Effect of Errors in Temperature Measurement on the Accuracy of Composition of the Liquid-Vapour Phases and Their Impact on the Calculated Number of Theoretical Stages of Rectification Columns

1992 ◽  
Vol 57 (9) ◽  
pp. 1867-1878
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Phase Composition ◽  
Binary Systems ◽  
Equilibrium Temperature ◽  
Systematic Errors ◽  
Operating Conditions ◽  
Rectification Column ◽  
Relative Volatility ◽  
The Impact ◽  
Calculated Number

The effect of random and systematic errors in the determination of the equilibrium temperature on the phase composition in isobaric L-G equilibria was simulated on five binary systems with different size and relative volatility. The impact of the inaccuracies on the calculated number of theoretical stages of a continuously operating rectification column is discussed with respect to the different operating conditions of the separatory process.

A Simulated Experiment for Examining the Effect of Errors in the Composition of the Equilibrium Liquid-Vapour Phases on the Calculated Number of Theoretical Stages of a Rectification Column

1993 ◽  
Vol 58 (3) ◽  
pp. 506-516
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Phase Composition ◽  
Binary Systems ◽  
Equilibrium Phase ◽  
Operating Conditions ◽  
Random Errors ◽  
Rectification Column ◽  
Simulated Experiment ◽  
Equilibrium Phase Composition ◽  
Calculated Number

Five model binary systems differing in the relative volatilities and their changes were used to simulate the effect of random errors and bias in the L-G equilibrium phase composition on the calculation of the number of theoretical stages of a continuously working rectification column in various operating conditions.

Effect of Random Errors and Bias of Isobaric Equilibrium x, y and t Data of LiquidVapour Binary Systemson the Calculated Number of Theoretical Plates of a Rectification Column

1994 ◽  
Vol 59 (4) ◽  
pp. 841-854
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Phase Composition ◽  
Binary Systems ◽  
Random Errors ◽  
Rectification Column ◽  
Relative Volatility ◽  
Composition Data ◽  
Calculated Number ◽  
Theoretical Plates

The effect of random errors and bias of temperature and phase composition data in the isobaric L-G equilibrium on the calculated number of theoretical plates of a continuously working rectification column at various reflux ratios was investigated. Five model binary systems exhibiting different behaviour and relative volatility were used.

Systematic errors in equilibrium composition of ternary liquid-liquid systems and their effect on the calculated number of theoretical stages of countercurrent extraction

1988 ◽  
Vol 53 (6) ◽  
pp. 1172-1180
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Equilibrium Composition ◽  
Systematic Errors ◽  
Liquid Equilibrium ◽  
Countercurrent Extraction ◽  
Liquid Systems ◽  
Equilibrium Concentrations ◽  
Line Slope ◽  
Tie Line ◽  
Calculated Number

The influence of magnitude of systematic errors in the determination of ternary liquid-liquid equilibrium concentrations on the accuracy of the calculated number of theoretical stages of countercurrent extraction is evaluated on using five hypothetical systems differing in the extent of mutual solubility of components, tie-line slope, and type of binodal curve.

The effect of systematic errors of the equilibrium distribution concentrations on the number of stages of countercurrent extraction with various consumption of extractant

1989 ◽  
Vol 54 (4) ◽  
pp. 981-989
Author(s):  
Ján Dojčanský ◽  
Soňa Bafrncová ◽  
Július Surový
Keyword(s):  
Equilibrium Distribution ◽  
Systematic Errors ◽  
Mutual Solubility ◽  
Operating Conditions ◽  
Liquid Equilibrium ◽  
Countercurrent Extraction ◽  
Absolute Deviation ◽  
Line Slope ◽  
Tie Line ◽  
Calculated Number

On using five hypothetical systems differing in the extent of mutual solubility of components, tie-line slope, and type of binodal curve, the effect is evaluated of systematic errors in the form of absolute deviation in the liquid-liquid equilibrium distribution concentrations on the accuracy of calculated number of theoretical stages of isothermal countercurrent extraction under various operating conditions.

Dynamic Analysis of Mechanical Systems With Clearances—Part 1: Formation of Dynamic Model

1971 ◽  
Vol 93 (1) ◽  
pp. 305-309 ◽  
Author(s):  
S. Dubowsky ◽  
F. Freudenstein
Keyword(s):  
Equations Of Motion ◽  
Operating Conditions ◽  
Coupled Systems ◽  
Dynamical Response ◽  
Dynamic Force ◽  
Dynamical Equations ◽  
Mechanical Joint ◽  
The Impact ◽  
Insight Into

A mathematical model of an elastic mechanical joint with clearances has been formulated and the dynamical equations of motion derived (Part I). The model, which we have called an Impact Pair, is basic to the determination of the dynamical response of mechanical and electromechanical systems with clearances, including determination of dynamic force amplification, frequency response, time-displacement characteristics, and other dynamic characteristics. Whenever possible, the results for the impact pair under various operating conditions are illustrated by graphs, which may also offer some insight into the behavior of clearance-coupled systems.

scholarly journals New Mixed Y0.5R0.5VO4 and RVO4:Bi Materials: Synthesis, Crystal Structure and Some Luminescence Properties

Inorganics ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 94 ◽  
Author(s):  
Leonid Vasylechko ◽  
Andrii Tupys ◽  
Vasyl Hreb ◽  
Volodymyr Tsiumra ◽  
Iryna Lutsiuk ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Binary Systems ◽  
Materials Synthesis ◽  
Lattice Constants ◽  
Cation Radius ◽  
Photoluminescence Studies ◽  
The Impact ◽  
Structure And Microstructure ◽  
Cell Volumes

The results are reported on a precise crystal structure and microstructure determination of new mixed YVO4-based orthovanadates of Y0.5R0.5VO4 (R = Sm, Tb, Dy, Ho, Tm, Yb, Lu) as well as some Bi3+-doped RVO4 (R = La, Gd, Y, Lu) nano- (submicro-) materials. The formation of continuous solid solutions in the YVO4–RVO4 pseudo-binary systems (R = Sm, Tb, Dy, Ho, Tm, Yb, Lu) has been proved. The lattice constants and unit cell volumes of the new mixed orthovanadates were analyzed as a function of R3+ cation radius. The impact of crystal structure parameters on the energy band gap of the materials was studied by means of photoluminescence studies of the Bi3+-doped compounds.

scholarly journals Synthesis of polar copolymers by the process of emulsion via free radicals (FRP)

2019 ◽  
pp. 1-5
Author(s):  
Luis Mario Magaña-Maldonado ◽  
David Contreras-López
Keyword(s):  
Free Radicals ◽  
Batch Reactor ◽  
Operating Conditions ◽  
Polymerization Process ◽  
Optimal Operating ◽  
Molecular Weights ◽  
Polymer Industry ◽  
The Impact ◽  
Vinyl Propionate

At present, the polymer industry has gained increasing importance due to the versatility of its properties, as well as the impact they have on the environment. The present investigation provides the determination of optimal operating conditions for the polymerization of styrene and vinyl propionate in a Batch reactor, as well as the copolymerization of styrene with propionate monomers by the process of emulsion via free radicals, allowing to observe the variations with respect to Reaction yields and molecular weights. Another important factor is the activation of the initiator so that the polymerization process begins within each of the micelles. Likewise, it was found that, in the copolymerizations, there are considerable variations with respect to reaction yields and molecular weights as the concentrations are modified. In addition, it was found that there are higher yields in styrene polymerizations per solution than emulsion.

Replacement of MEG with KHI for Hydrate Control in Subsea Flowline Offshore Myanmar

2021 ◽  
Author(s):  
Jonghyun Kim ◽  
Paolo Scalea ◽  
Chulhwan Hwang ◽  
Jeongmoon Kim
Keyword(s):  
Selection Process ◽  
Field Tests ◽  
Equilibrium Temperature ◽  
Field Application ◽  
Operating Conditions ◽  
Field Conditions ◽  
Gas Industry ◽  
Promising Alternative ◽  
Selection Of

Abstract Objectives/Scope This paper describes the successful replacement of Mono Ethylene Glycol (MEG) by Kinetic Hydrate Inhibitor (KHI) to guarantee flow assurance in the Shwe field subsea production system, offshore Myanmar. It covers the initial difficulties experienced with MEG, specific field conditions, the comprehensive KHI selection process and testing up to field application and operation. Methods, Procedures, Process MEG used for hydrate inhibition in the field's subsea flowline was originally regenerated in the topside facility, however contamination of the MEG with salts from formation water was causing process upsets. The option of installing a reclamation package presented many challenges and, after review of field conditions, the application of a KHI was considered as a promising alternative to MEG. With the engagement of specialist chemical suppliers a broad and challenging series of laboratory, as well as field tests, was carried out to select a suitable product. Finally a dedicated permanent injection skid was installed to guarantee stable KHI delivery and production. Results, Observations, Conclusions The difficulties caused by salt contamination of the MEG system, combined with the intricate field logistics at the remote site offshore Myanmar, entailed a speedy solution. This combined with suitable operating parameters of the field; i.e. low water content, high wellhead flowing temperatures, subcooling within known KHI operating range, ensured KHI was an economical solution. Nevertheless from desktop study to successful field application a series hurdles had to be crossed, including performance and compatibility tests, simulating all the expected Shwe Offshore Platform (SHP) operating conditions: Determination of Hydrate Equilibrium Temperature (HET); Induction Time Autoclave test for the required residence time in the presence of Corrosion Inhibitor (CI); Hot Injection ests at wellhead operating temperature; Thermal stability tests for topsides and condensate disposal system; Umbilical material compatibility tests; Compatibility of KHI with incumbent products (MEG and CI). Testing of a range of products, carried out by specialist chemical supplier, resulted in the selection of a qualified product, followed by a successful field application testing programme. Seven years after its introduction, KHI has helped achieve optimum field uptime and reduced operational costs as well as eased logistics constraints. Novel/Additive Information KHI is not new to the Oil & Gas industry, however information on its selection and application is not widely available. This paper sheds light on the steps to be considered when evaluating KHI as a suitable hydrate inhibitor, as well as the detailed laboratory tests for proper selection of a product. The intent is to help operators who are facing challenges with hydrate inhibition and could revert to KHI as an alternative.

Dynamic Analysis of Mechanical Systems With Clearances—Part 2: Dynamic Response

1971 ◽  
Vol 93 (1) ◽  
pp. 310-316 ◽  
Author(s):  
S. Dubowsky ◽  
F. Freudenstein
Keyword(s):  
Control Theory ◽  
Dynamic Response ◽  
Dynamic Analysis ◽  
Mechanical Systems ◽  
Operating Conditions ◽  
Approximate Methods ◽  
Simulation Techniques ◽  
The Impact

The theory developed in Part I has been applied to the determination of the dynamic response of the Impact Pair under various operating conditions. Simulation techniques, as well as approximate methods used in control theory, have been used for this purpose.

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