Surface Plasmon Resonances, Optical Properties, and Electrical Conductivity Thermal Hystersis of Silver Nanofibers Produced by the Electrospinning Technique

Langmuir ◽  
2008 ◽  
Vol 24 (20) ◽  
pp. 11982-11987 ◽  
Author(s):  
Nasser A. M. Barakat ◽  
Kee-Do Woo ◽  
Muzafar A. Kanjwal ◽  
Kyung Eun Choi ◽  
Myung Seob Khil ◽  
...  
2019 ◽  
Author(s):  
Dev Kumar Thapa ◽  
Subham Kumar Saha ◽  
Guru Pratheep Rajasekar ◽  
Biswajit Bhattacharyya ◽  
Rekha Mahadevu ◽  
...  

This article describes the optical properties of nanostructures composed of silver particles embedded into a gold matrix. In previous studies these materials were shown to exhibit temperature dependent transitions to a highly conductive and strongly diamagnetic state. Here we describe the anomalous optical properties of these nanostructures. Most notably, these materials fail to obey Mie theory and exhibit an unconventional resonance with a maximum at about 4 eV, while the usual gold and silver localized surface plasmon resonances are suppressed. This effect implies a significant deviation from the bulk dielectric functions of gold and silver. We further resolved this resonance into its absorbance and scattering sub-parts. It is observed that the resonance is largely comprised of scattering, with negligible losses even at ultraviolet frequencies.


2019 ◽  
Author(s):  
Dev Kumar Thapa ◽  
Subham Kumar Saha ◽  
Guru Pratheep Rajasekar ◽  
Biswajit Bhattacharyya ◽  
Rekha Mahadevu ◽  
...  

This article describes the optical properties of nanostructures composed of silver particles embedded into a gold matrix. In previous studies these materials were shown to exhibit temperature dependent transitions to a highly conductive and strongly diamagnetic state. Here we describe the anomalous optical properties of these nanostructures. Most notably, these materials fail to obey Mie theory and exhibit an unconventional resonance with a maximum at about 4 eV, while the usual gold and silver localized surface plasmon resonances are suppressed. This effect implies a significant deviation from the bulk dielectric functions of gold and silver. We further resolved this resonance into its absorbance and scattering sub-parts. It is observed that the resonance is largely comprised of scattering, with negligible losses even at ultraviolet frequencies.


Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Adi Salomon ◽  
Heiko Kollmann ◽  
Manfred Mascheck ◽  
Slawa Schmidt ◽  
Yehiam Prior ◽  
...  

Abstract Localized surface plasmon resonances of individual sub-wavelength cavities milled in metallic films can couple to each other to form a collective behavior. This coupling leads to a delocalization of the plasmon field at the film surface and drastically alters both the linear and nonlinear optical properties of the sample. In periodic arrays of nanocavities, the coupling results in the formation of propagating surface plasmon polaritons (SPP), eigenmodes extending across the array. When artificially introducing dislocations, defects and imperfections, multiple scattering of these SPP modes can lead to hot-spot formation, intense and spatially confined fluctuations of the local plasmonic field within the array. Here, we study the underlying coupling effects by probing plasmonic modes in well-defined individual triangular dimer cavities and in arrays of triangular cavities with and without artificial defects. Nonlinear confocal spectro-microscopy is employed to map the second harmonic (SH) radiation from these systems. Pronounced spatial localization of the SPP field and significant enhancements of the SH intensity in certain, randomly distributed hot spots by more than an order of magnitude are observed from the triangular arrays as compared to a bare silver film by introducing a finite degree of disorder into the array structure. Hot-spot formation and the resulting enhancement of the nonlinear efficiency are correlated with an increase in the lifetime of the localized SPP modes. By using interferometric SH autocorrelation measurements, we reveal lifetimes of hot-spot resonances in disordered arrays that are much longer than the few-femtosecond lifetimes of the localized surface plasmon resonances of individual nanocavity dimers. This suggests that hot spot lifetime engineering provides a path for manipulating the linear and nonlinear optical properties of nanosystems by jointly exploiting coherent couplings and tailored disorder.


2007 ◽  
Vol 15 (12) ◽  
pp. 7439 ◽  
Author(s):  
Elizabeth J. Smythe ◽  
Ertugrul Cubukcu ◽  
Federico Capasso

Plasmonics ◽  
2013 ◽  
Vol 8 (3) ◽  
pp. 1379-1385 ◽  
Author(s):  
Kristof Lodewijks ◽  
Jef Ryken ◽  
Willem Van Roy ◽  
Gustaaf Borghs ◽  
Liesbet Lagae ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document