An estimate of limiting values of relative volatility with help of the theorem of corresponding states. II. Binary systems of tetrachloromethane, benzene, and cyclohexane

1963 ◽  
Vol 28 (7) ◽  
pp. 1771-1779 ◽  
Author(s):  
T. Boublík
Keyword(s):  
Binary Systems ◽  
Corresponding States ◽  
Relative Volatility ◽  
Limiting Values

Effect of Errors in Temperature Measurement on the Accuracy of Composition of the Liquid-Vapour Phases and Their Impact on the Calculated Number of Theoretical Stages of Rectification Columns

1992 ◽  
Vol 57 (9) ◽  
pp. 1867-1878
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Phase Composition ◽  
Binary Systems ◽  
Equilibrium Temperature ◽  
Systematic Errors ◽  
Operating Conditions ◽  
Rectification Column ◽  
Relative Volatility ◽  
The Impact ◽  
Calculated Number

The effect of random and systematic errors in the determination of the equilibrium temperature on the phase composition in isobaric L-G equilibria was simulated on five binary systems with different size and relative volatility. The impact of the inaccuracies on the calculated number of theoretical stages of a continuously operating rectification column is discussed with respect to the different operating conditions of the separatory process.

scholarly journals Discussion of Observations of the Flow of Matter Within Binary Systems

1973 ◽  
Vol 51 ◽  
pp. 1-21
Author(s):  
Alan H. Batten
Keyword(s):  
Hot Spots ◽  
Total Mass ◽  
Binary Systems ◽  
Empirical Relation ◽  
Circumstellar Matter ◽  
Theoretical Treatment ◽  
Flare Activity ◽  
The Stability ◽  
Limiting Values ◽  
Very High

Observational determinations of density, dimensions, temperatures, and velocities of circumstellar features are surveyed and discussed, with a view to establishing limiting values that could be useful in any theoretical treatment of circumstellar structure. Densities of the order of 1013 particles cm-3 are found for streams and disks, although there is evidence for regions of much lower density in many systems, and some systems may have much denser circumstellar matter.Dimensions of disks seem to be remarkably constant (fractional radius ∼ 0.3) in a wide variety of systems. The total mass of circumstellar matter is always a small fraction of the mass of the system. Temperatures are usually similar to the temperatures of the stars in the system, although hot spots certainly exist in some systems, and ‘flare’ activity is evidence of localized very high temperatures. On the other hand, some systems may contain solid circumstellar matter. Observed velocities are usually several hundred km s-1. The empirical relation between the velocity of rotation of disks and the orbital period is described. Finally, the stability of these features is briefly discussed.

Use of the Law of Corresponding States for the evaluation of surface properties of pure compounds and binary systems

2007 ◽  
Vol 262 (1-2) ◽  
pp. 87-96 ◽  
Author(s):  
Aly J. Castellanos ◽  
Jhoan Toro-Mendoza ◽  
Germán Urbina-Villalba ◽  
Máximo García-Sucre
Keyword(s):  
Surface Properties ◽  
Binary Systems ◽  
Corresponding States ◽  
Pure Compounds ◽  
Law Of Corresponding States ◽  
The Law

Effect of Random Errors and Bias of Isobaric Equilibrium x, y and t Data of LiquidVapour Binary Systemson the Calculated Number of Theoretical Plates of a Rectification Column

1994 ◽  
Vol 59 (4) ◽  
pp. 841-854
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Phase Composition ◽  
Binary Systems ◽  
Random Errors ◽  
Rectification Column ◽  
Relative Volatility ◽  
Composition Data ◽  
Calculated Number ◽  
Theoretical Plates

The effect of random errors and bias of temperature and phase composition data in the isobaric L-G equilibrium on the calculated number of theoretical plates of a continuously working rectification column at various reflux ratios was investigated. Five model binary systems exhibiting different behaviour and relative volatility were used.

Some Results of the Spectroscopic Study of Four Close Binary Systems of Early Spectral Types

1965 ◽  
Vol 5 ◽  
pp. 120-130
Author(s):  
T. S. Galkina
Keyword(s):  
Spectroscopic Study ◽  
Spectral Type ◽  
Spectroscopic Investigation ◽  
Binary Systems ◽  
Quantitative Information ◽  
Close Binary ◽  
Physical Parameters ◽  
Absorption And Emission ◽  
Close Binary Systems ◽  
Quantitative Estimates

It is necessary to have quantitative estimates of the intensity of lines (both absorption and emission) to obtain the physical parameters of the atmosphere of components.Some years ago at the Crimean observatory we began the spectroscopic investigation of close binary systems of the early spectral type with components WR, Of, O, B to try and obtain more quantitative information from the study of the spectra of the components.

Quasi-Periodic Oscillations in Dwarf Novae

1979 ◽  
Vol 46 ◽  
pp. 77-88
Author(s):  
Edward L. Robinson
Keyword(s):  
Binary Systems ◽  
Outer Edge ◽  
Light Curves ◽  
Close Binary ◽  
Bright Spot ◽  
Dwarf Novae ◽  
Periodic Oscillations ◽  
High Frequencies ◽  
Short Period ◽  
Typical Time

Three distinct kinds of rapid variations have been detected in the light curves of dwarf novae: rapid flickering, short period coherent oscillations, and quasi-periodic oscillations. The rapid flickering is seen in the light curves of most, if not all, dwarf novae, and is especially apparent during minimum light between eruptions. The flickering has a typical time scale of a few minutes or less and a typical amplitude of about .1 mag. The flickering is completely random and unpredictable; the power spectrum of flickering shows only a slow decrease from low to high frequencies. The observations of U Gem by Warner and Nather (1971) showed conclusively that most of the flickering is produced by variations in the luminosity of the bright spot near the outer edge of the accretion disk around the white dwarf in these close binary systems.

Bence-albee after 25 years: A new superior α-factor correction procedure for the quantitative analysis of oxides and silicates

1992 ◽  
Vol 50 (2) ◽  
pp. 1744-1745
Author(s):  
John T. Armstrong
Keyword(s):  
Quantitative Analysis ◽  
Electron Microprobe ◽  
Binary Systems ◽  
Correction Procedure ◽  
Geological Samples ◽  
The Past ◽  
Large Matrix ◽  
Computational Speed ◽  
Microprobe Data ◽  
Geological Sciences

One of the most cited papers in the geological sciences has been that of Albee and Bence on the use of empirical " α -factors" to correct quantitative electron microprobe data. During the past 25 years this method has remained the most commonly used correction for geological samples, despite the facts that few investigators have actually determined empirical α-factors, but instead employ tables of calculated α-factors using one of the conventional "ZAF" correction programs; a number of investigators have shown that the assumption that an α-factor is constant in binary systems where there are large matrix corrections is incorrect (e.g, 2-3); and the procedure’s desirability in terms of program size and computational speed is much less important today because of developments in computing capabilities. The question thus exists whether it is time to honorably retire the Bence-Albee procedure and turn to more modern, robust correction methods. This paper proposes that, although it is perhaps time to retire the original Bence-Albee procedure, it should be replaced by a similar method based on compositiondependent polynomial α-factor expressions.

Fractionation of polymethylene chains: An electron crystallographic investigation

1986 ◽  
Vol 44 ◽  
pp. 794-795
Author(s):  
Douglas L. Dorset
Keyword(s):  
Cross Section ◽  
Binary Systems ◽  
Linear Chain ◽  
Pure Component ◽  
Organic Substrates ◽  
Crystallographic Investigation ◽  
X Ray Diffraction ◽  
X Ray ◽  
Molecular Sizes ◽  
The Stability

A variety of linear chain materials exist as polydisperse systems which are difficultly purified. The stability of continuous binary solid solutions assume that the Gibbs free energy of the solution is lower than that of either crystal component, a condition which includes such factors as relative molecular sizes and shapes and perhaps the symmetry of the pure component crystal structures.Although extensive studies of n-alkane miscibility have been carried out via powder X-ray diffraction of bulk samples we have begun to examine binary systems as single crystals, taking advantage of the well-known enhanced scattering cross section of matter for electrons and also the favorable projection of a paraffin crystal structure posited by epitaxial crystallization of such samples on organic substrates such as benzoic acid.

Sign in / Sign up

Export Citation Format

Share Document