Thermochemical Upgrading of Calcium Bentonite for Drilling Fluid Applications

2018 ◽  
Vol 141 (4) ◽  
Author(s):  
Musaab Magzoub ◽  
Mohamed Mahmoud ◽  
Mustafa Nasser ◽  
Ibnelwaleed Hussein ◽  
Salaheldin Elkatatny ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Drilling Fluid ◽  
Exchange Process ◽  
Thermochemical Treatment ◽  
Drilling Fluids ◽  
Wet Process ◽  
Swelling Capacity ◽  
Sodium Activation ◽  
The One ◽  
Calcium Bentonite

The rheological properties of bentonite suspensions depend on the chemical composition and the contained dominant element, such as calcium (Ca), potassium (K), and sodium (Na). Na-bentonite type is the one used in drilling fluids, because it has good dispersion stability, high swelling capacity, and outstanding rheological properties. Ca-bentonite generally has bad rheological performance; however, it can be activated by sodium to be used in drilling fluids, since there are huge unutilized Ca-bentonite resources. Many previous attempts of activation of Ca-bentonite were not feasible, upgrading required addition of many extra additives or sometimes mixed with commercial Na-bentonite to improve its properties. In this paper, a process of integrated beneficiation method is designed to efficiently remove the nonclay impurities and produce pure Ca-bentonite. An upgraded Ca-bentonite was produced using a combined thermochemical treatment in a wet process by adding 4 wt % of soda ash (Na2CO3) while heating and stirring. The new thermal treatment optimized and described in this study greatly improved the sodium activation and ions exchange process and improved bentonite properties. The thermochemically upgraded Ca-bentonite outperformed the rheological properties of the commercial bentonite. And when tested in a typical drilling fluid formulation at high temperature, the investigations showed an identical behavior of the commercial drilling grade bentonite. Moreover, the results obtained showed that the thermochemically upgraded Ca-bentonite has higher yield point/plastic viscosity (YP/PV) ratio than commercial Na-bentonite when mixed with the drilling fluid additives. Higher YP/PV ratio is expected to enhance the hole cleaning and prevent most of the drilling problems.

Improving the rheological properties of water-based calcium bentonite drilling fluids using water-soluble polymers in high temperature applications

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jinliang Liu ◽  
Fengshan Zhou ◽  
Fengyi Deng ◽  
Hongxing Zhao ◽  
Zhongjin Wei ◽  
...  
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
Apparent Viscosity ◽  
Drilling Fluid ◽  
Shear Thickening ◽  
Water Soluble ◽  
Drilling Fluids ◽  
Drilling Depth ◽  
Filtration Loss ◽  
Calcium Bentonite

Abstract Most of bentonite used in modern drilling engineering is physically and chemically modified calcium bentonite. However, with the increase of drilling depth, the bottom hole temperature may reach 180 °C, thus a large amount of calcium bentonite used in the drilling fluid will be unstable. This paper covers three kinds of calcium bentonite with poor rheological properties at high temperature, such as apparent viscosity is greater than 45 mPa·s or less than 10 mPa·s, API filtration loss is greater than 25 mL/30 min, which are diluted type, shear thickening type and low-shear type, these defects will make the rheological properties of drilling fluid worse. The difference is attributed to bentonite mineral composition, such as montmorillonite with good hydration expansion performance. By adding three kinds of heat-resistant water-soluble copolymers Na-HPAN (hydrolyzed polyacrylonitrile sodium), PAS (polycarboxylate salt) and SMP (sulfomethyl phenolic resin), the rheological properties of calcium bentonite drilling fluids can be significantly improved. For example, the addition of 0.1 wt% Na-HPAN and 0.1 wt% PAS increased the apparent viscosity of the XZJ calcium bentonite suspension from 4.5 to 19.5 mPa·s at 180 °C, and the filtration loss also decreased from 20.2 to 17.8 mL.

Annular Frictional Pressure Losses During Drilling—Predicting the Effect of Drillstring Rotation

2014 ◽  
Vol 136 (3) ◽  
Author(s):  
Arild Saasen
Keyword(s):  
Rheological Properties ◽  
Pressure Loss ◽  
Drilling Fluid ◽  
Axial Flow ◽  
Drilling Fluids ◽  
Unstable Flow ◽  
Pressure Losses ◽  
Shear Dependent Viscosity ◽  
Water Based ◽  
Dependent Viscosity

Controlling the annular frictional pressure losses is important in order to drill safely with overpressure without fracturing the formation. To predict these pressure losses, however, is not straightforward. First of all, the pressure losses depend on the annulus eccentricity. Moving the drillstring to the wall generates a wider flow channel in part of the annulus which reduces the frictional pressure losses significantly. The drillstring motion itself also affects the pressure loss significantly. The drillstring rotation, even for fairly small rotation rates, creates unstable flow and sometimes turbulence in the annulus even without axial flow. Transversal motion of the drillstring creates vortices that destabilize the flow. Consequently, the annular frictional pressure loss is increased even though the drilling fluid becomes thinner because of added shear rate. Naturally, the rheological properties of the drilling fluid play an important role. These rheological properties include more properties than the viscosity as measured by API procedures. It is impossible to use the same frictional pressure loss model for water based and oil based drilling fluids even if their viscosity profile is equal because of the different ways these fluids build viscosity. Water based drilling fluids are normally constructed as a polymer solution while the oil based are combinations of emulsions and dispersions. Furthermore, within both water based and oil based drilling fluids there are functional differences. These differences may be sufficiently large to require different models for two water based drilling fluids built with different types of polymers. In addition to these phenomena washouts and tool joints will create localised pressure losses. These localised pressure losses will again be coupled with the rheological properties of the drilling fluids. In this paper, all the above mentioned phenomena and their consequences for annular pressure losses will be discussed in detail. North Sea field data is used as an example. It is not straightforward to build general annular pressure loss models. This argument is based on flow stability analysis and the consequences of using drilling fluids with different rheological properties. These different rheological properties include shear dependent viscosity, elongational viscosity and other viscoelastic properties.

Development of Digital Twins for Drilling Fluids: Local Velocities for Hole Cleaning and Rheology Monitoring

2021 ◽  
Author(s):  
Mehrdad Gharib Shirangi ◽  
Roger Aragall ◽  
Reza Ettehadi ◽  
Roland May ◽  
Edward Furlong ◽  
...  
Keyword(s):  
Machine Learning ◽  
Rheological Properties ◽  
Drilling Fluid ◽  
Training Data ◽  
Drilling Fluids ◽  
Hole Cleaning ◽  
Digital Twins ◽  
Wide Range ◽  
Drilling Operations ◽  
Cuttings Bed

Abstract In this work, we present our advances to develop and apply digital twins for drilling fluids and associated wellbore phenomena during drilling operations. A drilling fluid digital twin is a series of interconnected models that incorporate the learning from the past historical data in a wide range of operational settings to determine the fluids properties in realtime operations. From several drilling fluid functionalities and operational parameters, we describe advancements to improve hole cleaning predictions and high-pressure high-temperature (HPHT) rheological properties monitoring. In the hole cleaning application, we consider the Clark and Bickham (1994) approach which requires the prediction of the local fluid velocity above the cuttings bed as a function of operating conditions. We develop accurate computational fluid dynamics (CFD) models to capture the effects of rotation, eccentricity and bed height on local fluid velocities above cuttings bed. We then run 55,000 CFD simulations for a wide range of operational settings to generate training data for machine learning. For rheology monitoring, thousands of lab experiment records are collected as training data for machine learning. In this case, the HPHT rheological properties are determined based on rheological measurement in the American Petroleum Institute (API) condition together with the fluid type and composition data. We compare the results of application of several machine learning algorithms to represent CFD simulations (for hole cleaning application) and lab experiments (for monitoring HPHT rheological properties). Rotating cross-validation method is applied to ensure accurate and robust results. In both cases, models from the Gradient Boosting and the Artificial Neural Network algorithms provided the highest accuracy (about 0.95 in terms of R-squared) for test datasets. With developments presented in this paper, the hole cleaning calculations can be performed more accurately in real-time, and the HPHT rheological properties of drilling fluids can be estimated at the rigsite before performing the lab experiments. These contributions advance digital transformation of drilling operations.

Characterization of the Rheological Behavior of Drilling Fluids

2020 ◽  
Author(s):  
Eric Cayeux ◽  
Amare Leulseged
Keyword(s):  
Shear Rate ◽  
Rheological Behavior ◽  
Drilling Fluid ◽  
Drilling Fluids ◽  
Shear Rates ◽  
Operation Conditions ◽  
Fluid Systems ◽  
Different Temperatures ◽  
The One ◽  
Shear Stress Response

Abstract It is nowadays well accepted that the steady state rheological behavior of drilling fluids must be modelled by at least three parameters. One of the most often used models is the yield power law, also referred as the Herschel-Bulkley model. Other models have been proposed like the one from Robertson-Stiff, while other industries have used other three-parameter models such as the one from Heinz-Casson. Some studies have been made to compare the degree of agreement between different rheological models and rheometer measurements but in most cases, already published works have only used mechanical rheometers that have a limited number of speeds and precision. For this paper, we have taken measurements with a scientific rheometer in well-controlled conditions of temperature and evaporation, and for relevant shear rates that are representative to normally encountered drilling operation conditions. Care has been made to minimize the effect of thixotropy on measurements, as the shear stress response of drilling fluids depends on its shear history. Measurements have been made at different temperatures, for various drilling fluid systems (both water and oil-based), and with variable levels of solid contents. Also, the shear rate reported by the rheometer itself, is corrected to account for the fact that the rheometer estimates the wall shear rate on the assumption that the tested fluid is Newtonian. A measure of proximity between the measurements and a rheological model is defined, thereby allowing the ranking of different rheological behavior model candidates. Based on the 469 rheograms of various drilling fluids that have been analyzed, it appears that the Heinz-Casson model describes most accurately the rheological behavior of the fluid samples, followed by the model of Carreau, Herschel-Bulkley and Robertson-Stiff, in decreasing order of fidelity.

Method and Mechanism of Regulating Rheological Properties of Water-Based Drilling Fluid by High-Frequency and High-Voltage Alternating Current Electric Field

SPE Journal ◽  
2020 ◽  
Vol 25 (05) ◽  
pp. 2220-2233
Author(s):  
Weian Huang ◽  
Ming Lei ◽  
Jingwen Wang ◽  
Kaihe Lv ◽  
Lin Jiang ◽  
...  
Keyword(s):  
Electric Field ◽  
Rheological Properties ◽  
High Voltage ◽  
High Frequency ◽  
Pulse Width ◽  
Drilling Fluid ◽  
Width Ratio ◽  
Drilling Fluids ◽  
Water Based ◽  
Bentonite Suspension

Summary The rheology of drilling fluid is commonly regulated by chemical methods. In this work, a physical method of a high-frequency and high-voltage alternating current (AC) electric field to regulate the rheological properties of water-based drilling fluid is established. The effects of the electric field on the continuous phase and dispersed phase, as well as two kinds of water-based drilling fluids, were investigated, and the response relationship among rheological properties modeled by Bingham and Herschel-Bulkley (H-B) models and electric-field parameters was explored. Results showed that water conductivity increased when voltage reached 4 kV, whereas it was restored to the original state after 3 hours in the absence of an electric field, showing a memory effect. The effect was also observed on bentonite suspension, whose plastic viscosity increased with the aid of an electric field and decreased over time. Voltage showed the greatest effect on bentonite-suspension viscosity, followed by frequency and pulse-width ratio. Under the condition of voltage of 5 kV, frequency of 5 kHz, and pulse-width ratio of 80%, there was a maximum increase of 50% in viscosity. The addition of salts caused bentonite-suspension flocculation, and electric field reduced the consistency coefficient and relieved flocculation state. When polymers were incorporated in bentonite suspension, the electric field could decrease the adsorption amount between clay particles and polymeric additives such as amphoteric and acrylamide-based polymers. For two typical drilling fluids, the voltage of an introduced electric field was the main controlling factor to change the rheological properties; their plastic viscosity and consistency coefficient both started to increase when voltage reached 4 kV.

Nano-Enhanced Drilling Fluids: Pioneering Approach to Overcome Uncompromising Drilling Problems

2011 ◽  
Vol 134 (1) ◽  
Author(s):  
J. Abdo ◽  
M. Danish Haneef
Keyword(s):  
Rheological Properties ◽  
Size Distribution ◽  
Oil And Gas ◽  
Drilling Fluid ◽  
Drilling Fluids ◽  
Lost Circulation ◽  
Drilling Operations ◽  
Cost Efficient ◽  
A Chain ◽  
Size Distribution Of Particles

The idea of pushing the limits of drilling oil and gas wells by improving drilling fluids for undemanding and cost efficient drilling operations by extracting advantage from the wonders of nanotechnology forms the basis of the work presented here. Foremost, in order to highlight the significance of reducing the size distribution of particles, new clay ATR which has a chain like structure and offers enormous surface area and increased reactivity was tested in different sizes that were chemically and mechanically milled. Bentonite which is a commonly used drilling fluid additive was also tested in different particle size distribution (PSD) and rheological properties were tested. Significant reduction in viscosity with small sized particles was recorded. The tested material called ATR throughout this paper is shown to offer better functionality than bentonite without the requirement of other expensive additives. Experiments were performed with different size distributions and compositions and drastic changes in rheological properties are observed. A detailed investigation of the shear thinning behavior was also carried out with ATR samples in order to confirm its functionality for eliminating the problem of mechanical and differential pipe sticking, while retaining suitable viscosity and density for avoidance of problems like lost circulation, poor hole cleaning and inappropriate operating hydrostatic pressures.

Real-Time Determination of Rheological Properties of Spud Drilling Fluids Using a Hybrid Artificial Intelligence Technique

2019 ◽  
Vol 141 (3) ◽  
Author(s):  
Khaled Abdelgawad ◽  
Salaheldin Elkatatny ◽  
Tamer Moussa ◽  
Mohamed Mahmoud ◽  
Shirish Patil
Keyword(s):  
Rheological Properties ◽  
Apparent Viscosity ◽  
Drilling Fluid ◽  
Differential Evolution Algorithm ◽  
Percentage Error ◽  
Drilling Fluids ◽  
Rheological Parameter ◽  
Ann Model ◽  
Hole Cleaning ◽  
Ann Models

The rheological properties of the drilling fluid play a key role in controlling the drilling operation. Knowledge of drilling fluid rheological properties is very crucial for drilling hydraulic calculations required for hole cleaning optimization. Measuring the rheological properties during drilling sometimes is a time-consuming process. Wrong estimation of these properties may lead to many problems, such as pipe sticking, loss of circulation, and/or well control issues. The aforementioned problems increase the non-productive time and the overall cost of the drilling operations. In this paper, the frequent drilling fluid measurements (mud density, Marsh funnel viscosity (MFV), and solid percent) are used to estimate the rheological properties of bentonite spud mud. Artificial neural network (ANN) technique was combined with the self-adaptive differential evolution algorithm (SaDe) to develop an optimum ANN model for each rheological property using 1029 data points. The SaDe helped to optimize the best combination of parameters for the ANN models. For the first time, based on the developed ANN models, empirical equations are extracted for each rheological parameter. The ANN models predicted the rheological properties from the mud density, MFV, and solid percent with high accuracy (average absolute percentage error (AAPE) less than 5% and correlation coefficient higher than 95%). The developed apparent viscosity model was compared with the available models in the literature using the unseen dataset. The SaDe-ANN model outperformed the other models which overestimated the apparent viscosity of the spud drilling fluid. The developed models will help drilling engineers to predict the rheological properties every 15–20 min. This will help to optimize hole cleaning and avoid pipe sticking and loss of circulation where bentonite spud mud is used. No additional equipment or special software is required for applying the new method.

Bentonite Suspension Filtration and its Electro-Kinetics in the Presence of Additives

2021 ◽  
Vol 58 (2) ◽  
pp. 121-126
Author(s):  
R. M. Farag ◽  
A. M. Salem ◽  
A. A. El-Midany ◽  
S. E. El-Mofty
Keyword(s):  
Zeta Potential ◽  
Rheological Properties ◽  
Electrostatic Interactions ◽  
Drilling Fluid ◽  
Colloidal Suspensions ◽  
Drilling Fluids ◽  
Fluid Filtration ◽  
Filtration Loss ◽  
Suspension Filtration ◽  
The Stability

Abstract Invasion of fluids into porous media during drilling can lead to irreparable damage and reduced well productivity. Hence, minimizing the filtration loss of the drilling fluid into the formation is very important. The stability of colloidal suspensions plays a crucial role in controlling the interfacial forces and consequently on minimizing the filtration. The zeta potential is an indicator of the stability of colloids with respect to their electrostatic interactions. In this study, the rheological properties of bentonite suspensions are investigated with and without additives. The starch and CMC were used as additives to enhance the rheological properties of bentonite. The effects of these additives on the drilling fluid filtration were examined. Zeta-potential, viscosity, gel strength and yield point were measured to characterize the extent to which control of the filtration loss of the drilling fluids can be achieved. The zeta-potential and the amount of filtration loss of water-bentonite suspensions were correlated. Finally, the results showed that the addition of either starch or carboxymethyl cellulose (CMC) enhances the filtration properties of water-bentonite suspensions.

Rheological Properties of Barite Sediments in Water-Based Drilling Fluids

2018 ◽  
Author(s):  
Torbjørn Vrålstad ◽  
Ragnhild Skorpa ◽  
Arild Saasen
Keyword(s):  
Rheological Properties ◽  
Drilling Fluid ◽  
Gravity Separation ◽  
Drilling Fluids ◽  
Water Based ◽  
Different Types ◽  
Preliminary Study ◽  
Well Abandonment

When a drilling fluid column remains static over a timeframe of several years, the drilling fluid separates into different sediment phases due to gravity separation. These heavy sediments, entitled “settled barite”, are the cause of significant operational problems several years after drilling. An important problem caused by settled barite occurs when performing casing cut-and-pull operations during slot recovery and well abandonment: the casing is “stuck” due to the sediments in the annulus outside the casing. The consistency and rheological properties of the sediments determine how easily the casing is removed. In this paper, we report a preliminary study were we have artificially prepared gravity sediment phases for two different types of water-based drilling fluids; one KCl/polymer-based fluid and one bentonite-based fluid. By studying the rheological properties of the obtained sediment phases, we see that there are considerable differences between the sediments for these different drilling fluids.

Can Titanium and Copper Oxide Commercial Nanoparticles Be Used for HP/HT Applications? A Comparison With the Very Well Performing Fe3O4 NP

2018 ◽  
Author(s):  
Zisis Vryzas ◽  
Vassilios C. Kelessidis ◽  
Lori Nalbandian ◽  
Vassilios Zaspalis
Keyword(s):  
Iron Oxide ◽  
Copper Oxide ◽  
Rheological Properties ◽  
Yield Stress ◽  
Base Fluid ◽  
Drilling Fluid ◽  
Filter Press ◽  
Fluid Loss ◽  
Drilling Fluids ◽  
Custom Made

Smart drilling fluids, which can change their properties according to the flow environment, must be carefully designed so that they can handle the difficult challenges of HP/HT drilling successfully. Due to their unique physico-chemical properties, nanoparticles (NP) are considered as very good candidates for the formulation of these smart drilling fluids. This study presents filtration and rheological results of newly developed high-performance water-based drilling fluid systems containing different nanoparticles, commercial (C) titanium oxide (TiO2) and commercial (C) copper oxide (CuO) NP and compares them with results from using custom-made (CM) iron oxide (Fe3O4) NP and commercial (C) iron oxide (Fe3O4) NP, previously reported. Novel nano-based drilling fluids were made of de-ionized water, 7 wt% commercial Na-bentonite (base fluid), and NP were added at 0.5 wt%. The rheological properties of the produced suspensions were measured at temperatures up to 60°C and at atmospheric pressure with a Couette-type viscometer. Filtration characteristics were determined at elevated pressures and temperatures in a HP/HT filter press (500 psi/176°C) using ceramic discs as filter media, of permeability, k = 775 mD. The results of this study showed that the samples containing 0.5 wt% C TiO2 caused a reduction in the fluid loss by 23%, while C CuO NP resulted in 16% reduction, when compared to that of the base fluid, at these HPHT conditions. This should be compared to the 47% and 34% reduction in fluid loss of 0.5% CM Fe3O4 NP and of 0.5% of C Fe3O4 NP, reported previously. Analysis of rheological data revealed shear-thinning behavior for all the tested novel drilling fluids. The samples containing TiO2 and CuO NP exhibited a yield stress less than that of the base fluid, compared to the increased yield stress observed for the C and CM Fe3O4 NP. This behavior can be attributed to the fact that TiO2 and CuO NP may also act as deflocculants and prevent the gelation of bentonite suspensions. This study shows that commercial nanoparticles of TiO2 and CuO do not perform as well as the Fe3O4 NP on filtration but provide drilling fluids with lower yield stresses, thus they could be considered as alternatives to Fe3O4 in situations where the rheological properties are critical.

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