Microscale Heat Conduction in Dielectric Thin Films

1993 ◽  
Vol 115 (1) ◽  
pp. 7-16 ◽  
Author(s):  
A. Majumdar

Heat conduction in dielectric thin films is a critical issue in the design of electronic devices and packages. Depending on the material properties, there exists a range of film thickness where the Fourier law, used for macroscale heat conduction, cannot be applied. This paper shows that in this microscale regime, heat transport by lattice vibrations or phonons can be analyzed as a radiative transfer problem. Based on Boltzmann transport theory, an equation of phonon radiative transfer (EPRT) is developed. In the acoustically thick limit, ξL ≫ 1, or the macroscale regime, where the film thickness is much larger than the phonon-scattering mean free path, the EPRT reduces to the Fourier law. In the acoustically thin limit, ξL ≪ 1, the EPRT yields the blackbody radiation law q = σ (T14 − T24) at temperatures below the Debye temperature, where q is the heat flux and T1 and T2 are temperatures at the film boundaries. For transient heat conduction, the EPRT suggests that a heat pulse is transported as a wave, which becomes attenuated in the film due to phonon scattering. It is also shown that the hyperbolic heat equation can be derived from the EPRT only in the acoustically thick limit. The EPRT is then used to study heat transport in diamond thin films in wide range of acoustical thicknesses spanning the thin and the thick regimes. The heat flux follows the relation q = 4σT3ΔT/(3ξL/4 + 1) as derived in the modified diffusion approximation for photon radiative transfer. The thermal conductivity, as currently predicted by kinetic theory, causes the Fourier law to overpredict the heat flux by 33 percent when ξL ≪ 1, by 133 percent when ξL = 1, and by about 10 percent when ξL increases to 10. To use the Fourier law in both ballistic and diffusive transport regimes, a simple expression for an effective thermal conductivity is developed.

Author(s):  
Gang Zhang ◽  
Nuo Yang ◽  
Gang Wu ◽  
Baowen Li

In this paper, we report the recent developments in the study of heat transport in nano materials. First of all, we show that phonon transports in nanotube super-diffusively which leads to a length dependence thermal conductivity, thus breaks down the Fourier law. Then we discuss how the introduction of isotope doping can reduce the thermal conductivity efficiently. The theoretical results are in good agreement with experimental ones. Finally, we will demonstrate that nanoscale structures are promising candidates for heat rectification.


Entropy ◽  
2019 ◽  
Vol 21 (12) ◽  
pp. 1200 ◽  
Author(s):  
David Jou ◽  
Liliana Restuccia

We consider heat conduction in a superlattice with mobile defects, which reduce the thermal conductivity of the material. If the defects may be dragged by the heat flux, and if they are stopped at the interfaces of the superlattice, it is seen that the effective thermal resistance of the layers will depend on the heat flux. Thus, the concentration dependence of the transport coefficients plus the mobility of the defects lead to a strongly nonlinear behavior of heat transport, which may be used in some cases as a basis for thermal transistors.


2010 ◽  
Vol 132 (5) ◽  
Author(s):  
Arpit Mittal ◽  
Sandip Mazumder

Abstract The Monte Carlo method has found prolific use in the solution of the Boltzmann transport equation for phonons for the prediction of nonequilibrium heat conduction in crystalline thin films. This paper contributes to the state-of-the-art by performing a systematic study of the role of the various phonon modes on thermal conductivity predictions, in particular, optical phonons. A procedure to calculate three-phonon scattering time-scales with the inclusion of optical phonons is described and implemented. The roles of various phonon modes are assessed. It is found that transverse acoustic (TA) phonons are the primary carriers of energy at low temperatures. At high temperatures (T>200 K), longitudinal acoustic (LA) phonons carry more energy than TA phonons. When optical phonons are included, there is a significant change in the amount of energy carried by various phonons modes, especially at room temperature, where optical modes are found to carry about 25% of the energy at steady state in silicon thin films. Most importantly, it is found that inclusion of optical phonons results in better match with experimental observations for silicon thin-film thermal conductivity. The inclusion of optical phonons is found to decrease the thermal conductivity at intermediate temperatures (50–200 K) and to increase it at high temperature (>200 K), especially when the film is thin. The effect of number of stochastic samples, the dimensionality of the computational domain (two-dimensional versus three-dimensional), and the lateral (in-plane) dimension of the film on the statistical accuracy and computational efficiency is systematically studied and elucidated for all temperatures.


2011 ◽  
Vol 399-401 ◽  
pp. 641-645 ◽  
Author(s):  
Cai Hua Huang ◽  
Xiao Hua Sun ◽  
Yi Hua Sun

Based on the surface morphology, a model is presented to investigate the heat transfer in anodic aluminum oxide (AAO) porous thin films. The extra thermal resistance from the micropores will inevitably cause a change in thermal properties, which can be analyzed by the Fourier law. The effect of the characteristic size on the thermal conductivity is discussed in details by means of the theory of phenomenological model of phonon scattering. Considering the effects of porosity and the distribution of micropores reflected by parameter D, the function of the effective thermal conductivity of AAO porous thin films expressed by two independent variables, εp and D. The temperature field is simulated with the effective thermal conductivity and the result demonstrates a bigger temperature rise in AAO porous thin films.


Author(s):  
Kamal M. Katika ◽  
Laurent Pilon

This study is concerned with the prediction of the effective thermal conductivity of nanocomposite thin films consisting of nanoparticles randomly distributed in a solid matrix. Crystalline sodium chloride with embedded monodisperse silver nanoparticles is investigated as a case study for thin films where phonons are the main heat carriers. To the best of our knowledge, the equation for phonon radiative transfer is solved for the first time with an exact scattering transport cross-section of the nanoparticles as a function of frequency which was obtained from the literature. The one-dimensional equation for phonon radiative transfer based on the isotropic scaling approximation is solved on a spectral basis using the discrete ordinates method to predict the temperature profile and the heat flux across the nanocomposite thin films. The thermal conductivity is retrieved at temperatures where the effects of Umklapp and Normal processes can be neglected and scattering by the particles on phonon transport dominates. The method of solution and closure laws were validated with experimental data of thermal conductivity for bulk samples at 2.53, 5.94, and 10.56 K. The effects of the film thickness (1 μm to 2.5 cm), nanoparticle diameter (5 nm to 100 nm) and volume fraction (0.0001 to 0.2) on the thermal conductivity of the nanocomposite thin film are investigated. The results indicate that the thermal conductivity decreases with decreasing particle radius as well as with increasing particle concentration. Finally, a dimensionless analysis revealed a power law relationship between the dimensionless thermal conductivity and a dimensionless length of the order of the acoustic thickness of the medium. These results can be used to design nanocomposite thin films for various low temperature thermal applications by choosing optimal nanoparticle radius and volume fraction, and film thickness.


2019 ◽  
Vol 2019 ◽  
pp. 1-7 ◽  
Author(s):  
Pornsiri Wanarattikan ◽  
Piya Jitthammapirom ◽  
Rachsak Sakdanuphab ◽  
Aparporn Sakulkalavek

In this work, stoichiometric Sb2Te3 thin films with various thicknesses were deposited on a flexible substrate using RF magnetron sputtering. The grain size and thickness effects on the thermoelectric properties, such as the Seebeck coefficient (S), electrical conductivity (σ), power factor (PF), and thermal conductivity (k), were investigated. The results show that the grain size was directly related to film thickness. As the film thickness increased, the grain size also increased. The Seebeck coefficient and electrical conductivity corresponded to the grain size of the films. The mean free path of carriers increases as the grain size increases, resulting in a decrease in the Seebeck coefficient and increase in electrical conductivity. Electrical conductivity strongly affects the temperature dependence of PF which results in the highest value of 7.5 × 10−4 W/m·K2 at 250°C for film thickness thicker than 1 µm. In the thermal conductivity mechanism, film thickness affects the dominance of phonons or carriers. For film thicknesses less than 1 µm, the behaviour of the phonons is dominant, while both are dominant for film thicknesses greater than 1 µm. Control of the grain size and film thickness is thus critical for controlling the performance of Sb2Te3 thin films.


2009 ◽  
Vol 60-61 ◽  
pp. 430-434 ◽  
Author(s):  
Xing Li Zhang ◽  
Zhao Wei Sun ◽  
Guo Qiang Wu

In this article, we select corresponding Tersoff potential energy to build potential energy model and investigate the thermal conductivities of single-crystal carbon thin-film. The equilibrium molecular dynamics (EMD) method is used to calculate the nanometer thin film thermal conductivity of diamond crystal at crystal direction (001), and the non-equilibrium molecular dynamics (NEMD) is used to calculate the nanometer thin film thermal conductivity of diamond crystal at crystal direction (111). The results of calculations demonstrate that the nanometer thin film thermal conductivity of diamond crystal is remarkably lower than the corresponding bulk experimental data and increase with increasing the film thickness, and the nanometer thin film thermal conductivity of diamond crystal relates to film thickness linearly in the simulative range. The nanometer thin film thermal conductivity also demonstrates certain regularity with the change of temperature. This work shows that molecular dynamics, applied under the correct conditions, is a viable tool for calculating the thermal conductivity of nanometer thin films.


2015 ◽  
Vol 117 (1) ◽  
pp. 015103 ◽  
Author(s):  
Kyeong Hyun Park ◽  
Mohamed Mohamed ◽  
Zlatan Aksamija ◽  
Umberto Ravaioli

2013 ◽  
Vol 209 ◽  
pp. 129-132 ◽  
Author(s):  
Shreya Shah ◽  
Tejal N. Shah ◽  
P.N. Gajjar

The temperature profile, heat flux and thermal conductivity are investigated for the chain length of 67 one-dimensional (1-D) oscillators. FPU-β and FK models are used for interparticle interactions and substrate interactions, respectively. As harmonic chain does not produce temperature gradient along the chain, it is required to introduce anharmonicity in the numerical simulation. The anharmonicity dependent temperature profile, thermal conductivity and heat flux are simulated for different strength of anharmonicity β = 0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1. It is concluded that heat flux obeys J = 0.3947 e0.553β with R2 = 0.9319 and thermal conductivity obeys κ = 0.0276 e0.5559β with R2 = 0.9319.


2006 ◽  
Vol 129 (4) ◽  
pp. 492-499 ◽  
Author(s):  
A. Bulusu ◽  
D. G. Walker

Several new reduced-scale structures have been proposed to improve thermoelectric properties of materials. In particular, superlattice thin films and wires should decrease the thermal conductivity, due to increased phonon boundary scattering, while increasing the local electron density of states for improved thermopower. The net effect should be increased ZT, the performance metric for thermoelectric structures. Modeling these structures is challenging because quantum effects often have to be combined with noncontinuum effects and because electronic and thermal systems are tightly coupled. The nonequilibrium Green’s function (NEGF) approach, which provides a platform to address both of these difficulties, is used to predict the thermoelectric properties of thin-film structures based on a limited number of fundamental parameters. The model includes quantum effects and electron-phonon scattering. Results indicate a 26–90 % decrease in channel current for the case of near-elastic, phase-breaking, electron-phonon scattering for single phonon energies ranging from 0.2 meV to 60 meV. In addition, the NEGF model is used to assess the effect of temperature on device characteristics of thin-film heterojunctions whose applications include thermoelectric cooling of electronic and optoelectronic systems. Results show the predicted Seebeck coefficient to be similar to measured trends. Although superlattices have been known to show reduced thermal conductivity, results show that the inclusion of scattering effects reduces the electrical conductivity leading to a significant reduction in the power factor (S2σ).


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