scholarly journals Techno-Economic and Environmental Evaluations of Decarbonized Fossil-Intensive Industrial Processes by Reactive Absorption & Adsorption CO2 Capture Systems

Energies ◽  
2020 ◽  
Vol 13 (5) ◽  
pp. 1268 ◽  
Author(s):  
Ana-Maria Cormos ◽  
Simion Dragan ◽  
Letitia Petrescu ◽  
Vlad Sandu ◽  
Calin-Cristian Cormos

Decarbonization of energy-intensive systems (e.g., heat and power generation, iron, and steel production, petrochemical processes, cement production, etc.) is an important task for the development of a low carbon economy. In this respect, carbon capture technologies will play an important role in the decarbonization of fossil-based industrial processes. The most significant techno-economic and environmental performance indicators of various fossil-based industrial applications decarbonized by two reactive gas-liquid (chemical scrubbing) and gas-solid CO2 capture systems are calculated, compared, and discussed in the present work. As decarbonization technologies, the gas-liquid chemical absorption and more innovative calcium looping systems were employed. The integrated assessment uses various elements, e.g., conceptual design of decarbonized plants, computer-aided tools for process design and integration, evaluation of main plant performance indexes based on industrial and simulation results, etc. The overall decarbonization rate for various assessed applications (e.g., power generation, steel, and cement production, chemicals) was set to 90% in line with the current state of the art in the field. Similar non-carbon capture plants are also assessed to quantify the various penalties imposed by decarbonization (e.g., increasing energy consumption, reducing efficiency, economic impact, etc.). The integrated evaluations exhibit that the integration of decarbonization technologies (especially chemical looping systems) into key energy-intensive industrial processes have significant advantages for cutting the carbon footprint (60–90% specific CO2 emission reduction), improving the energy conversion yields and reducing CO2 capture penalties.

Energies ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3840
Author(s):  
Alla Toktarova ◽  
Ida Karlsson ◽  
Johan Rootzén ◽  
Lisa Göransson ◽  
Mikael Odenberger ◽  
...  

The concept of techno-economic pathways is used to investigate the potential implementation of CO2 abatement measures over time towards zero-emission steelmaking in Sweden. The following mitigation measures are investigated and combined in three pathways: top gas recycling blast furnace (TGRBF); carbon capture and storage (CCS); substitution of pulverized coal injection (PCI) with biomass; hydrogen direct reduction of iron ore (H-DR); and electric arc furnace (EAF), where fossil fuels are replaced with biomass. The results show that CCS in combination with biomass substitution in the blast furnace and a replacement primary steel production plant with EAF with biomass (Pathway 1) yield CO2 emission reductions of 83% in 2045 compared to CO2 emissions with current steel process configurations. Electrification of the primary steel production in terms of H-DR/EAF process (Pathway 2), could result in almost fossil-free steel production, and Sweden could achieve a 10% reduction in total CO2 emissions. Finally, (Pathway 3) we show that increased production of hot briquetted iron pellets (HBI), could lead to decarbonization of the steel industry outside Sweden, assuming that the exported HBI will be converted via EAF and the receiving country has a decarbonized power sector.


Energies ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3599 ◽  
Author(s):  
Martinez-Fernandez ◽  
deLlano-Paz ◽  
Calvo-Silvosa ◽  
Soares

Carbon mitigation is a major aim of the power-generation regulation. Renewable energy sources for electricity are essential to design a future low-carbon mix. In this work, financial Modern Portfolio Theory (MPT) is implemented to optimize the power-generation technologies portfolio. We include technological and environmental restrictions in the model. The optimization is carried out in two stages. Firstly, we minimize the cost and risk of the generation portfolio, and afterwards, we minimize its emission factor and risk. By combining these two results, we are able to draw an area which can be considered analogous to the Capital Market Line (CML) used by the Capital Asset Pricing model (CAPM). This area delimits the set of long-term power-generation portfolios that can be selected to achieve a progressive decarbonisation of the mix. This work confirms the relevant role of small hydro, offshore wind, and large hydro as preferential technologies in efficient portfolios. It is necessary to include all available renewable technologies in order to reduce the cost and the risk of the portfolio, benefiting from the diversification effect. Additionally, carbon capture and storage technologies must be available and deployed if fossil fuel technologies remain in the portfolio in a low-carbon approach.


Author(s):  
Olivier Le Galudec ◽  
James Oszewski ◽  
John Preston ◽  
David Thimsen

In the field of Power Generation, Operators — Plant Owners, Utilities, IPPs … — have had to face severe constraints linked not only with price of electricity and cost of fuel, but also with more and more demanding environmental constraints. It appears that the next atmospheric emission coming under scrutiny is CO2. Some small scale laboratory size experiments and pilot scale tests demonstrating the ability to capture CO2 before it reaches the atmosphere have already been conducted, and some industrial scale demonstrators are already at the permitting stage and will soon reach construction. In order to anticipate the needs of Performance Tests within this coming market, ASME decided to form a new committee in order to prepare and deliver ASME Performance Test Code – PTC 48 “Overall Plant Performance with Carbon Capture” test code. This new code may be seen as an evolution of ASME PTC 46 “Performance Test Code on Overall Plant Performance” 1996 (currently under revision), which goes beyond the sole verification of components to provide guidelines for testing a full Plant. Capturing CO2 from fuel–fired power plants will have a significant impact on net capacity and net heat rate of the plant. Such plants will, in addition to the Power Block and Steam Generator, also include systems not commonly included in non-CO2 capture power plants. The addition of an ASU (Air Separation Unit, for oxy-combustion with CO2 capture) and/or CPU (CO2 Purification Unit, for oxy-combustion or post-combustion CO2 capture) has made necessary the preparation of a dedicated test code based upon same guiding principle than PTC 46, i.e. treating the plant globally as a “Black Box”. This approach allows correction of output and efficiency at the plant interfaces, but at the exclusion of internal parameters. It is anticipated that the code can inform development of regulations that define the rules and obligations of Operators. Currently, the proposed PTC 48 aims at fossil fuel fired Steam-electric power plants using either post-combustion CO2 capture or oxy-combustion with CO2 capture technologies. Combined cycles and Integrated Gasification Combined Cycles — IGCCs — are not addressed.


Author(s):  
Ana R. Diaz

The tendency in the world energy demand seems clear: it can only grow. The energetic industry will satisfy this demand-despite all its dialectic about new technologies-at least medium term mostly with current fossil fuel technologies. In this picture from an engineer’s point of view, one of the primary criterions for mitigating the effects of increasing atmospheric concentration of CO2 is to restrict the CO2 fossil fuel emissions into the atmosphere. This paper is focused on the analysis of different CO2 capture technologies for power plants. Indeed, one of the most important goal to concentrate on is the CO2 capture energy requirements, as it dictates the net size of the power plant and, hence, the net cost of power generation with CO2 avoidance technologies. Here, the Author presents a critical review of different CO2 absorption capture technologies. These technologies have been widely analyzed in the literature under chemical and economic points of view, leaving their impact on the energy power plant performance in a second plan. Thus, the central question examined in this paper is the connection between abatement capability and its energetic requirements, which seriously decrease power generation efficiency. Evidencing that the CO2 capture needs additional technical effort and establishing that further developments in this area must be constrained by reducing its energy requirements. After a comprehensive literature revision, six different chemical absorption methods are analyzed based on a simplified energetic model, in order to account for its energetic costs. Furthermore, an application case study is provided where the different CO2 capture systems studied are coupled to a natural gas cogeneration power plant.


Author(s):  
Luca Andreassi ◽  
Daniele Chiappini ◽  
Elio Jannelli ◽  
Stefano Ubertini

The application of high temperature fuel cells in stationary power generation seems to be one of the possible solutions to the problem related to the environment preservation and to the growing interest for distributed electric power generation. Great expectations have been placed on both simple and hybrid fuel cell plants, thus making necessary the evolution of analysis strategies to evaluate thermodynamic performance, design improvements and acceleration of new developments. This paper investigates the thermodynamic potential of combining traditional internal combustion energy systems (i.e. gas turbine and internal combustion engine) with a Molten Carbonate Fuel Cell (MCFC) for medium and low-scale electrical power production with low CO2 emissions. The coupling is performed by placing the fuel cell at the exhaust of the thermal engine. As in MCFCs the oxygen-charge carrier in the electrolyte is the carbonate ion, part of the CO2 in the gas turbine flue gas is moved to the anode and then separated by steam condensation. Plant performance are evaluated in function of different parameters to identify optimal solutions. The results show that the proposed power system can be conveniently used as a source of power generation.


2019 ◽  
Vol 14 (3) ◽  
pp. 453-459
Author(s):  
Dawid P. Hanak ◽  
Vasilije Manovic

AbstractRenewable energy sources and low-carbon power generation systems with carbon capture and storage (CCS) are expected to be key contributors towards the decarbonisation of the energy sector and to ensure sustainable energy supply in the future. However, the variable nature of wind and solar power generation systems may affect the operation of the electricity system grid. Deployment of energy storage is expected to increase grid stability and renewable energy utilisation. The power sector of the future, therefore, needs to seek a synergy between renewable energy sources and low-carbon fossil fuel power generation. This can be achieved via wide deployment of CCS linked with energy storage. Interestingly, recent progress in both the CCS and energy storage fields reveals that technologies such as calcium looping are technically viable and promising options in both cases. Novel integrated systems can be achieved by integrating these applications into CCS with inherent energy storage capacity, as well as linking other CCS technologies with renewable energy sources via energy storage technologies, which will maximise the profit from electricity production, mitigate efficiency and economic penalties related to CCS, and improve renewable energy utilisation.


Author(s):  
Ram G. Narula ◽  
Harvey Wen

Coal is an abundant, widespread, cheap energy source and contributes to 39% of the world’s electric power generation. Coal releases large amounts of carbon dioxide (CO2), which is believed to play a major role in global warming and climate change. To de-carbonize power generation, three distinct carbon capture technologies are in varying stages of development. These include pre-combustion carbon capture through the use of integrated coal gasification combined cycle (IGCC), post-combustion carbon capture from a pulverized-coal (PC)-fired power plant flue gas using monoethanolamine (MEA) or ammonia (NH3), and oxy-combustion technology. In the latter technology, oxygen is first separated from nitrogen in an air separator unit and used for combustion of coal in a conventional PC boiler. With oxy-combustion technology, the resulting flue gas is predominantly CO2, which makes CO2 capture easier than in the PC-MEA case. This paper discusses the development status as well as the advantages, limitations, performance and economics of each technology in regard to the capture and non-capture cases.


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