Metal-free oxidation of aromatic carbon–hydrogen bonds through a reverse-rebound mechanism

Nature ◽  
2013 ◽  
Vol 499 (7457) ◽  
pp. 192-196 ◽  
Author(s):  
Changxia Yuan ◽  
Yong Liang ◽  
Taylor Hernandez ◽  
Adrian Berriochoa ◽  
Kendall N. Houk ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Aromatic Carbon ◽  
Metal Free ◽  
Carbon Hydrogen Bonds ◽  
Free Oxidation

Solvent-Free Oxidation of Primary Carbon-Hydrogen Bonds in Toluene Using Au-Pd Alloy Nanoparticles

Science ◽  
2011 ◽  
Vol 331 (6014) ◽  
pp. 195-199 ◽  
Author(s):  
L. Kesavan ◽  
R. Tiruvalam ◽  
M. H. A. Rahim ◽  
M. I. bin Saiman ◽  
D. I. Enache ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Solvent Free ◽  
Alloy Nanoparticles ◽  
Pd Alloy ◽  
Carbon Hydrogen Bonds ◽  
Free Oxidation

Ruthenium-Catalyzed Coupling of Aromatic Carbon-Hydrogen Bonds in Aromatic Imidates with Olefins

1999 ◽  
Vol 28 (1) ◽  
pp. 19-20 ◽  
Author(s):  
Fumitoshi Kakiuchi ◽  
Taisuke Sato ◽  
Masakazu Yamauchi ◽  
Naoto Chatani ◽  
Shinji Murai
Keyword(s):  
Hydrogen Bonds ◽  
Aromatic Carbon ◽  
Carbon Hydrogen Bonds

Confinement of Au3+-Rich Clusters by Silicalite-1 for Selective Solvent-Free Oxidation of Toluene

2021 ◽  
Author(s):  
He Huang ◽  
Wanyue Ye ◽  
Caicheng Song ◽  
Yingcen Liu ◽  
Xiaotong Zhang ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Selective Oxidation ◽  
Solvent Free ◽  
Selective Solvent ◽  
Methyl Group ◽  
Carbon Hydrogen Bonds ◽  
Free Oxidation

Selective oxidation of the primary carbon-hydrogen bonds in the methyl group of toluene to corresponding oxygenates is of immense significance. This transformation, however, remains challenging and often requires either extensive...

ChemInform Abstract: Efficient Catalytic Addition of Aromatic Carbon-Hydrogen Bonds to Olefins.

ChemInform ◽  
2010 ◽  
Vol 25 (8) ◽  
pp. no-no
Author(s):  
S. MURAI ◽  
F. KAKIUCHI ◽  
S. SEKINE ◽  
Y. TANAKA ◽  
A. KAMATANI ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Aromatic Carbon ◽  
Carbon Hydrogen Bonds ◽  
Catalytic Addition
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