Development of a Polyimide/SiC-Whisker/Nano-Particles Composite with High Thermal Conductivity and Low Coefficient of Thermal Expansion as Dielectric Layer for Interposer Application

2018 ◽  
Author(s):  
Yunna Sun ◽  
Jiangbo Luo ◽  
Zhuoqing Yang ◽  
Yan Wang ◽  
Guifu Ding ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Dielectric Layer ◽  
Coefficient Of Thermal Expansion ◽  
High Thermal Conductivity ◽  
Nano Particles

Thermal Characteristics of Cu Matrix-SiC Filler Composite Using Nano-Sized Cu Powder

2021 ◽  
Vol 21 (9) ◽  
pp. 4964-4967
Author(s):  
Bok-Hyun Oh ◽  
Choong-Hwan Jung ◽  
Heon Kong ◽  
Sang-Jin Lee
Keyword(s):  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Thermal Expansion Coefficient ◽  
Expansion Coefficient ◽  
Coefficient Of Thermal Expansion ◽  
Liquid Phase Sintering ◽  
High Thermal Conductivity ◽  
Ceramic Filter ◽  
Ceramic Filler ◽  
Significant Difference

A Cu metal-ceramic filter composite with high thermal conductivity and a suitable thermal expansion coefficient was designed to be applied to high performance heat dissipation materials. The purpose of using the ceramic filler was to decrease the high coefficient of thermal expansion of Cu matrix utilizing the high thermal conductivity of Cu. In this study, a SiC ceramic filler powder was added to the Cu sol including Zn as a liquid phase sintering agent. The final complex was produced by applying a PVB polymer to prepare a homogeneous precursor followed by sintering in a reducing atmosphere. The pressureless sintered composite showed lower thermal conductivity than pure bulk Cu due to the some residual pores. In the case of the Cu–SiC composite in which 10 wt% of SiC filler was added, it showed a thermal conductivity of 100 W/m·°C and a thermal expansion coefficient of 13.3×10−6/°C. The thermal conductivity showed some difference from the theoretical calculated value due to the pores in the composite, but the thermal expansion coefficient did not show a significant difference.

Synthesis of Copper/Silicon-Carbide Composites in a Thermodynamic Disequilibrium

2015 ◽  
Vol 825-826 ◽  
pp. 189-196 ◽  
Author(s):  
Maren Klement ◽  
Alwin Nagel ◽  
Oliver Lott
Keyword(s):  
Thermal Conductivity ◽  
Silicon Carbide ◽  
Thermal Expansion ◽  
Coefficient Of Thermal Expansion ◽  
Quantitative Description ◽  
Casting Process ◽  
Heat Sinks ◽  
High Thermal Conductivity ◽  
Structure Property ◽  
Mechanical Loads

Composites with interpenetrating metal-ceramic microstructures (IPC, interpenetrating composites) can be tailored for specific applications, such as high thermal conductivity combined with low thermal expansion, e.g. for heat sinks. Heat sinks are required in power electronic devices or in future fusion reactor technology where extreme conditions and high cyclic thermo-mechanical loads appear. Due to its rigid ceramic backbone IPCs are expected to reveal high thermal stability. Pure silicon carbide exhibits high thermal conductivity, low coefficient of thermal expansion, high corrosion and wear resistance. But it is also known as a very brittle material when mechanical loads are applied. Thus a composite of silicon carbide with ductile and highly conductive copper seems to be a promising new material for a number of applications.This paper reports the synthesis of Cu-SiC composites using a unique high temperature squeeze casting process (HTSC). Microstructural design of SiC-preforms with open porosity and its synthesis progress is reported. Influence of preform properties, temperature, pressure and atmosphere during HTSC were investigated. A qualitative and quantitative description of the microstructure of the composites and their composition allows the creation of structure-property correlations that take effect retroactively to the casting process.

Thermal Conductivity of the Diamond-Cu Composites with Chromium Addition

2011 ◽  
Vol 311-313 ◽  
pp. 287-292 ◽  
Author(s):  
Qiang Zuo ◽  
Wei Wang ◽  
Meng Sen Gu ◽  
Hai Jiang Fang ◽  
Li Ma ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Heat Conduction ◽  
Hot Pressing ◽  
Coefficient Of Thermal Expansion ◽  
High Thermal Conductivity ◽  
Electronic Components ◽  
Pressing Method ◽  
Diamond Particles ◽  
Continuous Progress

The continuous progress of the electronic industries put forward a new requirement to the electronic components that must have an excellent heat conduction performance. Thus diamond-Cu composite is developed as a high thermal conductivity and low coefficient of thermal expansion material. A vacuum hot pressing method is chosen to prepare diamond-Cu composites and the thermal conductivity of the diamond-Cu composite is researched. The effects of different contents of chromium, the size of diamond particles and the content of diamond particles on the thermal conductivity of the diamond-Cu composite are discussed. The results demonstrate that the chromium element can improve the thermal conductivity of the composites and the thermal conductivity is largest when the content of chromium is 3 percent.

scholarly journals Thermal Properties of Copper Matrix-Ceramic Filler Composite Prepared by Polymer Solution Method

2022 ◽  
Vol 60 (1) ◽  
pp. 68-75
Author(s):  
Bok-Hyun Oh ◽  
Chung-Il Ma ◽  
Ji-Yeon Kwak ◽  
Heon Kong ◽  
Sang-Jin Lee
Keyword(s):  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Thermal Expansion Coefficient ◽  
Expansion Coefficient ◽  
Heat Dissipation ◽  
Coefficient Of Thermal Expansion ◽  
High Thermal Conductivity ◽  
Ceramic Filler ◽  
Aqueous Solvent ◽  
Significant Difference

A copper (Cu) metal-ceramic filler composite with high thermal conductivity and a suitable thermal expansion coefficient was designed for application as a high-performance heat dissipation material. The purpose of the designed material was to utilize the high thermal conductivity of Cu while lowering its high coefficient of thermal expansion by using a ceramic filler. In this study, a Cu-sol containing a certain amount of AlN or SiC ceramic filler was prepared using a non-aqueous solvent. A complex was produced by applying a PVB polymer to prepare a homogeneous precursor. The composite sintered without pressure in a reducing atmosphere showed low thermal conductivity due to residual pores, but the hot press sintered composite exhibited improved thermal conductivity. The Cu composite with 30 wt% AlN filler added exhibited a thermal conductivity of 290 W/m·K and a thermal expansion coefficient of 9.2 × 10-6/oC. Due to the pores in the composite, the thermal conductivity showed some difference from the theoretical value calculated from the rule of mixture. However, the thermal expansion coefficient did not show any significant difference.

Evaluation of CeSZ Thermal Barrier Coatings for Diesels

2000 ◽  
Author(s):  
P.J. Huang ◽  
J.J. Swab ◽  
P.J. Patel ◽  
W.S. Chu
Keyword(s):  
Thermal Conductivity ◽  
Thermal Expansion ◽  
Thermal Barrier Coatings ◽  
Coefficient Of Thermal Expansion ◽  
Fuel Efficiency ◽  
Atmospheric Plasma ◽  
Thermal Barrier ◽  
Mechanical And Thermal Properties ◽  
Barrier Coatings ◽  
Spray Process

Abstract The development of thermal barrier coatings (TBCs) for diesel engines has been driven by the potential improvements in engine power and fuel efficiency that TBCs represent. TBCs have been employed for many years to reduce corrosion of valves and pistons because of their high temperature durability and thermal insulative properties. There are research programs to improve TBCs wear resistance to allow for its use in tribologically intensive areas of the engine. This paper will present results from tribological tests of ceria stabilized zirconia (CeSZ). The CeSZ was applied by atmospheric plasma spray process. Various mechanical and thermal properties were measured including wear, coefficient of thermal expansion, thermal conductivity, and microhardness. The results show the potential use of CeSZ in wear sensitive applications in diesel applications. Keywords: Thermal Barrier Coating, Diesel Engine, Wear, Thermal Conductivity, and Thermal Expansion

Mechanical Properties of Microscale Graphitic Carbon Foam Ligaments and Nodes

2009 ◽  
Author(s):  
S. Ganguli ◽  
A. K. Roy ◽  
R. Wheeler
Keyword(s):  
Thermal Conductivity ◽  
Thermal Management ◽  
Thermal Protection ◽  
Solid Phase ◽  
Coefficient Of Thermal Expansion ◽  
Carbon Foam ◽  
High Thermal Conductivity ◽  
Uniform Size ◽  
Open Cell ◽  
Carbon Foams

Carbon foam is recognized as having the greatest potential to replacement for metal fins in thermal management systems such as heat exchangers, space radiators, and thermal protection systems [1–5]. Carbon foam refers to a broad class of materials that include reticulated glassy, carbon and graphitic foams that are generally open-cell or mostly open-cell. They can be tailored to have low or high thermal conductivity with a low coefficient of thermal expansion and density. These foams have high modulus but low compression and tensile strength. Among the carbon foams, the graphitic foam offers superior thermal management properties such as high thermal conductivity. Graphitic foams are made of a network of spheroidal shell segments. Each cell has thin, stretched ligaments in the walls that are joined at the nodes or junctions. The parallel arrangement of graphene planes in the ligaments confers highly anisotropic properties to the walls of the graphitic foams. The graphene planes tend to be oriented with the plane of the ligaments but become disrupted at the junctions (nodes) of the walls. Since conduction is highest along parallel graphene planes, the thermal conductivity is highest in the plane of the ligaments or struts, and much lower in the direction transverse to the plane of these ligaments. In a previous study [6] extensive mechanical and thermal property characterization of carbon foams from Kopper Inc. (L1) and POCO Graphite, Inc. (P1) were reported. These foams were graphitic ones that are expected to have high thermal conductivity. Figure 1 shows sections of light microscopy images of the three foams of four foams. The most important thing to notice is that the images were not at the same magnification. The large cells in the GrafTech foam have an average diameter of only ∼100 μm but have a bimodal distribution cells with many small closed-cells few micrometers in diameter. Changes in density in the GrafTech foam was accompanied by a change in the large cells’ diameter — larger diameter giving greater porosity and lower density without changing the smaller cells’ sizes that filled the solid phase between the larger bubbles. The POCO foam has a fairly uniform size cell distribution of a few hundred micrometers. The Koppers’ foams show larger cells yet with the left (“L” precursor) having a uniform size while the right-hand (“D” precursor) is a less uniform and lower porosity.

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