Rapid Modular Synthesis and Processing of Thiol–Ene Functionalized Styrene–Butadiene Block Copolymers

2012 ◽  
Vol 45 (7) ◽  
pp. 3161-3167 ◽  
Author(s):  
Joshua S. Silverstein ◽  
Brendan J. Casey ◽  
Mary E. Natoli ◽  
Benita J. Dair ◽  
Peter Kofinas
Keyword(s):  
Block Copolymers ◽  
Modular Synthesis ◽  
Synthesis And Processing ◽  
Styrene Butadiene

Ordered Structures of Styrene Butadiene Block Copolymers

1967 ◽  
Vol 40 (5) ◽  
pp. 1526-1528
Author(s):  
Ed Vanzo
Keyword(s):  
Solid State ◽  
Block Copolymers ◽  
Mechanical Deformation ◽  
Solution Properties ◽  
Two Dimensional ◽  
Ordered Structure ◽  
Ordered Structures ◽  
Polymer Molecules ◽  
Cast Films ◽  
Styrene Butadiene

Abstract Anionically prepared block copolymers of butadiene and styrene exhibit solution properties which result from a two dimensional ordering of the polymer molecules. The most notable of these properties is the iridescent colors of toluene solutions which are dependent on concentration and abruptly change on mechanical deformation. Electron micrographs of the surface of cast films indicate that the ordered structure is retained to some degree in the solid state.

Correlation between Molecular Architecture, Morphology, and Deformation Behaviour of Styrene/Butadiene Block Copolymers

2003 ◽  
Vol 204 (3) ◽  
pp. 488-499 ◽  
Author(s):  
Rameshwar Adhikari ◽  
Goerg H. Michler ◽  
Trinh An Huy ◽  
Elena Ivan'kova ◽  
Reinhold Godehardt ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Deformation Behaviour ◽  
Molecular Architecture ◽  
Styrene Butadiene

Novel styrene-butadiene block copolymers by sequential and statistical copolymerization of corresponding macromonomers

1998 ◽  
Vol 128 (1) ◽  
pp. 21-37 ◽  
Author(s):  
Daniel Grande ◽  
Jean-Luc Six ◽  
Valérie Héroguez ◽  
Yves Gnanou ◽  
Michel Fontanille
Keyword(s):  
Block Copolymers ◽  
Styrene Butadiene

The Results of the Compromise Task Solution Directed for Development of Polymer-Modified Binder

2021 ◽  
Vol 899 ◽  
pp. 67-72
Author(s):  
V.D. Polonik ◽  
A.S. Kukleva ◽  
N.D. Avdeev ◽  
M.D. Shlyaptseva ◽  
Vadim G. Nikol'skii ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Softening Point ◽  
Mutual Influence ◽  
Brittleness Temperature ◽  
Styrene Butadiene Styrene ◽  
Modified Binder ◽  
Styrene Butadiene ◽  
Butadiene Styrene

This work presents the results of optimization compositions of polymer-modified binder (PMB) by a compromise task. The conducted study of influence two prescription factors – containing styrene-butadiene-styrene and sulfur – on which is a set of indicators of polymer-bitumen binders were carried out. The regularities of these factors of mutual influence were established by such indicators as the Fraas brittleness temperature, penetration, softening point, ductility. The dosages of SBS and sulfur have been determined by ensuring the achievement of the required level of PBB indicators in accordance with GOST R 52056-2003 «Bitumen-polymer road binders are based on styrene-butadiene-styrene block copolymers. Specifications».

The Properties of a Styrene Butadiene Block Copolymer with a High Styrene Content

2014 ◽  
Vol 41 (10) ◽  
pp. 45-50
Author(s):  
A.A. Alekseev ◽  
A.V. Lobanov ◽  
V.S. Osipchik ◽  
V.S. Glukhovskoi ◽  
V.M. Aristov ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Absorption Band ◽  
Ir Spectra ◽  
Structure And Properties ◽  
Styrene Content ◽  
Styrene Butadiene ◽  
Butadiene Styrene

The structure and properties of block copolymers (BCPs) of styrene and butadiene of grade StiroTEP-70 (styrene:butadiene = 70:30, Mw/Mn = 1.43–1.45) are discussed. Analysis of IR spectra enables the BCP to be treated as polystyrene-stat-copoly(butadiene/styrene/1,2-butadiene)-polystyrene. It is suggested that the absorption band at 542 cm-1 be considered as characteristic when identifying polymers with extensive polystyrene phases. At temperatures of 190–230°C, the BCP is partially crosslinked, and at 260°C it breaks down. The BCP is processed well at temperatures up to 200°C.

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