Rheology and Phase Transition in 30% Solutions of Styrene‐Butadiene Radial Block Copolymers

1989 ◽  
Vol 33 (3) ◽  
pp. 469-480
Author(s):  
Toshiro Masuda ◽  
Toshikazu Takigawa ◽  
Takahiko Kojima ◽  
Yasuhiko Ohta
Keyword(s):  
Phase Transition ◽  
Block Copolymers ◽  
Styrene Butadiene

Ordered Structures of Styrene Butadiene Block Copolymers

1967 ◽  
Vol 40 (5) ◽  
pp. 1526-1528
Author(s):  
Ed Vanzo
Keyword(s):  
Solid State ◽  
Block Copolymers ◽  
Mechanical Deformation ◽  
Solution Properties ◽  
Two Dimensional ◽  
Ordered Structure ◽  
Ordered Structures ◽  
Polymer Molecules ◽  
Cast Films ◽  
Styrene Butadiene

Abstract Anionically prepared block copolymers of butadiene and styrene exhibit solution properties which result from a two dimensional ordering of the polymer molecules. The most notable of these properties is the iridescent colors of toluene solutions which are dependent on concentration and abruptly change on mechanical deformation. Electron micrographs of the surface of cast films indicate that the ordered structure is retained to some degree in the solid state.

Correlation between Molecular Architecture, Morphology, and Deformation Behaviour of Styrene/Butadiene Block Copolymers

2003 ◽  
Vol 204 (3) ◽  
pp. 488-499 ◽  
Author(s):  
Rameshwar Adhikari ◽  
Goerg H. Michler ◽  
Trinh An Huy ◽  
Elena Ivan'kova ◽  
Reinhold Godehardt ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Deformation Behaviour ◽  
Molecular Architecture ◽  
Styrene Butadiene

Novel styrene-butadiene block copolymers by sequential and statistical copolymerization of corresponding macromonomers

1998 ◽  
Vol 128 (1) ◽  
pp. 21-37 ◽  
Author(s):  
Daniel Grande ◽  
Jean-Luc Six ◽  
Valérie Héroguez ◽  
Yves Gnanou ◽  
Michel Fontanille
Keyword(s):  
Block Copolymers ◽  
Styrene Butadiene

Rapid Modular Synthesis and Processing of Thiol–Ene Functionalized Styrene–Butadiene Block Copolymers

2012 ◽  
Vol 45 (7) ◽  
pp. 3161-3167 ◽  
Author(s):  
Joshua S. Silverstein ◽  
Brendan J. Casey ◽  
Mary E. Natoli ◽  
Benita J. Dair ◽  
Peter Kofinas
Keyword(s):  
Block Copolymers ◽  
Modular Synthesis ◽  
Synthesis And Processing ◽  
Styrene Butadiene

The Results of the Compromise Task Solution Directed for Development of Polymer-Modified Binder

2021 ◽  
Vol 899 ◽  
pp. 67-72
Author(s):  
V.D. Polonik ◽  
A.S. Kukleva ◽  
N.D. Avdeev ◽  
M.D. Shlyaptseva ◽  
Vadim G. Nikol'skii ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Softening Point ◽  
Mutual Influence ◽  
Brittleness Temperature ◽  
Styrene Butadiene Styrene ◽  
Modified Binder ◽  
Styrene Butadiene ◽  
Butadiene Styrene

This work presents the results of optimization compositions of polymer-modified binder (PMB) by a compromise task. The conducted study of influence two prescription factors – containing styrene-butadiene-styrene and sulfur – on which is a set of indicators of polymer-bitumen binders were carried out. The regularities of these factors of mutual influence were established by such indicators as the Fraas brittleness temperature, penetration, softening point, ductility. The dosages of SBS and sulfur have been determined by ensuring the achievement of the required level of PBB indicators in accordance with GOST R 52056-2003 «Bitumen-polymer road binders are based on styrene-butadiene-styrene block copolymers. Specifications».

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