scholarly journals Charge-reversal surfactant antibiotic material for reducing microbial corrosion in petroleum exploitation and transportation

2020 ◽  
Vol 6 (25) ◽  
pp. eaba7524 ◽  
Author(s):  
Lingda Zeng ◽  
Yincheng Chang ◽  
Yukun Wu ◽  
Jinpeng Yang ◽  
Jiang-Fei Xu ◽  
...  

The corrosions caused by sulfate-reducing bacteria (SRB) are serious problems in petroleum exploitation and transportation, which can lead to safety problems, environmental pollutions, and economic losses. Here, a charge-reversal surfactant antibiotic material N-dodecyl-1-carboxylic acid-1-cyclohexenyl-2-carboxamide (C12N-DCA) is designed and synthesized. C12N-DCA is a negatively charged surfactant, which cannot be adsorbed by soil and rock in a large amount. Therefore, it can reach the “lesion location”, with enough concentration. After being hydrolyzed and charge reversed under the acceleration of H2S produced by SRB, C12N-DCA becomes a positively charged surfactant dodecane ammonium salt to kill SRB. Through a simulating experiment, it is found that C12N-DCA can reach the SRB inhibition ratio of almost 100%, and it can reduce iron corrosion by 88%. Such an antibiotic material or its homologs may be added to the chemical flooding fluids, killing SRB during petroleum exploitation and reducing the SRB-induced corrosion in the petroleum exploitation and transportation.

3 Biotech ◽  
2018 ◽  
Vol 8 (12) ◽  
Author(s):  
Shanthi Vaithiyanathan ◽  
Karthikeyan Chandrasekaran ◽  
R. C. Barik

2011 ◽  
Vol 356-360 ◽  
pp. 161-164
Author(s):  
Cai Xiang Gu ◽  
Xiao Ming Zhao ◽  
Yan Sheng Yin ◽  
Gui Jun Ji

Advantage strains SRB and V.natriegens were obtained from the China East Sea for this study. Polarization curves, corrosion potential, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) analyses were adopted in order to investigate the corrosion behaviors of 0Cr18Ni9 stainless steel under the combination action of anaerobic SRB and facultative anaerobic V.natriegens, The characteristics and mechanisms of microbial corrosion action in sea water were analyzed in this paper. The results show that SRB and V.natriegens promote each other’s growth when cultivated in the mixed microbe medium, in which the rate of corrosion is higher than that in the single microbe; Under the combined action of the mixed microbe, the microbial film gets wider and thicker, and corrosion products and metabolite are produced, which furthermore accelerates the passivation and pit corrosion to the 0Cr18Ni9 stainless steel.


2018 ◽  
Vol 65 (1) ◽  
pp. 46-52
Author(s):  
Fengling Xu ◽  
Zhenghui Qiu ◽  
Ri Qiu ◽  
Jiadong Yang ◽  
Cunguo Lin

Purpose For mitigating biocorrosion induced by sulfate-reducing bacteria (SRB) in seawater, the zwitterionic molecule layer (ZML) of poly (sulfobetaine methacrylate) is grafted onto B10 surface by chemical vapor deposition and surface-initiated atom transfer radical polymerization. Design/methodology/approach Energy-dispersive spectroscopy-attenuated total reflectance Fourier transform infrared spectroscopy and static contact angle measurements are used to characterize the as-formed layer. Findings After surface modification, B10 can significantly reduce SRB adhesion, demonstrating the good antifouling property. Further, the biocorrosion inhibition is investigated by potentiodynamic polarization and electrochemical impedance spectroscopy, indicating that ZML exhibits high resistance to biocorrosion with inhibition efficiency of approximately 90 per cent. Originality/value ZML performs a dual feature, i.e. antifouling film and corrosion inhibitor, for the biocorrosion inhibition.


2021 ◽  
Vol 21 (1) ◽  
Author(s):  
Yan-Yu Cui ◽  
Yong-Xiang Qin ◽  
Qing-Miao Ding ◽  
Yu-Ning Gao

Abstract Background At present, microorganism has been considered as important factors that threaten to buried pipelines with disbonded coatings. Aiming at the problem of unknown corrosion mechanism of sulfate-reducing bacteria (SRB), a series of studies have been carried out in this paper. Spectrophotometer and fluorescent labeling technology are used to study the growth and attachment of SRB in the simulated soil solution. The corrosion behavior of X80 pipeline steel with or without SRB was researched by electrochemical methods such as open circuit potential, dynamic potential polarization curve, and electrochemical impedance spectroscopy. The microscopic morphology of the corrosion products on the surface was observed with a scanning electron microscope (SEM), and the element content of the corrosion products on the surface of the sample after corrosion was observed using X-ray energy spectrum (EDS) analysis. Results The results showed that the growth and reproduction of SRB caused the pH of the soil simulated solution to increase, which may promote the corrosion of X80 steel. In addition, the cathode reaction of X80 steel in a sterile environment is the reduction of H+, and the main corrosion product is iron oxide. When the soil simulation solution contains SRB, the cathodic reaction is controlled by both H+ reduction and sulfide depolarization reactions, and FeS appears in the corrosion products. Conclusion Although the life cycle of SRB is only about 14 days, the corrosion of X80 steel is greatly promoted by SRB, and even causes corrosion perforation, which will bring huge economic losses and serious safety hazards.


1998 ◽  
Vol 44 (11) ◽  
pp. 1060-1065 ◽  
Author(s):  
Anita J Telang ◽  
Sara Ebert ◽  
Julia M Foght ◽  
Donald WS Westlake ◽  
Gerrit Voordouw

The effects of diamine (R1-NH-R2-NH2) biocides A and B on the microbial population from an oil field were investigated with reverse sample genome probing (RSGP), a technique designed to track multiple oil field bacteria in a single assay. RSGP studies of sessile microbial populations scraped from corrosion coupons obtained from biocide-treated oil field installations indicated dominance of Desulfovibrio spp. Lac6 and Eth3, or of selected heterotrophs. RSGP of planktonic production water samples indicated a broad distribution of microorganisms that changed with the addition of medium for the growth of sulfate-reducing bacteria, containing different organic acids as electron donors for sulfate reduction. Use of lactate, propionate, or acetate enriched Desulfovibrio spp., Desulfobulbus sp. Pro4, or Desulfobacter spp., respectively. Treatment of lactate- or mixed organic acid-fed planktonic populations with biocides indicated resistance of Lac6 and Eth3 to 400 ppm of biocide B and 40 ppm of biocide A. The dominance of these two Desulfovibrio spp. in many sessile field samples is, therefore, likely caused by biocide selection.Key words: Desulfovibrio, sulfate reduction, microbial corrosion, souring, biocide.


Author(s):  
Інна Сергіївна Погребова ◽  
Ірина Панасівна Козлова ◽  
Лариса Михайлівна Пуриш ◽  
Марія Володимирівна Соколовська

2018 ◽  
Vol 3 (1) ◽  
pp. 301
Author(s):  
Vicente Calbo ◽  
Octavio Javier Furlong ◽  
Silvia Viviana Julián

Recently, in the city of La Rioja, the Microbiologically-Induced Corrosion (MIC) phenomenon has been confirmed. The last studied case corresponds to the water well of the La Rioja Regional Faculty of the National Technological University (UTN), where the water well facilities showed signs of this phenomenon.These microorganisms catalyze the iron (and magnesium) oxidation reactions, solubilizing or solubilizing and precipitating the metal. Confirming the existence of the MIC phenomenon is essential to mitigate or solve the problem.The laboratory work consisted in processing pipe and pump samples extracted after the well ceased to be used, at three initial temperatures and with different culture media, trying to cultivate, reproduce, and isolate and identify the different species.Thus, through culture methodology, the existence of a mixed flora featuring iron bacteria and sulfate-reducing bacteria was confirmed.Complementary Scanning Electron Microscopy (SEM) and Energy-dispersive X-ray Spectroscopy (EDS) spectroscopy scans allowed to visualize the bacteria, the damage to the analyzed material, and the morphology of the bioprecipitation.This little-known phenomenon causes significant economic losses and should therefore be taken into account in the execution as well as the maintenance of wells. Keywords: Metal Corrosion, Microbiologically Induced Corrosion, Water Well, Bacteria.


2020 ◽  
Author(s):  
Yanyu Cui ◽  
Yongxiang Qin ◽  
Qingmiao Ding ◽  
Yuning Gao

Abstract Background: At present, microorganism has been considered as important factors that threaten to buried pipelines with disbonded coatings. Aiming at the problem of unknown corrosion mechanism of sulfate-reducing bacteria (SRB), a series of studies have been carried out in this paper. Spectrophotometer and fluorescent labeling technology are used to study the growth and attachment of SRB in the simulated soil solution. The electrochemical behavior of X80 pipeline steel with or without SRB was researched by electrochemical methods such as open circuit potential, dynamic potential polarization curve, and electrochemical impedance spectroscopy. The microscopic morphology of the corrosion products on the surface of the sample was observed with a scanning electron microscope (SEM), and the element content of the corrosion products on the surface of the sample after corrosion was observed using X-ray energy spectrum (EDS) analysis. Results: The results showed that the growth and reproduction of SRB caused the pH of the soil simulated solution to increase, which promoted the corrosion of X80 steel. In addition, the cathode reaction of X80 steel in a sterile environment is the reduction of H+, and the main corrosion product is Fe oxides. When the soil simulation solution contains SRB, the cathodic reaction is controlled by both H+ reduction and sulfide depolarization reactions, and FeS appears in the corrosion products. Conclusion: Although the life cycle of SRB is only about 14 days, the corrosion of X80 steel is greatly promoted by SRB, and even causes corrosion perforation, which will bring huge economic losses and serious safety hazards.


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