Influence of Partial Blocking of the Electrode Surface on the Transfer Coefficients

1993 ◽  
Vol 58 (3) ◽  
pp. 496-505
Author(s):  
Ondřej Wein
Keyword(s):  
Surface Activity ◽  
Elliptic Problem ◽  
Electrode Surface ◽  
Driving Force ◽  
Two Dimensional ◽  
Transfer Coefficients ◽  
Constant Potential ◽  
Numeric Solution ◽  
Active Zones ◽  
Partial Blocking

Partial blocking of the transport surface under the stagnant (nerst) layer is simulated by periodically alternating bands of perfectly insulating zones and active zones with a constant potential of driving force. The numeric solution of the corresponding two-dimensional elliptic problem is represented by a simple empirical correlation for the transfer coefficients. The result is interpreted in terms of a simple electrochemical problem about limiting diffusion currents at electrodes with non-uniform surface activity.

Mono-6-thio-β-cyclodextrin-functionalized AuNP/two-dimensional TiO2 nanosheet nanocomposite for the electrochemical determination of trace methyl parathion in water

2019 ◽  
Vol 11 (37) ◽  
pp. 4751-4760 ◽  
Author(s):  
Xu-Cheng Fu ◽  
Chao Zhang ◽  
Xuan-Hua Li ◽  
Jian Zhang ◽  
Gan Wei
Keyword(s):  
Electrode Surface ◽  
Methyl Parathion ◽  
Au Nanoparticles ◽  
Electrochemical Determination ◽  
Two Dimensional

In this work, two-dimensional TiO2 nanosheets material composited with Au nanoparticles and mono-6-thio-β-cyclodextrin was prepared on electrode surface (SH-β-CD/AuNPs/TiO2NSs/GCE).

scholarly journals Large band offset as driving force of two-dimensional electron confinement: The case of SrTiO3/SrZrO3interface

2013 ◽  
Vol 88 (11) ◽  
Author(s):  
P. Delugas ◽  
A. Filippetti ◽  
A. Gadaleta ◽  
I. Pallecchi ◽  
D. Marré ◽  
...  
Keyword(s):  
Driving Force ◽  
Band Offset ◽  
Two Dimensional ◽  
Dimensional Electron ◽  
Electron Confinement

scholarly journals The Superposition Approach to Local Heat Transfer Coefficients in High Density Ratio Film Cooling Flows

1999 ◽  
Author(s):  
Michael Gritsch ◽  
Stefan Baldauf ◽  
Moritz Martiny ◽  
Achmed Schulz ◽  
Sigmar Wittig
Keyword(s):  
Heat Transfer ◽  
Heat Transfer Coefficient ◽  
Film Cooling ◽  
Density Ratio ◽  
Two Dimensional ◽  
Transfer Coefficients ◽  
Cooling Flows ◽  
Heat Transfer Coefficients ◽  
High Density Ratio ◽  
The Heat Transfer Coefficient

The present paper reports on the use of the superposition approach in high density ratio film cooling flows. It arises from the linearity and homogeneity of the simplified boundary layer differential equations. However, it is widely assumed that the linearity does not hold for variable property flows. Therefore, theoretical considerations and numerical calculations will demonstrate the linearity of the heat transfer coefficient with the dimensionless coolant temperature θ as long as identical flow conditions are applied. This makes it necessary to perform at least two experiments at different θ but with the coolant to main flow temperature ratio kept unchanged. A comprehensive set of experiments is presented to demonstrate the capability of the superposition approach for determining heat transfer coefficients for different film cooling geometries. These comprise coolant injection from two dimensional tangential slots, single holes, and rows of cylindrical holes. Particularly, two dimensional local distributions of the heat transfer coefficient will be addressed.

Heat Transfer Characteristics of Impinging Two-Dimensional Air Jets

1966 ◽  
Vol 88 (1) ◽  
pp. 101-107 ◽  
Author(s):  
Robert Gardon ◽  
J. Cahit Akfirat
Keyword(s):  
Heat Transfer ◽  
Flat Plate ◽  
Two Dimensional ◽  
Heat Transfer Characteristics ◽  
Transfer Coefficients ◽  
Average Heat ◽  
Heat Transfer Coefficients ◽  
Transfer Characteristics ◽  
Air Jets

Local as well as average heat transfer coefficients between an isothermal flat plate and impinging two-dimensional jets were measured for both single jets and arrays of jets. For a large and technologically important range of variables the results have been correlated in relatively simple terms, and their application to design is briefly considered.

scholarly journals Two-dimensional heat transfer coefficients with simultaneous flow visualisations during two-phase flow boiling in a PDMS microchannel

2018 ◽  
Vol 130 ◽  
pp. 624-636 ◽  
Author(s):  
Sofia Korniliou ◽  
Coinneach Mackenzie-Dover ◽  
John R.E. Christy ◽  
Souad Harmand ◽  
Anthony J. Walton ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Two Phase Flow ◽  
Flow Boiling ◽  
Phase Flow ◽  
Two Dimensional ◽  
Transfer Coefficients ◽  
Two Phase ◽  
Heat Transfer Coefficients ◽  
Pdms Microchannel

Topological rearrangements and flow simulation of dry ordered foams

2014 ◽  
Vol 05 (supp01) ◽  
pp. 1441007 ◽  
Author(s):  
J. S. Espinoza Ortiz ◽  
H. Belich ◽  
M. T. D. Orlando ◽  
R. E. Lagos
Keyword(s):  
Strain Rate ◽  
Critical Behavior ◽  
Potts Model ◽  
Driving Force ◽  
Flow Simulation ◽  
Two Dimensional ◽  
Fluid Regime ◽  
Cellular Potts Model ◽  
Flow Through ◽  
Liquid Foam

Flow through a narrow bent channel may induce topological rearrangements in a two-dimensional monodispersed dry liquid foam. We use the Cellular Potts Model to simulate a foam under a variable driving force in order to investigate the strain-rate response from these rearrangements. We observe a set of foams' behaviors ranging from elastic, viscoelastic to fluid regime. Bubble's topological rearrangements are localized and their cumulative rearrangements change linearly with time, thus nonavalanches critical behavior is found. The strain-rate affects the rate of topological rearrangements, its dependence on the drag force is nonlinear, obeying a Herschel–Bulkley-like relationship below the foam's flow point.

Interaction Between Dislocations and Misfit Interface

2000 ◽  
Vol 634 ◽  
Author(s):  
A. Kuronen ◽  
K. Kaski ◽  
L. F. Perondi ◽  
J. Rintala
Keyword(s):  
Molecular Dynamics ◽  
Molecular Dynamics Simulations ◽  
Misfit Dislocation ◽  
Driving Force ◽  
Two Dimensional ◽  
Lennard Jones ◽  
Dynamics Simulations ◽  
Nucleation Of Dislocations

ABSTRACTMechanisms responsible for the formation of a misfit dislocation in a lattice-mismatched system have been studied using Molecular Dynamics simulations of a two-dimensional Lennard-Jones system. Results show clearly how the strain due to the lattice-mismatched interface acts as a driving force for migration of dislocations in the substrate and the overlayer and nucleation of dislocations in the overlayer edges. Moreover, we observe dislocation reactions in which the gliding planes of dislocations change such that they can migrate to the interface.

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