Confinement of Au3+-Rich Clusters by Silicalite-1 for Selective Solvent-Free Oxidation of Toluene

2021 ◽  
Author(s):  
He Huang ◽  
Wanyue Ye ◽  
Caicheng Song ◽  
Yingcen Liu ◽  
Xiaotong Zhang ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Selective Oxidation ◽  
Solvent Free ◽  
Selective Solvent ◽  
Methyl Group ◽  
Carbon Hydrogen Bonds ◽  
Free Oxidation

Selective oxidation of the primary carbon-hydrogen bonds in the methyl group of toluene to corresponding oxygenates is of immense significance. This transformation, however, remains challenging and often requires either extensive...

Solvent-Free Oxidation of Primary Carbon-Hydrogen Bonds in Toluene Using Au-Pd Alloy Nanoparticles

Science ◽  
2011 ◽  
Vol 331 (6014) ◽  
pp. 195-199 ◽  
Author(s):  
L. Kesavan ◽  
R. Tiruvalam ◽  
M. H. A. Rahim ◽  
M. I. bin Saiman ◽  
D. I. Enache ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Solvent Free ◽  
Alloy Nanoparticles ◽  
Pd Alloy ◽  
Carbon Hydrogen Bonds ◽  
Free Oxidation

scholarly journals Two-dimensional gold nanostructures with high activity for selective oxidation of carbon–hydrogen bonds

2015 ◽  
Vol 6 (1) ◽  
Author(s):  
Liang Wang ◽  
Yihan Zhu ◽  
Jian-Qiang Wang ◽  
Fudong Liu ◽  
Jianfeng Huang ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
High Activity ◽  
Selective Oxidation ◽  
Gold Nanostructures ◽  
Two Dimensional ◽  
Carbon Hydrogen Bonds

Maximizing the Number of Interfacial Sites in Single-Atom Catalysts for the Highly Selective, Solvent-Free Oxidation of Primary Alcohols

2018 ◽  
Vol 130 (26) ◽  
pp. 7921-7925 ◽  
Author(s):  
Tianbo Li ◽  
Fei Liu ◽  
Yan Tang ◽  
Lin Li ◽  
Shu Miao ◽  
...  
Keyword(s):  
Solvent Free ◽  
Single Atom ◽  
Primary Alcohols ◽  
Selective Solvent ◽  
Free Oxidation

Selective Solvent-Free and Additive-Free Oxidation of Primary Benzylic C–H Bonds with O2 Catalyzed by the Combination of Metalloporphyrin with N-Hydroxyphthalimide

2020 ◽  
Vol 150 (11) ◽  
pp. 3096-3111 ◽  
Author(s):  
Hai-Min Shen ◽  
Bei Qi ◽  
Meng-Yun Hu ◽  
Lei Liu ◽  
Hong-Liang Ye ◽  
...  
Keyword(s):  
Solvent Free ◽  
Selective Solvent ◽  
Free Oxidation

Metal-free oxidation of aromatic carbon–hydrogen bonds through a reverse-rebound mechanism

Nature ◽  
2013 ◽  
Vol 499 (7457) ◽  
pp. 192-196 ◽  
Author(s):  
Changxia Yuan ◽  
Yong Liang ◽  
Taylor Hernandez ◽  
Adrian Berriochoa ◽  
Kendall N. Houk ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Aromatic Carbon ◽  
Metal Free ◽  
Carbon Hydrogen Bonds ◽  
Free Oxidation

Synthesis of ordered mesoporous silica/ceria–silica composites and their high catalytic performance for solvent-free oxidation of benzyl alcohol at room temperature

RSC Advances ◽  
2014 ◽  
Vol 4 (18) ◽  
pp. 9213-9222 ◽  
Author(s):  
Nabanita Pal ◽  
Eun-Bum Cho ◽  
Dukjoon Kim
Keyword(s):  
Benzyl Alcohol ◽  
Room Temperature ◽  
Catalytic Performance ◽  
Solvent Free ◽  
Ordered Mesoporous Silica ◽  
Selective Solvent ◽  
Oxidation Of Benzyl Alcohol ◽  
Ordered Mesoporous ◽  
Phase Oxidation ◽  
Free Oxidation

Ordered mesoporous Ce-MCM-41 and Ce-MCM-48 were prepared in which cerium was incorporated up to 29% of Ce/Si. These materials exhibit outstanding efficiency for highly selective solvent-free liquid phase oxidation of benzyl alcohol to benzaldehyde at room temperature.

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