Hot-wire CVD hydrogenated amorphous silicon for multi-layer photonic applications

Author(s):  
Harold M. H. Chong ◽  
Swe Zin Oo ◽  
Rafidah Petra ◽  
Antulio Tarazona ◽  
Vinita Mittal ◽  
...  
1996 ◽  
Author(s):  
A. H. Mahan ◽  
B. P. Nelson ◽  
E. Iwaniczko ◽  
Q. Wang ◽  
E. C. Molenbroek ◽  
...  

1997 ◽  
Vol 82 (4) ◽  
pp. 1909-1917 ◽  
Author(s):  
Edith C. Molenbroek ◽  
A. H. Mahan ◽  
Alan Gallagher

1997 ◽  
Vol 467 ◽  
Author(s):  
K. F. Feenstra ◽  
C. H. M. Van Der Werf ◽  
E. C. Molenbroek ◽  
R. E. I. Schropp

ABSTRACTIn this paper we present the results of the optimization of hydrogenated amorphous silicon films deposited by the hot-wire method in a larger area system. Using a two-wire design, we succeeded in depositing films that exhibit uniform electrical properties over the whole 4” x 4” Corning 7059 glass substrate. At a substrate temperature of 430 °C. and a pressure of 20 μbar we obtained a growth rate of ∼2 nm/s. The temperature of the tungsten filaments was kept at 1850 °C. The values for the photoconductivity and dark conductivity were 8.9×10−6 S/cm and 1.6×10−10 S/cm respectively, whereas the ambipolar diffusion length, as measured with the Steady-State Photocarrier Grating technique (SSPG), amounted to 145 nm. This value is higher than for our device quality glow-discharge (GD) films, which yield devices with efficiencies higher than 10%. The hydrogen content was 9.5%.We report on the density-of-states (DOS) distribution in the films, which was measured with the techniques of Thermally Stimulated Conductivity (TSC) and Constant Photocurrent Method (CPM). Furthermore, we describe the behavior of the electrical properties on light-induced degradation. Finally, we incorporated these films in solar cells, using conventional GD doped layers. Preliminary SS/n-i-p/ITO devices yielded efficiencies in excess of 3% under 100 mW/cm2 AM 1.5 illumination. Further work concerning the optimization of the interfaces is in progress.


1998 ◽  
Vol 507 ◽  
Author(s):  
Guozhen Yue ◽  
Liangfan Chen ◽  
Qi Wang ◽  
Eugene Iwaniczko ◽  
Guanglin Kong ◽  
...  

ABSTRACTDevice-quality a-Si:H films were prepared by glow discharge CVD with pure or H-diluted silane as well as by hot-wire CVD. The hydrogen content was varied from ∼2 to 15 at. %. The Si-H bond absorption and its light-soaking-induced changes were studied by IR and differential IR absorption spectroscopes. The results indicate that the more stable sample exhibits an increase of the absorption at wave number ∼2000 cm−1, and the less stable one exhibits a decrease at ∼2040 cm−1and an increase at ∼1880 cm−1.


2013 ◽  
Vol 1536 ◽  
pp. 175-180 ◽  
Author(s):  
W. Beyer ◽  
W. Hilgers ◽  
D. Lennartz ◽  
F.C. Maier ◽  
N.H. Nickel ◽  
...  

ABSTRACTAn important property of thin film silicon and related materials is the microstructure which may involve the presence of interconnected and isolated voids. We report on effusion measurements of implanted helium (He) to detect such voids. Several series of hydrogenated and unhydrogenated amorphous silicon films prepared by the methods of plasma deposition, hot wire deposition and vacuum evaporation were investigated. The results show common features like a He effusion peak at low temperatures attributed to He out-diffusion through a compact material or through interconnected voids, and a He effusion peak at high temperatures attributed to He trapped in isolated voids. While undoped plasma-grown device-grade hydrogenated amorphous silicon (a-Si:H) films show a rather low concentration of such isolated voids, its concentration can be rather high in doped a-Si:H, in unhydrogenated evaporated material and others.


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