scholarly journals Novel Graphitic Structures by Design

Author(s):  
Jonathon Phillips ◽  
Zayd C. Leseman ◽  
Joseph Cordaro ◽  
Claudia Luhrs ◽  
Marwan Al-Haik

Graphitic Structures by Design (GSD) is a novel technology for growing graphite in precise patterns from the nano to the macroscale, rapidly (>1 layer/sec), at low temperatures (ca. 500°C), and in a single step using ordinary laboratory equipment. The GSD process consists of exposing particular metals (Ni, Pd, Pt, Co), which act as ‘templates’, to a fuel rich combustion environment. As an example, we have thoroughly characterized graphite growth on nickel in a mixture of ethylene and oxygen (O2/C2H4 ratio<3), and found that it grows in a geometry remarkably consistent with the shape of the metal template at a rate of the order one graphene layer/second at temperatures between about 500 and 700°C. Graphite structures created with GSD to date include two dimensional ‘screens’ that are inches in extent, yet are composed of micron scale squares graphite foam, hollow nanoparticles, and micron scale particles. All alternative technologies for graphite growth require specialty equipment, such as 2000 °C + ovens, and multiple steps. The alternatives are also not suited for a wide variety of pattern growth in either two or three dimensions. We propose to change focus from demonstrating GSD to determination of the mechanism of graphite growth. GSD could meet a number of recognized technological needs for future generation integrated circuits (IC). Precise patterns of oriented graphite are envisioned as: i) replacements of carbon fibers as structural elements in some aerospace and transport applications, ii) as heat conductive pathways aiding thermal management in ICs iii) as electrical conduits in ICs, iv) as the basic elements of nano-scale logic circuits. GSD graphite is arguably superior to the older and more broadly studied carbon nanotubes technology for all these IC applications for many reasons: only GSD be grown in any pattern on any surface, GSD is far cleaner (no metal residue in the graphite structure, in contrast to nanotubes), GSD structures can be formed consistently and cheaply, at low temperature, and only GSD can be readily grown into large designed macrostructures required for some heat transfer applications.

Author(s):  
P. E. Batson ◽  
C. H. Chen ◽  
J. Silcox

We wish to report in this paper measurements of the inelastic scattering component due to the collective excitations (plasmons) and single particlehole excitations of the valence electrons in Al. Such scattering contributes to the diffuse electronic scattering seen in electron diffraction patterns and has recently been considered of significance in weak-beam images (see Gai and Howie) . A major problem in the determination of such scattering is the proper correction for multiple scattering. We outline here a procedure which we believe suitably deals with such problems and report the observed single scattering spectrum.In principle, one can use the procedure of Misell and Jones—suitably generalized to three dimensions (qx, qy and #x2206;E)--to derive single scattering profiles. However, such a computation becomes prohibitively large if applied in a brute force fashion since the quasi-elastic scattering (and associated multiple electronic scattering) extends to much larger angles than the multiple electronic scattering on its own.


2014 ◽  
Vol 62 (1) ◽  
pp. 129-137
Author(s):  
A. Sawicki ◽  
J. Mierczyński

Abstract A basic set of experiments for the determination of mechanical properties of sands is described. This includes the determination of basic physical and mechanical properties, as conventionally applied in soil mechanics, as well as some additional experiments, which provide further information on mechanical properties of granular soils. These additional experiments allow for determination of steady state and instability lines, stress-strain relations for isotropic loading and pure shearing, and simple cyclic shearing tests. Unconventional oedometric experiments are also presented. Necessary laboratory equipment is described, which includes a triaxial apparatus equipped with local strain gauges, an oedometer capable of measuring lateral stresses and a simple cyclic shearing apparatus. The above experiments provide additional information on soil’s properties, which is useful in studying the following phenomena: pre-failure deformations of sand including cyclic loading compaction, pore-pressure generation and liquefaction, both static and caused by cyclic loadings, the effect of sand initial anisotropy and various instabilities. An important feature of the experiments described is that they make it possible to determine the initial state of sand, defined as either contractive or dilative. Experimental results for the “Gdynia” model sand are shown.


Author(s):  
Ferrari Colin ◽  
Resongles Eléonore ◽  
Freydier Rémi ◽  
Casiot Corinne

Thiol-functionalized silica powder allowed single-step purification of antimony for exploring stable Sb isotope signatures in the environment.


2021 ◽  
Vol 11 (3) ◽  
pp. 933
Author(s):  
Mario Lucido

The method of analytical preconditioning combines the discretization and the analytical regularization of a singular integral equation in a single step. In a recent paper by the author, such a method has been applied to a spectral domain integral equation formulation devised to analyze the propagation in polygonal cross-section microstrip lines, which are widely used as high-speed interconnects in monolithic microwave and millimeter waves integrated circuits. By choosing analytically Fourier transformable expansion functions reconstructing the behavior of the fields on the wedges, fast convergence is achieved, and the convolution integrals are expressed in closed form. However, the coefficient matrix elements are one-dimensional improper integrals of oscillating and, in the worst cases, slowly decaying functions. In this paper, a novel technique for the efficient evaluation of such kind of integrals is proposed. By means of a procedure based on Cauchy integral theorem, the general coefficient matrix element is written as a linear combination of fast converging integrals. As shown in the numerical results section, the proposed technique always outperforms the analytical asymptotic acceleration technique, especially when highly accurate solutions are required.


Micromachines ◽  
2021 ◽  
Vol 12 (5) ◽  
pp. 541
Author(s):  
Muhammad Imran Khan ◽  
Ahmed S. Alshammari ◽  
Badr M. Alshammari ◽  
Ahmed A. Alzamil

This work deals with the analysis of spectrum generation from advanced integrated circuits in order to better understand how to suppress the generation of high harmonics, especially in a given frequency band, to design and implement noise-free systems. At higher frequencies, the spectral components of signals with sharp edges contain more energy. However, current closed-form expressions have become increasingly unwieldy to compute higher-order harmonics. The study of spectrum generation provides an insight into suppressing higher-order harmonics (10th order and above), especially in a given frequency band. In this work, we discussed the influence of transistor model quality and input signal on estimates of the harmonic contents of switching waveforms. Accurate estimates of harmonic contents are essential in the design of highly integrated micro- and nanoelectromechanical systems. This paper provides a comparative analysis of various flip-flop/latch topologies on different process technologies, i.e., 130 and 65 nm. An FFT plot of the simulated results signifies that the steeper the spectrum roll-off, the lesser the content of higher-order harmonics. Furthermore, the results of the comparison illustrate the improvement in the rise time, fall time, clock-Q delay and spectrum roll-off on the better selection of slow-changing input signals and more accurate transistor models.


Author(s):  
Amin Najafi ◽  
Mohammad Saeed Seif

Determination of high-speed crafts’ hydrodynamic coefficients will help to analyze the dynamics of these kinds of vessels and the factors affecting their dynamic stabilities. Also, it can be useful and effective in controlling the vessel instabilities. The main purpose of this study is to determine the coefficients of longitudinal motions of a planing catamaran with and without a hydrofoil using Reynolds-averaged Navier–Stokes method to evaluate the foil effects on them. Determination of hydrodynamic coefficients by experimental approach is costly and requires meticulous laboratory equipment; therefore, utilizing the numerical methods and developing a virtual laboratory seem highly efficient. In this study, the numerical results for hydrodynamic coefficients of a high-speed craft are verified against Troesch’s experimental results. In the following, after determination of hydrodynamic coefficients of a planing catamaran with and without foil, the foil effects on its hydrodynamic coefficients are evaluated. The results indicate that most of the coefficients are frequency-independent especially at high frequencies.


1997 ◽  
Vol 786 (1) ◽  
pp. 99-106 ◽  
Author(s):  
Travis H. Tani ◽  
Jamie M. Moore ◽  
Thomas W. Patapoff

Sign in / Sign up

Export Citation Format

Share Document