Gas-phase study of the group VI transition metal tricarbonyl complexes by negative-ion photoelectron spectroscopy

1992 ◽  
Author(s):  
Ashfaq A. Bengali ◽  
Sean M. Casey ◽  
Chun-Lin Cheng ◽  
Jonathan P. Dick ◽  
P. T. Fenn ◽  
...  
Keyword(s):  
Transition Metal ◽  
Gas Phase ◽  
Photoelectron Spectroscopy ◽  
Negative Ion ◽  
Group Vi ◽  
Phase Study

scholarly journals Negative ion photoelectron spectroscopy confirms the prediction that D3h carbon trioxide (CO3) has a singlet ground state

2016 ◽  
Vol 7 (2) ◽  
pp. 1142-1150 ◽  
Author(s):  
David A. Hrovat ◽  
Gao-Lei Hou ◽  
Bo Chen ◽  
Xue-Bin Wang ◽  
Weston Thatcher Borden
Keyword(s):  
Gas Phase ◽  
Ground State ◽  
Photoelectron Spectroscopy ◽  
Radical Anion ◽  
Negative Ion ◽  
Singlet Ground State

The CO3 radical anion (CO3˙−) has been formed by electrospraying carbonate dianion (CO32−) into the gas phase.

scholarly journals Photoelectron spectroscopy of reactive intermediates

1988 ◽  
Vol 324 (1578) ◽  
pp. 197-207 ◽  
Keyword(s):  
Transition Metal ◽  
Gas Phase ◽  
Photoelectron Spectroscopy ◽  
Photoelectron Spectrum ◽  
Reactive Intermediates ◽  
Vapour Phase ◽  
Photoelectron Spectra ◽  
Triatomic Molecule ◽  
Recent Developments ◽  
Vanadium Monoxide

Recent developments in the use of photoelectron spectroscopy to study reactive intermediates in the gas phase are reviewed. The information to be derived on low-lying cationic states from such studies is illustrated by considering two diatomic molecules, NCI and PF, and one triatomic molecule, HNO. Also, the use of a transition-metal photoelectron spectrum to interpret the photoelectron spectrum of the corresponding transition-metal oxide is discussed by using the spectra of vanadium and vanadium monoxide as examples. The value of super-heating in high-temperature photoelectron spectroscopy is demonstrated by considering the vapour-phase photoelectron spectra of the monomers and dimers of sodium hydroxide.

Gas-Phase transition-metal negative ion chemistry

1987 ◽  
Vol 87 (3) ◽  
pp. 623-646 ◽  
Author(s):  
Robert R. Squires
Keyword(s):  
Phase Transition ◽  
Transition Metal ◽  
Gas Phase ◽  
Negative Ion ◽  
Ion Chemistry

Negative Ion Photoelectron Spectroscopy of NH2-(NH3)1 and NH2-(NH3)2: Gas Phase Basicities of Partially Solvated Anions

1995 ◽  
Vol 99 (24) ◽  
pp. 9675-9680 ◽  
Author(s):  
Joseph T. Snodgrass ◽  
James V. Coe ◽  
Carl B. Freidhoff ◽  
Kevin M. McHugh ◽  
Susan T. Arnold ◽  
...  
Keyword(s):  
Gas Phase ◽  
Photoelectron Spectroscopy ◽  
Negative Ion ◽  
Gas Phase Basicities

ChemInform Abstract: Negative Ion Photoelectron Spectroscopy of Coordinatively Unsaturated Group VI Metal Carbonyls: Cr(CO)3, Mo(CO)3, and W(CO)3.

ChemInform ◽  
2010 ◽  
Vol 23 (40) ◽  
pp. no-no
Author(s):  
A. A. BENGALI ◽  
S. M. CASEY ◽  
C.-L. CHENG ◽  
J. P. DICK ◽  
P. T. FENN ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Negative Ion ◽  
Metal Carbonyls ◽  
Group Vi ◽  
Unsaturated Group

Electronic Structure of Early Transition-Metal Carbonyls:  Gas-Phase Photoelectron Spectroscopy of (η5-C5H5)M(CO)4(M = V, Nb, Ta)

2000 ◽  
Vol 19 (10) ◽  
pp. 2012-2021 ◽  
Author(s):  
Dennis L. Lichtenberger ◽  
Hua-Jun Fan ◽  
Nadine E. Gruhn ◽  
Thomas E. Bitterwolf ◽  
Skip Gallagher
Keyword(s):  
Electronic Structure ◽  
Transition Metal ◽  
Gas Phase ◽  
Photoelectron Spectroscopy ◽  
Metal Carbonyls ◽  
Early Transition Metal ◽  
Transition Metal Carbonyls ◽  
Early Transition

Negative ion photoelectron spectroscopy of coordinatively unsaturated Group VI metal carbonyls of chromium, molybdenum, and tungsten: Cr(CO)3, Mo(CO)3, and W(CO)3

1992 ◽  
Vol 114 (13) ◽  
pp. 5257-5268 ◽  
Author(s):  
Ashfaq A. Bengali ◽  
Sean M. Casey ◽  
Chun Lin Cheng ◽  
Jonathan P. Dick ◽  
P. Thomas Fenn ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Negative Ion ◽  
Metal Carbonyls ◽  
Group Vi ◽  
Unsaturated Group ◽  
And Tungsten

Negative-Ion Photoelectron Spectroscopy, Gas-Phase Acidity, and Thermochemistry of the Peroxyl Radicals CH3OO and CH3CH2OO

2001 ◽  
Vol 123 (39) ◽  
pp. 9585-9596 ◽  
Author(s):  
Stephen J. Blanksby ◽  
Tanya M. Ramond ◽  
Gustavo E. Davico ◽  
Mark R. Nimlos ◽  
Shuji Kato ◽  
...  
Keyword(s):  
Gas Phase ◽  
Photoelectron Spectroscopy ◽  
Peroxyl Radicals ◽  
Negative Ion ◽  
Gas Phase Acidity
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