Optimization of the Cement Slurry Compositions With Addition of Zeolite for Cementing Carbon Dioxide Injection Wells

2015 ◽  
Author(s):  
Krunoslav Sedić ◽  
Nediljka Gaurina-Medjimurec ◽  
Borivoje Pašić
Keyword(s):  
Carbon Dioxide ◽  
Oil And Gas ◽  
Co2 Injection ◽  
Carbon Dioxide Injection ◽  
Cement Slurry ◽  
Gas Reservoirs ◽  
Injection Wells ◽  
Standard Size ◽  
Well Integrity ◽  
Well Cement

Well integrity related to carbon dioxide injection into depleted oil and gas reservoirs can be compromised by corrosion which can affect casing, downhole and surface equipment and well cement. Impact on well cement can cause overall degradation of set cement and lead to migration of carbon dioxide back to the surface. Thus, special types of cements should be used. One of the acceptable solutions is application of cement blends based on a mixture of Portland cement and pozzolans. The present paper deals with optimization of the cement slurry design containing zeolite which is nowadays widely used due to its high pozzolan activity potential. Cement blends containing 20%, 30% and 40% zeolite clinoptilolite were used. Cement slurries were optimized for application in slim hole conditions on CO2 injection wells on Žutica and Ivanić oil fields in Croatia (Europe), where an old and deteriorated production casing was re-lined with new smaller sized one. Results obtained by this study suggest that cement slurry containing zeolite can be optimized for application in well conditions related to CO2 injection and underground storage, ranging from a slim hole to standard size casing cement jobs which leads to an improvement of well integrity related to CO2 injection.

Enhanced Cement Composition for Preventing Annular Gas Migration

2019 ◽  
Author(s):  
George Kwatia ◽  
Mustafa Al Ramadan ◽  
Saeed Salehi ◽  
Catalin Teodoriu
Keyword(s):  
Oil And Gas ◽  
Oil And Gas Industry ◽  
Oil Well ◽  
Gas Migration ◽  
Cement Slurry ◽  
Gas Industry ◽  
Well Integrity ◽  
Transit Times ◽  
Well Cement ◽  
Gas Tight

Abstract Cementing operations in deepwater exhibit many challenges worldwide due to shallow flows. Cement sheath integrity and durability play key roles in the oil and gas industry, particularly during drilling and completion stages. Cement sealability serves in maintaining the well integrity by preventing fluid migration to surface and adjacent formations. Failure of cement to seal the annulus can lead to serious dilemmas that may result in loss of well integrity. Gas migration through cemented annulus has been a major issue in the oil and gas industry for decades. Anti-gas migration additives are usually mixed with the cement slurry to combat and prevent gas migration. In fact, these additives enhance and improve the cement sealability, bonding, and serve in preventing microannuli evolution. Cement sealability can be assessed and evaluated by their ability to seal and prevent any leakage through and around the cemented annulus. Few laboratory studies have been conducted to evaluate the sealability of oil well cement. In this study, a setup was built to simulate the gas migration through and around the cement. A series of experiments were conducted on these setups to examine the cement sealability of neat Class H cement and also to evaluate the effect of anti-gas migration additives on the cement sealability. Different additives were used in this setup such as microsilica, fly ash, nanomaterials and latex. Experiments conducted in this work revealed that the cement (without anti-gas migration additive) lack the ability to seal the annulus. Cement slurries prepared with latex improved the cement sealability and mitigated gas migration for a longer time compared to the other slurries. The cement slurry formulated with a commercial additive completely prevented gas migration and proved to be a gas tight. Also, it was found that slurries with short gas transit times have a decent potential to mitigate gas migration, and this depends on the additives used to prepare the cement slurry.

scholarly journals Application of fluidal ashes as a component of cement slurry used in carbon dioxide injection wells - possibility analysis

2018 ◽  
Vol 35 (1) ◽  
pp. 157
Author(s):  
Małgorzata Formela ◽  
Kamil Gonet ◽  
Stanisław Stryczek ◽  
Rafał Wiśniowski
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Injection ◽  
Cement Slurry ◽  
Injection Wells

A Laboratory Investigation of the Effect of Ethanol-Treated Carbon Dioxide Injection on Oil Recovery and Carbon Dioxide Storage

SPE Journal ◽  
2021 ◽  
pp. 1-17
Author(s):  
Saira ◽  
Emmanuel Ajoma ◽  
Furqan Le-Hussain
Keyword(s):  
Carbon Dioxide ◽  
Oil Recovery ◽  
Carbon Capture ◽  
Molar Fraction ◽  
Co2 Injection ◽  
Carbon Dioxide Injection ◽  
Treated Carbon ◽  
Carbon Dioxide Co2 ◽  
And Storage ◽  
Experimental Runs

Summary Carbon dioxide (CO2) enhanced oil recovery is the most economical technique for carbon capture, usage, and storage. In depleted reservoirs, full or near-miscibility of injected CO2 with oil is difficult to achieve, and immiscible CO2 injection leaves a large volume of oil behind and limits available pore volume (PV) for storing CO2. In this paper, we present an experimental study to delineate the effect of ethanol-treated CO2 injection on oil recovery, net CO2 stored, and amount of ethanol left in the reservoir. We inject CO2 and ethanol-treated CO2 into Bentheimer Sandstone cores representing reservoirs. The oil phase consists of a mixture of 0.65 hexane and 0.35 decane (C6-C10 mixture) by molar fraction in one set of experimental runs, and pure decane (C10) in the other set of experimental runs. All experimental runs are conducted at constant temperature 70°C and various pressures to exhibit immiscibility (9.0 MPa for the C6-C10 mixture and 9.6 MPa for pure C10) or near-miscibility (11.7 MPa for the C6-C10 mixture and 12.1 MPa for pure C10). Pressure differences across the core, oil recovery, and compositions and rates of the produced fluids are recorded during the experimental runs. Ultimate oil recovery under immiscibility is found to be 9 to 15% greater using ethanol-treated CO2 injection than that using pure CO2 injection. Net CO2 stored for pure C10 under immiscibility is found to be 0.134 PV greater during ethanol-treated CO2 injection than during pure CO2 injection. For the C6-C10 mixture under immiscibility, both ethanol-treated CO2 injection and CO2 injection yield the same net CO2 stored. However, for the C6-C10 mixture under near-miscibility,ethanol-treated CO2 injection is found to yield 0.161 PV less net CO2 stored than does pure CO2 injection. These results suggest potential improvement in oil recovery and net CO2 stored using ethanol-treated CO2 injection instead of pure CO2 injection. If economically viable, ethanol-treated CO2 injection could be used as a carbon capture, usage, and storage method in low-pressure reservoirs, for which pure CO2 injection would be infeasible.

Carbon Dioxide Corrosion and Corrosion Prevention of Oil Well Cement Paste Matrix in Deep Wells

2014 ◽  
Vol 692 ◽  
pp. 433-438 ◽  
Author(s):  
Jing Fu Zhang ◽  
Jin Long Yang ◽  
Kai Liu ◽  
Bo Wang ◽  
Rui Xue Hou
Keyword(s):  
Carbon Dioxide ◽  
Compressive Strength ◽  
Cement Paste ◽  
Oil Wells ◽  
Oil Well ◽  
Cement Slurry ◽  
Corrosion Prevention ◽  
Oil Well Cement ◽  
Oil Well Cement Paste ◽  
Well Cement

Carbon dioxide CO2could corrode the oil well cement paste matrix under agreeable moisture and pressure condition in deep oil wells, which could decrease the compressive strength and damage the annular seal reliability of cement paste matrix. The problem of oil well cement paste matrix corrosion by CO2was researched in the paper for obtain the feasible corrosion prevention technical measures. The microstructure and compressive strength of corroded cement paste matrix were examined by scanning electron microscopeSEMand strength test instrument etc. under different corrosion conditions. The mechanism and effect law of corrosion on oil well cement paste matrix by CO2were analyzed. And the suitable method to protect CO2corrosion in deep oil wells was explored. The results show that the corrosion mechanism of cement paste matrix by CO2was that the wetting phase CO2could generate chemical reaction with original hydration products produced from cement hydration, which CaCO3were developed and the original composition and microstructure of cement paste matrix were destroyed. The compressive strength of corrosion cement paste matrix always was lower than that of un-corrosion cement paste matrix. The compressive strength of corrosion cement paste matrix decreased with increase of curing temperature and differential pressure. The corroded degree of cement paste matrix was intimately related with the compositions of cement slurry. Developing and design anti-corrosive cement slurry should base on effectively improving the compact degree and original strength of cement paste matrix. The compounding additive R designed in the paper could effectively improve the anti-corrosive ability of cement slurry.

Synthesis and performance of a self crosslinkable acrylate copolymer with high compatibility for an oil well cement modifier

2014 ◽  
Vol 34 (5) ◽  
pp. 405-413
Author(s):  
Xianru He ◽  
Qian Chen ◽  
Chunhui Feng ◽  
Liang Wang ◽  
Hailong Hou
Keyword(s):  
High Performance ◽  
Oil And Gas ◽  
High Strength ◽  
Ammonium Persulfate ◽  
Fluid Loss ◽  
Oil Well ◽  
Cement Slurry ◽  
Oil Well Cement ◽  
Well Cement ◽  
Loss Control

Abstract High performance cement slurry polymer modifiers are increasingly in demand in the cementing process of oil and gas. A new polymer modifier with outstanding fluid loss control and high strength and toughness was synthesized by the main monomers butyl acrylate (BA), methyl methacrylate (MMA), acrylamide (AM), the functional monomers vinyltriethoxysilane (VTS), glycidyl methacrylate (GMA) and the initiator of ammonium persulfate (APS) through emulsion polymerization. By using Fourier transform infrared (FTIR) spectrometer, a laser particle analyzer, a scanning electron microscope and a differential scanning calorimeter, we studied the mechanism of fluid loss control and microstructure of polymer latex cement slurries. The experimental results showed that the copolymer could be crosslinked at 160°C and have the lowest fluid loss control, 12 ml, when the polymer content reached 5%. Acrylate latex modified by the silane coupling agent VTS had excellent performance on fluid loss control, as well as mechanical properties for oil well cement. These results have a potential significant value for the development of a new polymer cement modifier with high thermal stability and durability.

THE DEVELOPMENT OF THE TIRRAWARRA OIL AND GAS FIELD

1984 ◽  
Vol 24 (1) ◽  
pp. 278
Author(s):  
H. T. Pecanek ◽  
I. M. Paton
Keyword(s):  
Carbon Dioxide ◽  
Oil And Gas ◽  
Gas Injection ◽  
Oil Field ◽  
Oil Reservoir ◽  
Gas Reservoirs ◽  
Gas Field ◽  
Associated Gas ◽  
Oil And Gas Field ◽  
Cooper Basin

The Tirrawarra Oil and Gas Field, discovered in 1970 in the South Australian portion of the Cooper Basin, is the largest onshore Permian oil field in Australia. Development began in 1981 as part of the $1400 million Cooper Basin Liquids ProjectThe field is contained within a broad anticline bisected by a north-south sealing normal fault. This fault divides the Tirrawarra oil reservoir into the Western and Main oil fields. Thirty-four wells have been drilled, intersecting ten Patchawarra Formation sandstone gas reservoirs and the Tirrawarra Sandstone oil reservoir. Development drilling discovered three further sandstone gas reservoirs in the Toolachee Formation.The development plan was based on a seven-spot pattern to allow for enhanced oil recovery by miscible gas drive. The target rates were 5400 barrels of oil (860 kilolitres) per day with 13 million ft3 (0.37 million m3) per day of associated gas and 70 million ft3 (2 million m') per day of wet, non-associated gas. Evaluation of early production tests showed rapid decline. The 100 ft (30 m) thick, low-permeability Tirrawarra oil reservoir was interpreted as an ideal reservoir for fracture treatment and as a result all oil wells have been successfully stimulated, with significant improvement in well production rates.The oil is highly volatile but miscibility with carbon dioxide has been proven possible by laboratory tests, even though the reservoir temperature is 285°F (140°C). Pilot gas injection will assess the feasibility of a larger-scale field-wide pressure maintenance scheme using miscible gas. Riot gas injection wells will use Tirrawarra Field Patchawarra Formation separator gas to defer higher infrastructure costs associated with the alternative option of piping carbon dioxide from Moomba, the nearest source.

Simulation of Two-Phase Flow in Carbon Dioxide Injection Wells

2011 ◽  
Author(s):  
Lawrence J. Pekot ◽  
Pierre Petit ◽  
Yasmin Adushita ◽  
Stephanie Saunier ◽  
Rohan Lakdasa De Silva
Keyword(s):  
Carbon Dioxide ◽  
Two Phase Flow ◽  
Phase Flow ◽  
Carbon Dioxide Injection ◽  
Injection Wells ◽  
Two Phase

scholarly journals Improving the Iraqi Oil Well Cement Properties Using Barolift: an Experimental Investigation

2021 ◽  
pp. 147-156
Author(s):  
Ali M. Hadi ◽  
Ayad A. Al-Haleem
Keyword(s):  
Compressive Strength ◽  
Oil And Gas ◽  
Free Water ◽  
American Petroleum Institute ◽  
Oil Well ◽  
Cement Slurry ◽  
X Ray ◽  
Gas Drilling ◽  
Drilling Operations ◽  
Well Cement

Cement is a major component in oil and gas drilling operations that is used to maintain the integrity of boreholes by preventing the movement of formation fluids through the annular space and outside the casing. In 2019, Iraq National Oil Company ordered all international oil and gas companies which are working in Iraq to use Iraqi cement (made in Iraq) in all Iraqi oil fields; however, the X-ray fluorescence (XRF) and compressive strength results in this study show that this cement is not matching with American Petroleum Institute (API) standards. During this study, barolift was used to improve the properties of Iraqi cement used in oil wells at high pressure and high temperature (HPHT). Barolift (1 g) was added to cement admixture to evaluate its influence on improving the performance of cement, mainly related to the property of toughness.  Primarily, the quality and quantity of cement contents were determined using X-ray fluorescence. Experiments were conducted to examine the characteristics of the base cement and the cement system containing 1g of barolift, such as thickening time, free water, compressive strength, and porosity. X-ray diffraction (XRD), scanning electron microscope (SEM), and energy dispersive X-ray spectroscopy (EDS) were conducted for analyzing the microstructure of cement powder. The experimental results showed that barolift acted as a retarder and improved the thickening time, slightly increased the free water, enhanced the mechanical properties, reduced the porosity, and aided in scheming new cement slurry to withstand the HPHT conditions. Microstructure analysis showed that barolift particles blocked the capillaries by filling cement spaces and, thus, a denser and stricter cement network was achieved.

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