scholarly journals Photoluminescent Detection of Dissolved Underwater Trace Explosives

2010 ◽  
Vol 10 ◽  
pp. 546-562 ◽  
Author(s):  
Tye Langston

A portable, rapid, and economical method forin situtrace explosive detection in aqueous solutions was demonstrated using photoluminescence. Using europium/thenoyltrifluoroacetone as the reagent, dissolved nitroglycerin was fluorescently tagged and detected in seawater solutions without sample preparation, drying, or preconcentration. The chemical method was developed in a laboratory setting and demonstrated in a flow-through configuration using lightweight, inexpensive, commercial components by directly injecting the reagents into a continually flowing seawater stream using a small amount of organic solvent (approximately 8% of the total solution). Europium's vulnerability to vibrational fluorescence quenching by water provided the mode of detection. Without nitroglycerin in the seawater solution, the reagent's fluorescence was quenched, but when dissolved nitroglycerin was present, it displaced the water molecules from the europium/thenoyltrifluoroacetone compound and restored fluorescence. This effort focused on developing a seawater sensor, but performance comparisons were made to freshwater. The method was found to perform better in freshwater and it was shown that certain seawater constituents (such as calcium) have an adverse impact. However, the concentrations of these constituents are not expected to vary significantly from the natural seawater used herein.

2005 ◽  
Vol 8 (06) ◽  
pp. 491-501 ◽  
Author(s):  
Cynthia L. Dinwiddie

Summary Laboratory measurement of permeability using a Hassler cell is the industry standard; however, consistently removing undisturbed rock samples from friableout crops is difficult. Although various conventional surface-sealing mini-permeameters are developed as an alternative for permeability measurement, these devices generally suffer from difficulties in maintaining optimal forces on the tip seal when dealing with outcrop irregularities in the field; outcrop weathering is also problematic. Because a reliable field method is needed for studies of friable geological units, this paper presents an innovative technique for measuring permeability in situ. The design of the small-drill hole minipermeameter probe is discussed, as well as the accompanying analytical technique and the size and shape of the instrument's averaging volume. Small-diameter holes [i.e., 1.8 cm (0.7 in.)] are drilled into an outcrop with a masonry drill, followed by drillhole vacuuming, probe insertion, sealexpansion, gas injection, and calculation of the intrinsic permeability through measurement of the injection pressure, gas-flow rate, and knowledge of the system geometry. Advantages of this approach include access to a nonweathered surface, an operator-independent sealing mechanism around the air-injection zone, and the potential for permeability measurement at multiple depths below an outcrop surface. To date, data have been collected from four diverse porousmedia: upper and lower shoreface sandstone (Escalante, Utah), saprolitic soils(Clemson, South Carolina), nonwelded and sintered ignimbrite (Bishop, California), and fluvially reworked tuffaceous sedimentary rock (Bishop, California). The probe has proved durable and robust, with a single probe sufficient for making thousands of measurements in a variety of environments. Data quality supports the conclusion that the drillhole probe is a practical field instrument. Introduction Small-scale permeability heterogeneity plays a substantial role in petroleum migration and reservoir performance; this parameter commonly ranges over many orders of magnitude (e.g., 0.01 to more than 10,000 md). Permeability heterogeneities on the meter-to-micrometer scale associated with beds, laminae, internal sedimentary structures, and variations in pore morphology are the source of most retrieval difficulties during enhanced-oil-recovery operations, thus negatively affecting reservoir recovery efficiency. Considerable heterogeneity is evident when permeability measurements are made on small scales, either in the field or on field samples in a laboratory setting. Traditionally, small-scale permeability measurements are made by inducing 1D gas flow through a cylindrical core plug in a Hassler sleeve or cell. Recently, such measurements also are made by inducing multidimensional gas flow through a sample with various configurations of the conventional surface-sealing gas minipermeameter. Cylindrical plugs generally are extracted from continuous core at 30-cmintervals for Hassler-cell permeability measurement, preserving a majority of the core while minimizing associated costs. Except for relatively homogeneous formations, this scale of permeability measurement is in an ill-defined geologic region, falling within the range of laminae and lamina sets. Furthermore, core-plug samples tend to be biased toward the more consolidated, less permeable, and less friable core sections. As an example, the effect of this arbitrary sampling density on Hassler-sleeve measurements for the case of tight gas sands is that magnitudes of permeability less than 100 md frequently result, even when coarser-grained beds that would operate as preferential flow channels or "thief zones" are clearly present. Currently, the scale of sedimentary heterogeneity is best resolved by use of the minipermeameter, which allows investigation of permeability heterogeneity at much greater (and statistically significant) sampling densities and on much smaller scales than is possible with the traditional technique. The literature documents use of the conventional surface-sealing minipermeameter probe for measurements made on outcrop surfaces, core plugs, slabbed cores, or large-cut blocks. One motivation for using cores, plugs, or blocks of rock is that natural weathering processes may greatly affect permeability values obtained from exposed outcrop surfaces. The weathering effect has been shown to extend up to several inches below the rock surface. Beyond the issue of weathering, there are other rationales for discouraging use of the conventional surface-sealing minipermeameter probe in a field setting. When applying this probe geometry to natural rock outcroppings in the field, as opposed to cut specimens in an automated laboratory setting, seal-quality problems are often encountered because of irregular, rough surfaces and difficulties associated with manually holding the probe stationary while applying a uniform normal force of the optimal magnitude on the tip seal. To enable in-situ measurements of friable geologic units and to overcome weathering and seal-quality problems, a new minipermeameter probe has been developed that is specifically intended for application inside a small drilled hole. The design of the small-drillhole minipermeameter probe is discussed in what follows, as well as the accompanying analytical technique and the size and shape of the instrument's averaging volume. This article concludes with brief reviews of data collected using the technique.


Hydrobiologia ◽  
1989 ◽  
Vol 188-189 (1) ◽  
pp. 277-283 ◽  
Author(s):  
C. Lindblad ◽  
U. Kautsky ◽  
C. André ◽  
N. Kautsky ◽  
M. Tedengren

2006 ◽  
Vol 77 (2) ◽  
pp. 023105 ◽  
Author(s):  
Simon R. Bare ◽  
George E. Mickelson ◽  
Frank S. Modica ◽  
Andrzej Z. Ringwelski ◽  
N. Yang

2012 ◽  
Vol 10 (3) ◽  
pp. 117-128 ◽  
Author(s):  
Ryan J. Bell ◽  
William B. Savidge ◽  
Strawn K. Toler ◽  
Robert H. Byrne ◽  
R. Timothy Short

2004 ◽  
Vol 76 (1) ◽  
pp. 115-122 ◽  
Author(s):  
K. Ichikawa ◽  
S. Sato ◽  
N. Shimomura

The metastable surface structure and dynamics of water molecules, cations, and anions at the interface between KBr(001) and water have been demonstrated from the images in situ observed in atomic resolution using atomic force microscopy. The vertical motion of potassium ions, which means their own transfer from the equilibrium sites to the upper height right on the underlying bromide ions, has been observed at the interface. They are used to be located in some steady state stabilized by their interaction with water molecules in the double atomic layer at the interface. The observed water molecules bridge two bromide ions by hydrogen bond; the water molecules are sandwiched by the potassium ions and vice versa.


2016 ◽  
Vol 206 ◽  
pp. 36-44 ◽  
Author(s):  
Marc-Antoni Goulet ◽  
Aronne Habisch ◽  
Erik Kjeang

2009 ◽  
Vol 2009 ◽  
pp. 1-5 ◽  
Author(s):  
Minerva Vargas ◽  
Marina E. Rincón ◽  
Eduardo Ramos

The elaboration of bilayerTiO2/CNTfilms dried under terrestrial gravity conditions (g) and on a centrifuge with 1.3gand 7gis reported. The changes in microstructure and thickness of these coatings under supergravity environment cause a red-shift tendency in the optical properties at increasing values of acceleration. Experiments of a drop under enhanced gravity force in the range of 3.7 < Bo (bond number) < 51.5 suggest the incomplete elimination of surfactant-water molecules in theTiO2/CNTbilayer film. Increasing acceleration up to 14gwill widen the optical differences found, proving the layer-by-layer solution-chemical method in combination with these drying protocols, an alternative to produce thickness-sensitive solar-selective absorbing coatings.


2018 ◽  
Vol 72 (8) ◽  
pp. 1234-1243 ◽  
Author(s):  
Shichuan Xi ◽  
Xin Zhang ◽  
Zhendong Luan ◽  
Zengfeng Du ◽  
Lianfu Li ◽  
...  

Raman spectroscopy has been applied to the quantitative analysis of the concentration of bisulfate in acid-sulfate fluids at different temperatures. The quantitative analysis method is based on the peak area ratios of [Formula: see text](ν1) and H2O (ν2), where PA([Formula: see text]/H2O) = [[Formula: see text]] × (0.0066 × T + 1.3070) at a temperature range of 0–100 ℃. We found that the molal scattering coefficient of bisulfate increases slightly at the elevated temperature may be due to the changes of fraction of water molecules that are hydrogen-bonded. The method can also be applied to analyze physicochemical parameters of other acid fluids, such as hydrogen phosphate, bicarbonate, etc., and especially to the in situ detection of deep sea acid-sulfate hydrothermal fluids in the future.


1993 ◽  
Vol 74 (4) ◽  
pp. 1499-1503 ◽  
Author(s):  
W. F. Brechue ◽  
B. T. Ameredes ◽  
G. M. Andrew ◽  
W. N. Stainsby

Blood flow through the gastrocnemius-plantaris muscle of the dog in situ was increased by a pump in the arterial supply during a 30-min period of 1/s isotonic tetanic contractions. Compared with a control series of experiments with normoxemia and spontaneous flow, the pump increased flow 84%, from 1.51 +/- 0.08 to 2.78 +/- 0.15 ml.g-1.min-1. The perfusion pressure was increased from 125 to 196 mmHg. The pump hyperemia increased maximal O2 uptake (VO2) at 5 min of contractions by 31%, from 8.97 +/- 0.44 to 12.89 +/- 0.30 mumol.g-1.min-1. The extraction was decreased, and venous PO2 (PVO2) was increased. Fatigue, measured as a drop in power production from the highest level at 10 s to 30 min, was 49% during pump hyperemia and 54% in the control conditions. VO2 decreased 30% from the 5-min value to the 30-min value with pump hyperemia and 28% over the same time in the control conditions. At maximal VO2, the ratio VO2/PVO2 was increased by pump hyperemia compared with control conditions, suggesting an increased O2 diffusing conductance of the muscles. We conclude that the elevated perfusion pressure of pump hyperemia increased flow to raise maximal VO2 mainly in areas of the muscle that had restricted flow under control conditions.


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