Solvent-Free Oxidation of Primary Carbon-Hydrogen Bonds in Toluene Using Au-Pd Alloy Nanoparticles

Science ◽  
2011 ◽  
Vol 331 (6014) ◽  
pp. 195-199 ◽  
Author(s):  
L. Kesavan ◽  
R. Tiruvalam ◽  
M. H. A. Rahim ◽  
M. I. bin Saiman ◽  
D. I. Enache ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Solvent Free ◽  
Alloy Nanoparticles ◽  
Pd Alloy ◽  
Carbon Hydrogen Bonds ◽  
Free Oxidation

Confinement of Au3+-Rich Clusters by Silicalite-1 for Selective Solvent-Free Oxidation of Toluene

2021 ◽  
Author(s):  
He Huang ◽  
Wanyue Ye ◽  
Caicheng Song ◽  
Yingcen Liu ◽  
Xiaotong Zhang ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Selective Oxidation ◽  
Solvent Free ◽  
Selective Solvent ◽  
Methyl Group ◽  
Carbon Hydrogen Bonds ◽  
Free Oxidation

Selective oxidation of the primary carbon-hydrogen bonds in the methyl group of toluene to corresponding oxygenates is of immense significance. This transformation, however, remains challenging and often requires either extensive...

Metal-free oxidation of aromatic carbon–hydrogen bonds through a reverse-rebound mechanism

Nature ◽  
2013 ◽  
Vol 499 (7457) ◽  
pp. 192-196 ◽  
Author(s):  
Changxia Yuan ◽  
Yong Liang ◽  
Taylor Hernandez ◽  
Adrian Berriochoa ◽  
Kendall N. Houk ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Aromatic Carbon ◽  
Metal Free ◽  
Carbon Hydrogen Bonds ◽  
Free Oxidation

scholarly journals Coordinately unsaturated O2c–Ti5c–O2c sites promote the reactivity of Pt/TiO2 catalysts in the solvent-free oxidation of octanol

2021 ◽  
Author(s):  
Pengfei Yang ◽  
Mark Douthwaite ◽  
Jiahao Pan ◽  
Lirong Zheng ◽  
Song Hong ◽  
...  
Keyword(s):  
Solvent Free ◽  
Tio2 Anatase ◽  
Free Oxidation

A series of TiO2 anatase materials were synthesized with varying proportions of exposed (101) and (001) facets. Pt was subsequently impregnated onto these materials, which were then exposed to either...

scholarly journals Efficient Solvent-free Oxidation of Benzylic and Aromatic Allylic Alcohols and Biaryl Acyloins by Manganese Dioxide and Barium Manganate

1999 ◽  
Vol 23 (3) ◽  
pp. 236-237
Author(s):  
Habib Firouzabadi ◽  
Babak Karimi ◽  
Mohammad Abbassi
Keyword(s):  
Manganese Dioxide ◽  
Solvent Free ◽  
Allylic Alcohols ◽  
Solvent Free Conditions ◽  
Free Oxidation

Active manganese dioxide and commercially available barium manganate are used for the efficient oxidation of benzylic and aromatic allylic alcohols and biaryl acyloins under solvent-free conditions.

ChemInform Abstract: Solvent-Free Oxidation of Benzoins Using Fe(NO3)3×9H2O as the Oxidant.

ChemInform ◽  
2010 ◽  
Vol 32 (39) ◽  
pp. no-no
Author(s):  
Yue-Wei Zhao ◽  
Yu-Lu Wang
Keyword(s):  
Solvent Free ◽  
Free Oxidation

scholarly journals Switching-off toluene formation in the solvent-free oxidation of benzyl alcohol using supported trimetallic Au–Pd–Pt nanoparticles

2013 ◽  
Vol 162 ◽  
pp. 365 ◽  
Author(s):  
Qian He ◽  
Peter J. Miedziak ◽  
Lokesh Kesavan ◽  
Nikolaos Dimitratos ◽  
Meenakshisundaram Sankar ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Pt Nanoparticles ◽  
Solvent Free ◽  
Oxidation Of Benzyl Alcohol ◽  
Free Oxidation
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