◽  
Benjamin C.-Y. Lu

1994 ◽  
Vol 72 (4) ◽  
pp. 1111-1115 ◽  
Author(s):  
Shemin Zhu ◽  
Shubao Shen ◽  
George C. Benson ◽  
Benjamin C.-Y. Lu

Calorimetric measurements of excess enthalpies are reported for the three ternary systems (1-propanol + methyl tert-butyl ether + (n-hexane, or 2,3-dimethylbutane, or cyclohexane)) at 298.15 K. Smoothing equations, fitted to the results, were used to construct constant enthalpy contours on a Roozeboom diagram for each of the systems.


1979 ◽  
Vol 44 (12) ◽  
pp. 3627-3631 ◽  
Author(s):  
Jiří Plura ◽  
Jaroslav Matouš ◽  
Josef P. Novák ◽  
Josef Šobr

Vapour-liquid equilibrium data in binary methyl tert-butyl ether-n-hexane and methyl tert-butyl ether-toluene mixtures were determined experimentally. The data were described thermodynamically by the one-constant Redlich-Kister equation.


1997 ◽  
Vol 75 (3) ◽  
pp. 308-313 ◽  
Author(s):  
Zhangfa Tong ◽  
Dankui Liao ◽  
George C. Benson ◽  
Benjamin C. Y. Lu

Excess molar enthalpies, measured at 298.15 K, are reported for the two ternary systems consisting of either n-heptane or n-decane, together with methyl tert-butyl ether and di-n-butyl ether. Smooth representations of the results were used to construct constant enthalpy contours on Roozeboom diagrams. It was found that the Flory theory can provide good estimates of the ternary enthalpies. Keywords: excess enthalpies, ternary mixtures, n-alkanes, ethers, Flory theory.


1993 ◽  
Vol 58 (5) ◽  
pp. 983-995
Author(s):  
Vladimír Kubíček ◽  
Josef P. Novák ◽  
Jaroslav Matouš

The liquid-liquid equilibrium was measured at 20 °C in the title quaternary system and in the three nitromethane-containing ternary subsystems. The data were compared with those predicted by a superposition of the Wilson and Redlich-Kister equations including the ternary parameters. The agreement between the observed and calculated data is very good both for the quaternary system and for the three ternary systems.


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