Simulating and discussion on surface plasmon typical optical properties of patterned periodic metallic nanostructures

Author(s):  
Ying Yuan ◽  
Haiwei Wang ◽  
Changsheng Xie ◽  
Huabao Long ◽  
runhan liu ◽  
...  
Photonics ◽  
2021 ◽  
Vol 8 (2) ◽  
pp. 41
Author(s):  
Najat Andam ◽  
Siham Refki ◽  
Hidekazu Ishitobi ◽  
Yasushi Inouye ◽  
Zouheir Sekkat

The determination of optical constants (i.e., real and imaginary parts of the complex refractive index (nc) and thickness (d)) of ultrathin films is often required in photonics. It may be done by using, for example, surface plasmon resonance (SPR) spectroscopy combined with either profilometry or atomic force microscopy (AFM). SPR yields the optical thickness (i.e., the product of nc and d) of the film, while profilometry and AFM yield its thickness, thereby allowing for the separate determination of nc and d. In this paper, we use SPR and profilometry to determine the complex refractive index of very thin (i.e., 58 nm) films of dye-doped polymers at different dye/polymer concentrations (a feature which constitutes the originality of this work), and we compare the SPR results with those obtained by using spectroscopic ellipsometry measurements performed on the same samples. To determine the optical properties of our film samples by ellipsometry, we used, for the theoretical fits to experimental data, Bruggeman’s effective medium model for the dye/polymer, assumed as a composite material, and the Lorentz model for dye absorption. We found an excellent agreement between the results obtained by SPR and ellipsometry, confirming that SPR is appropriate for measuring the optical properties of very thin coatings at a single light frequency, given that it is simpler in operation and data analysis than spectroscopic ellipsometry.


Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1728
Author(s):  
Joshua Fernandes ◽  
Sangmo Kang

The near-field enhancement and localized surface plasmon resonance (LSPR) on the core-shell noble metal nanostructure surfaces are widely studied for various biomedical applications. However, the study of the optical properties of new plasmonic non-spherical nanostructures is less explored. This numerical study quantifies the optical properties of spherical and non-spherical (prolate and oblate) dimer nanostructures by introducing finite element modelling in COMSOL Multiphysics. The surface plasmon resonance peaks of gold nanostructures should be understood and controlled for use in biological applications such as photothermal therapy and drug delivery. In this study, we find that non-spherical prolate and oblate gold dimers give excellent tunability in a wide range of biological windows. The electromagnetic field enhancement and surface plasmon resonance peak can be tuned by varying the aspect ratio of non-spherical nanostructures, the refractive index of the surrounding medium, shell thickness, and the distance of separation between nanostructures. The absorption spectra exhibit considerably greater dependency on the aspect ratio and refractive index than the shell thickness and separation distance. These results may be essential for applying the spherical and non-spherical nanostructures to various absorption-based applications.


Langmuir ◽  
2008 ◽  
Vol 24 (20) ◽  
pp. 11982-11987 ◽  
Author(s):  
Nasser A. M. Barakat ◽  
Kee-Do Woo ◽  
Muzafar A. Kanjwal ◽  
Kyung Eun Choi ◽  
Myung Seob Khil ◽  
...  

2019 ◽  
Author(s):  
Dev Kumar Thapa ◽  
Subham Kumar Saha ◽  
Guru Pratheep Rajasekar ◽  
Biswajit Bhattacharyya ◽  
Rekha Mahadevu ◽  
...  

This article describes the optical properties of nanostructures composed of silver particles embedded into a gold matrix. In previous studies these materials were shown to exhibit temperature dependent transitions to a highly conductive and strongly diamagnetic state. Here we describe the anomalous optical properties of these nanostructures. Most notably, these materials fail to obey Mie theory and exhibit an unconventional resonance with a maximum at about 4 eV, while the usual gold and silver localized surface plasmon resonances are suppressed. This effect implies a significant deviation from the bulk dielectric functions of gold and silver. We further resolved this resonance into its absorbance and scattering sub-parts. It is observed that the resonance is largely comprised of scattering, with negligible losses even at ultraviolet frequencies.


2005 ◽  
Vol 872 ◽  
Author(s):  
Kai Yang ◽  
Hongyou Fan ◽  
Michael J. O'Brien ◽  
Sima La Fontaine ◽  
Gabriel P. Lopez ◽  
...  

AbstractHighly ordered gold NC/silica films are synthesized by self-assembly of water-soluble gold nanocrystal micelles and soluble silica using a sol-gel spin-coating technique. The optical properties are analyzed using ellipsometry and ultraviolet-visible spectroscopy. The absorption spectra show a strong surface plasmon absorption band at ∼520 nm for all samples. Angular excitation spectra of the surface plasmon show a steep dip in the reflectivity curve at ∼65°. Charge transport behavior of the films is examined using metal-oxide-semiconductor (MOS) structures.MOS capacitor samples exhibit charge storage with discharge behavior dominated by electron transport within the gold NC arrays.


Author(s):  
Phool Shahzadi

The chapter provides a timely review of the various properties of nonmaterial and their applications into environmental compartments. An extensive variety of poisonous chemicals is discharged into the environment because of globalization and industrialization. The dimensional, compositional, geometric, and structural properties are fundamental to convey usefulness of the nanomaterials. The controlled sizes and shapes of nanoparticles are anticipated to yield unique catalytic, electrochemical, and photochemical properties. The electrochemical properties of monolayer-functional metal nanoparticles are expected to be controlled by the particle sizes. Metal nanomaterials have interesting optical properties due to strong surface plasmon absorption and field enhancement effects; metal oxides lack visible absorption due to very large bandgap. Nanocomposites have complex optical properties. Nanomaterials present gigantic advantages on diverse applications, catalysis, imaging, biotechnological, and sensor applications due to their improved properties.


Nanomaterials ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 863 ◽  
Author(s):  
Owen Kendall ◽  
Pierce Wainer ◽  
Steven Barrow ◽  
Joel van Embden ◽  
Enrico Della Gaspera

Fluorine-doped tin oxide (FTO) is one of the most studied and established materials for transparent electrode applications. However, the syntheses for FTO nanocrystals are currently very limited, especially for stable and well-dispersed colloids. Here, we present the synthesis and detailed characterization of FTO nanocrystals using a colloidal heat-up reaction. High-quality SnO2 quantum dots are synthesized with a tuneable fluorine amount up to ~10% atomic, and their structural, morphological and optical properties are fully characterized. These colloids show composition-dependent optical properties, including the rise of a dopant-induced surface plasmon resonance in the near infrared.


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