scholarly journals Multi-Objective Optimized Overlapping Peak Separation Algorithm for Simultaneous Detection of Copper and Cobalt by Ultraviolet-Visible Spectroscopy

IEEE Access ◽  
2020 ◽  
Vol 8 ◽  
pp. 130896-130905
Author(s):  
Fengbo Zhou ◽  
Zhu Hongqi ◽  
Changgeng Li
2021 ◽  
Vol 11 (7) ◽  
pp. 3023
Author(s):  
Kejun Yang ◽  
Chenhaolei Han ◽  
Jinhua Feng ◽  
Yan Tang ◽  
Zhongye Xie ◽  
...  

The surface and thickness distribution measurement for transparent film is of interest for electronics and packaging materials. Structured illumination microscopy (SIM) is a prospective technique for measuring film due to its high accuracy and efficiency. However, when the distance between adjacent layers becomes close, the peaks of the modulation depth response (MDR) start to overlap and interfere with the peak extraction, which restricts SIM development in the field of film measurement. In this paper, an iterative peak separation algorithm is creatively applied in the SIM-based technique, providing a precise peak identification even as the MDR peaks overlap and bend into one. Compared with the traditional method, the proposed method has a lower detection threshold for thickness. The experiments and theoretical analysis are elaborated to demonstrate the feasibility of the mentioned method.


2021 ◽  
Vol 13 (14) ◽  
pp. 7907
Author(s):  
Fengbo Zhou ◽  
Ammar Oad ◽  
Hongqiu Zhu ◽  
Changgeng Li

In order to detect and control the concentration of polymetallic ions in industrial wastewater in real time, a spectrophotometric method combining wavelet transform (WT) and partial least squares regression (PLSR) is proposed for the simultaneous determination of zinc, cobalt and nickel in industrial wastewater by ultraviolet-visible spectrometry, without a separation step. WT was found to be suitable for spectral preprocessing, which effectively eliminated the noise, enhanced spectral feature information, improved the linearity of the detected ions and increased the number of selectable modeling wavelengths. PLSR was used to study the simultaneous detection of zinc, cobalt and nickel. The linear detection ranges were 10–100 mg/L for zinc, 0.6–6.0 mg/L for nickel and 0.3–3.0 mg/L for cobalt. The average relative deviation for zinc, nickel and cobalt was 2.85%, 3.05% and 2.24%, respectively. The results indicated that the WT–PLSR method is suitable for the online detection of polymetallic ions by ultraviolet-visible spectroscopy in zinc industrial wastewater.


1996 ◽  
Vol 76 (06) ◽  
pp. 1090-1095 ◽  
Author(s):  
C Ravanat ◽  
M Freund ◽  
S Schuhler ◽  
P Grunert ◽  
L Meyer ◽  
...  

SummaryThe purpose of this study was to develop specific and sensitive immunoassays to detect early indices of hypercoagulability in the rat. Rat platelet factor 4 (rPF4) and rat fibrinopeptide A (rFPA) assays, tools for the detection of activation of platelets and coagulation respectively, were designed using antibodies raised against purified rPF4 and against synthetic rFPA. The relevance of these new assays and of the commercially available ELISA kit for thrombin-antithrombin III (TAT) complexes was demonstrated in a rat model of a prethrombotic state induced by intravenous infusion of varying doses of thromboplastin (90 to 2400 μl/kg/h). In this model, the immunoassays allowed simultaneous detection of low levels of rFPA and rPF4 which were correlated with fibrinogen and platelet consumption and TAT generation and further proved to be of higher sensitivity than the classical methods of platelet count or measurement of fibrinogen levels. Plasma concentrations of rFPA, rPF4 and TAT were dependent on infusion time and thromboplastin dose, while hirudin (1 mg/kg) prevented their appearance. Thus the new specific immunoassays for rPF4 and rFPA and the commercial human TAT assay represent useful tools for pathophysiological studies or the screening of antithrombotic drugs in rats.


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