scholarly journals Strategies in catalysts and electrolyzer design for electrochemical CO2 reduction toward C2+ products

2020 ◽  
Vol 6 (8) ◽  
pp. eaay3111 ◽  
Author(s):  
Lei Fan ◽  
Chuan Xia ◽  
Fangqi Yang ◽  
Jun Wang ◽  
Haotian Wang ◽  
...  

In light of environmental concerns and energy transition, electrochemical CO2 reduction (ECR) to value-added multicarbon (C2+) fuels and chemicals, using renewable electricity, presents an elegant long-term solution to close the carbon cycle with added economic benefits as well. However, electrocatalytic C─C coupling in aqueous electrolytes is still an open challenge due to low selectivity, activity, and stability. Design of catalysts and reactors holds the key to addressing those challenges. We summarize recent progress in how to achieve efficient C─C coupling via ECR, with emphasis on strategies in electrocatalysts and electrocatalytic electrode/reactor design, and their corresponding mechanisms. In addition, current bottlenecks and future opportunities for C2+ product generation is discussed. We aim to provide a detailed review of the state-of-the-art C─C coupling strategies to the community for further development and inspiration in both fundamental understanding and technological applications.

Author(s):  
Shuzhen Zhang ◽  
Celia Chen ◽  
Kangkang Li ◽  
Hai Yu ◽  
Fengwang Li

Electrochemical CO2 reduction reaction (eCO2RR) has been regarded as a promising means to store renewable electricity in the form of value-added chemicals or fuels. However, most of present eCO2RR studies...


2018 ◽  
Vol 11 (6) ◽  
pp. 1536-1551 ◽  
Author(s):  
Joshua M. Spurgeon ◽  
Bijandra Kumar

Electrochemical reduction of CO2 to fuels and chemicals is currently a focus of significant research effort as a technology that can simultaneously mitigate greenhouse gas emissions while storing renewable electricity for use on demand. Herein, the economics of CO2 reduction to select liquid products is analyzed.


Author(s):  
Dui Ma ◽  
Ting Jin ◽  
Keyu Xie ◽  
Haitao Huang

Converting CO2 into value-added fuels or chemical feedstocks through electrochemical reduction is one of the several promising avenues to reduce atmospheric carbon dioxide levels and alleviate global warming. This approach...


2018 ◽  
Vol 9 (11) ◽  
pp. 2952-2960 ◽  
Author(s):  
Eva M. Nichols ◽  
Jeffrey S. Derrick ◽  
Sepand K. Nistanaki ◽  
Peter T. Smith ◽  
Christopher J. Chang

The development of catalysts for electrochemical reduction of carbon dioxide offers an attractive approach to transforming this greenhouse gas into value-added carbon products with sustainable energy input.


Catalysts ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 98 ◽  
Author(s):  
Chaitanya B. Hiragond ◽  
Hwapyong Kim ◽  
Junho Lee ◽  
Saurav Sorcar ◽  
Can Erkey ◽  
...  

Electrochemical CO2 reduction towards value-added chemical feedstocks has been extensively studied in recent years to resolve the energy and environmental problems. The practical application of electrochemical CO2 reduction technology requires a cost-effective, highly efficient, and robust catalyst. To date, vigorous research have been carried out to increase the proficiency of electrocatalysts. In recent years, two-dimensional (2D) graphene and transition metal chalcogenides (TMCs) have displayed excellent activity towards CO2 reduction. This review focuses on the recent progress of 2D graphene and TMCs for selective electrochemical CO2 reduction into CO.


Author(s):  
Min Zhang ◽  
Wenbo Wei ◽  
Shenghua Zhou ◽  
Dong-Dong Ma ◽  
Aihui Cao ◽  
...  

Electrochemical CO2 reduction reaction (CO2RR) to value-added and readily collectable liquid products is promising but remains a great challenge due to the lack of efficient and robust electrocatalysts. Herein, a...


2018 ◽  
Author(s):  
Moza Salim Al Naimi ◽  
Mohamed I. Hassan Ali ◽  
Gento Mogi

Sustainable energy transition requires a critical prediction for the long-term evolvement of energy systems around the world. It is affected by several factors: the changes in the oil economy, the climate change, and the development of renewable energy supply technologies. The aim of this research is to compare and analyze Abu Dhabi’s generation sector in its transition from complete conventional gas to a mix of conventional and Photovoltaic (PV) energy systems. Employing a Mixed Integer Linear Program (MILP) and PLEXOS software, two capacity expansion scenarios of Abu Dhabi’s generation sector for five years are optimized, analyzed, and compared using a real data from the generation and demand sides. This research means to highlight, to the UAE government, the effect of introducing more renewable energy and to evaluate the performance of the generation side in meeting the forecasted demand. Furthermore, this work opens the doors wide for further development and optimization in the GCC area.


Energies ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 98
Author(s):  
Cristobal Gallego-Castillo ◽  
Marta Victoria

Reservoir and pumped hydro storage facilities represent one of the best options for providing flexibility at low marginal cost and very low life cycle carbon emissions. However, hydropower generation is subject to physical, environmental and regulatory constraints, which introduce complexity in the modelling of hydropower in the context of transition energy analysis. In this article, a probabilistic model for hydropower generation is developed in order to improve an hourly-resolved tool for transition path analysis presented in previous research. The model is based on time series analysis, which exploits the fact that the different constraints affecting hydropower generation were met in the past. The upgraded version of the transition path analysis tool shows a decrease in the hydropower flexibility as compared with previous published results, providing a better picture of the benefits and drawbacks associated with a specific transition path under analysis, for example in terms of assessing the probability of unserved energy. The upgraded version of the tool was employed to analyse the Spanish National Energy and Climate Plan (NECP), finding consistence between proposals associated with the power system and related CO2 reduction and share of renewable electricity targets.


2021 ◽  
Author(s):  
Wenbo Wang ◽  
Runqing Lu ◽  
Xin-Xin Xiao ◽  
Shanhe Gong ◽  
Daniel Kobina Sam ◽  
...  

Electrochemical carbon dioxide reduction reaction (eCO2RR) is a promising technology that uses electrical energy to catalytically reduce the greenhouse gas-CO2, which can convert CO2 into high value-added products such as...


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