Combined Cycles With CO2 Capture: Two Alternatives for System Integration

Author(s):  
Nikolett Sipöcz ◽  
Mohsen Assadi

As carbon capture and storage technology has grown as a promising option to significantly reduce CO2 emissions, system integration and optimization claim an important and crucial role. This paper presents a comparative study of a gas turbine cycle with postcombustion CO2 separation using an amine-based absorption process with monoethanolamine. The study has been made for a triple pressure reheated 400 MWe natural gas-fuelled combined cycle with exhaust gas recirculation (EGR) to improve capture efficiency. Two different options for the energy supply to the solvent regeneration have been evaluated and compared concerning plant performance. In the first alternative heat is provided by steam extracted internally from the bottoming steam cycle, while in the second option an external biomass-fuelled boiler was utilized to generate the required heat. With this novel configuration the amount of CO2 captured can be even more than 100% if the exhaust gas from the biofuelled boiler is mixed and cleaned together with the main exhaust gas flow from the combined cycle. In order to make an unprejudiced comparison between the two alternatives, the reduced steam turbine efficiency has been taken into consideration and estimated, for the alternative with internal steam extraction. The cycles have been modeled in the commercial heat and mass balance program IPSEPRO™ using detailed component models. Utilizing EGR can double the CO2 content of the exhaust gases and reduce the energy need for the separation process by approximately 2% points. Using an external biomass-fuelled boiler as heat source for amine regeneration turns out to be an interesting option due to high CO2 capture effectiveness. However the electrical efficiency of the power plant is reduced compared with the option with internal steam extraction. Another drawback with the external boiler is the higher investment costs but nevertheless, it is flexibility due to the independency from the rest of the power generation system represents a major operational advantage.

Author(s):  
Nikolett Sipo¨cz ◽  
Mohsen Assadi

As Carbon Capture and Storage (CCS) technology has grown as a promising option to significantly reduce CO2 emissions, system integration and optimization claim an important and crucial role. This paper presents a comparative study of a gas turbine cycle with post-combustion CO2 separation using an amine-based absorption process with Monoethanolamine (MEA). The study has been made for a triple pressure reheated 400 MWe natural gas-fuelled combined cycle (NGCC) with exhaust gas recirculation (EGR) to improve capture efficiency. Two different options for the energy supply to the solvent regeneration have been evaluated and compared concerning plant performance. In the first alternative heat is provided by steam extracted internally from the bottoming steam cycle while in the second option an external biomass-fuelled boiler was utilized to generate the required heat. With this novel configuration the amount of CO2 captured can be even more than 100% if the exhaust gas from the bio-fuelled boiler is mixed and cleaned together with the main exhaust gas flow from the combined cycle. In order to make an unprejudiced comparison between the two alternatives, the reduced steam turbine efficiency has been taken into consideration and estimated, for the alternative with internal steam extraction. The cycles have been modelled in the commercial heat and mass balance programme IPSEpro™ using detailed component models. Utilizing EGR can double the CO2 content of the exhaust gases and reduce the energy need for the separation process by approximately 2%-points. Using an external biomass-fuelled boiler as heat source for amine regeneration, turns out to be an interesting option due to high CO2 capture effectiveness. However the electrical efficiency of the power plant is reduced compared to the option with internal steam extraction. Another drawback with the external boiler is the higher investment costs but nevertheless, it is flexibility due to the independency from the rest of the power generation system represents a major operational advantage.


Author(s):  
Klas Jonshagen ◽  
Nikolett Sipöcz ◽  
Magnus Genrup

Most state-of-the-art natural gas-fired combined cycle (NGCC) plants are triple-pressure reheat cycles with efficiencies close to 60%. However, with carbon capture and storage, the efficiency will be penalized by almost 10% units. To limit the energy consumption for a carbon capture NGCC plant, exhaust gas recirculation (EGR) is necessary. Utilizing EGR increases the CO2 content in the gas turbine exhaust while it reduces the flue gas flow to be treated in the capture plant. Nevertheless, due to EGR, the gas turbine will experience a different media with different properties compared with the design case. This study looks into how the turbomachinery reacts to EGR. The work also discusses the potential of further improvements by utilizing pressurized water rather than extraction steam as the heat source for the CO2 stripper. The results show that the required low-pressure level should be elevated to a point close to the intermediate-pressure to achieve optimum efficiency, hence, one pressure level can be omitted. The main tool used for this study is an in-house off-design model based on fully dimensionless groups programmed in the commercially available heat and mass balance program IPSEPRO. The model is based on a GE 109FB machine with a triple-pressure reheat steam cycle.


Author(s):  
Klas Jonshagen ◽  
Nikolett Sipo¨cz ◽  
Magnus Genrup

Most state-of-the-art natural gas fired combined cycle (NGCC) plants are triple-pressure reheat cycles with efficiencies close to 60 percent. However, with carbon capture and storage, the efficiency will be penalized by almost 10 percent units. To limit the energy consumption for a carbon capture NGCC plant, exhaust gas recirculation (EGR) is necessary. Utilizing EGR increases the CO2 content in the gas turbine exhaust while it reduces the flue gas flow to be treated in the capture plant. Nevertheless, due to EGR, the gas turbine will experience a different media with different properties compared to the design case. This study looks into how the turbo machinery reacts to EGR. The work also discusses the potential of further improvements by utilizing pressurized water rather than extraction steam as the heat source for the CO2 stripper. The results show that the required low-pressure level should be elevated to a point close to the intermediate-pressure to achieve optimum efficiency; hence one pressure level can be omitted. The main tool used for this study is an in-house off-design model based on fully dimensionless groups programmed in the commercially-available heat and mass balance program IPSEpro. The model is based on a GE 109FB machine with a triple-pressure reheat steam cycle.


Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 3055 ◽  
Author(s):  
Yue Hu ◽  
Yachi Gao ◽  
Hui Lv ◽  
Gang Xu ◽  
Shijie Dong

Although carbon mitigation in power industry is attracting more and more attention around the world, the large scale application of carbon capture technology is obstructed because of the enormous energy consumption and huge capital investment required. In this study, an integrated system with power generation, CO2 capture and heat supply are proposed, which adopts three measures to reutilize the waste heat released from the CO2 capture process, including extracted steam recirculation, a CO2 Rankine cycle and a radiant floor heat subsystem. Amongst these measures, the radiant floor heat subsystem can efficiently reuse the relatively low temperature waste energy in the absorbent cooler. Through thermodynamic analysis, it is determined that the power output of the new integrated system is 19.48 MW higher compared with the decarbonization Natural Gas Combined Cycle (NGCC) power plant without system integration. On the other hand, 247.59 MW of heat can be recovered through the radiant floor heat subsystem, leading to an improved overall energy efficiency of 73.6%. In terms of the economic performance, the integration requires only 2.6% more capital investment than a decarbonization NGCC power plant without system integration and obtains extra revenue of 3.40 $/MWh from the simultaneous heat supply, which reduces the cost of CO2 avoided by 22.3%. The results prove the economic and efficiency potential of a NGCC power plant integrated with carbon capture, which may promote the industrial demonstration of carbon capture theology.


Author(s):  
Walter W. Shelton ◽  
Robin W. Ames ◽  
Richard A. Dennis ◽  
Charles W. White ◽  
John E. Plunkett ◽  
...  

The U.S. Department of Energy’s (DOE) provides a worldwide leadership role in the development of advanced fossil fuel-based energy conversion technologies, with a focus on electric power generation with carbon capture and storage (CCS). As part of DOE’s Office of Fossil Energy, the National Energy Technology Laboratory (NETL) implements research, development, and demonstration (RD&D) programs that address the challenges of reducing greenhouse gas emissions. To meet these challenges, NETL evaluates advanced power cycles that will maximize system efficiency and performance, while minimizing CO2 emissions and the costs of CCS. NETL’s Hydrogen Turbine Program has sponsored numerous R&D projects in support of Advanced Hydrogen Turbines (AHT). Turbine systems and components targeted for development include combustor technology, materials research, enhanced cooling technology, coatings development, and more. The R&D builds on existing gas turbine technologies and is intended to develop and test the component technologies and subsystems needed to validate the ability to meet the Turbine Program goals. These technologies are key components of AHTs, which enable overall plant efficiency and cost of electricity (COE) improvements relative to an F-frame turbine-based Integrated Gasification Combined Cycle (IGCC) reference plant equipped with carbon capture (today’s state-of-the-art). This work has also provided the basis for estimating future IGCC plant performance based on a Transformational Hydrogen Turbine (THT) with a higher turbine inlet temperature, enhanced material capabilities, reduced air cooling and leakage, and higher pressure ratios than the AHT. IGCC cases from using system-level AHT and THT gas turbine models were developed for comparisons with an F-frame turbine-based IGCC reference case and for an IGCC pathway study. The IGCC pathway is presented in which the reference case (i.e. includes F-frame turbine) is sequentially-modified through the incorporation of advanced technologies. Advanced technologies are considered to be either 2nd Generation or Transformational, if they are anticipated to be ready for demonstration by 2025 and 2030, respectively. The current results included the THT, additional potential transformational technologies related to IGCC plant sections (e.g. air separation, gasification, gas cleanup, carbon capture, NOx reduction) are being considered by NETL and are topics for inclusion in future reports.


Author(s):  
Andrea Ciani ◽  
John P. Wood ◽  
Anders Wickström ◽  
Geir J. Rørtveit ◽  
Rosetta Steeneveldt ◽  
...  

Abstract Today gas turbines and combined cycle power plants play an important role in power generation and in the light of increasing energy demand, their role is expected to grow alongside renewables. In addition, the volatility of renewables in generating and dispatching power entails a new focus on electricity security. This reinforces the importance of gas turbines in guaranteeing grid reliability by compensating for the intermittency of renewables. In order to achieve the Paris Agreement’s goals, power generation must be decarbonized. This is where hydrogen produced from renewables or with CCS (Carbon Capture and Storage) comes into play, allowing totally CO2-free combustion. Hydrogen features the unique capability to store energy for medium to long storage cycles and hence could be used to alleviate seasonal variations of renewable power generation. The importance of hydrogen for future power generation is expected to increase due to several factors: the push for CO2-free energy production is calling for various options, all resulting in the necessity of a broader fuel flexibility, in particular accommodating hydrogen as a future fuel feeding gas turbines and combined cycle power plants. Hydrogen from methane reforming is pursued, with particular interest within energy scenarios linked with carbon capture and storage, while the increased share of renewables requires the storage of energy for which hydrogen is the best candidate. Compared to natural gas the main challenge of hydrogen combustion is its increased reactivity resulting in a decrease of engine performance for conventional premix combustion systems. The sequential combustion technology used within Ansaldo Energia’s GT36 and GT26 gas turbines provides for extra freedom in optimizing the operation concept. This sequential combustion technology enables low emission combustion at high temperatures with particularly high fuel flexibility thanks to the complementarity between its first stage, stabilized by flame propagation and its second (sequential) stage, stabilized by auto-ignition. With this concept, gas turbines are envisaged to be able to provide reliable, dispatchable, CO2-free electric power. In this paper, an overview of hydrogen production (grey, blue, and green hydrogen), transport and storage are presented targeting a CO2-free energy system based on gas turbines. A detailed description of the test infrastructure, handling of highly reactive fuels is given with specific aspects of the large amounts of hydrogen used for the full engine pressure tests. Based on the results discussed at last year’s Turbo Expo (Bothien et al. GT2019-90798), further high pressure test results are reported, demonstrating how sequential combustion with novel operational concepts is able to achieve the lowest emissions, highest fuel and operational flexibility, for very high combustor exit temperatures (H-class) with unprecedented hydrogen contents.


Energies ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1268 ◽  
Author(s):  
Ana-Maria Cormos ◽  
Simion Dragan ◽  
Letitia Petrescu ◽  
Vlad Sandu ◽  
Calin-Cristian Cormos

Decarbonization of energy-intensive systems (e.g., heat and power generation, iron, and steel production, petrochemical processes, cement production, etc.) is an important task for the development of a low carbon economy. In this respect, carbon capture technologies will play an important role in the decarbonization of fossil-based industrial processes. The most significant techno-economic and environmental performance indicators of various fossil-based industrial applications decarbonized by two reactive gas-liquid (chemical scrubbing) and gas-solid CO2 capture systems are calculated, compared, and discussed in the present work. As decarbonization technologies, the gas-liquid chemical absorption and more innovative calcium looping systems were employed. The integrated assessment uses various elements, e.g., conceptual design of decarbonized plants, computer-aided tools for process design and integration, evaluation of main plant performance indexes based on industrial and simulation results, etc. The overall decarbonization rate for various assessed applications (e.g., power generation, steel, and cement production, chemicals) was set to 90% in line with the current state of the art in the field. Similar non-carbon capture plants are also assessed to quantify the various penalties imposed by decarbonization (e.g., increasing energy consumption, reducing efficiency, economic impact, etc.). The integrated evaluations exhibit that the integration of decarbonization technologies (especially chemical looping systems) into key energy-intensive industrial processes have significant advantages for cutting the carbon footprint (60–90% specific CO2 emission reduction), improving the energy conversion yields and reducing CO2 capture penalties.


Author(s):  
S. Can Gülen ◽  
Chris Hall

This paper describes a gas turbine combined cycle (GTCC) power plant system, which addresses the three key design challenges of postcombustion CO2 capture from the stack gas of a GTCC power plant using aqueous amine-based scrubbing method by offering the following: (i) low heat recovery steam generator (HRSG) stack gas temperature, (ii) increased HRSG stack gas CO2 content, and (iii) decreased HRSG stack gas O2 content. This is achieved by combining two bottoming cycle modifications in an inventive manner, i.e., (i) high supplementary (duct) firing in the HRSG and (ii) recirculation of the HRSG stack gas. It is shown that, compared to an existing natural gas-fired GTCC power plant with postcombustion capture, it is possible to reduce the CO2 capture penalty—power diverted away from generation—by almost 65% and the overall capital cost ($/kW) by about 35%.


Author(s):  
James C. Corman ◽  
Douglas M. Todd

The integrated gasification combined cycle (IGCC) concept is gaining acceptance as the Clean Coal technology with the best potential for continued improvement in performance and continued reduction in capital cost. In large part this potential will be realized by optimizing the integration of power generation and fuel conversion subsystems and by exploiting advances in gas turbine technology. This paper discusses the impact that technology advances in the gas turbine combined cycle are having on the commercial viability of the IGCC concept. Technical innovations in such areas as coal gas combustion, plant control, and system integration will ensure that IGCC technology will continue to advance well into the future.


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