Influence of capillarity on chemical stability and of electric field on surface tension near the critical point

1998 ◽  
Vol 356 (1739) ◽  
pp. 819-828 ◽  
Author(s):  
A. Sanfeld
Keyword(s):  
Surface Tension ◽  
Electric Field ◽  
Critical Point ◽  
Chemical Stability

The Critical Point Drying Method Applied to Scanning Electron Microscopy of L-929 Cells

1970 ◽  
Vol 28 ◽  
pp. 278-279
Author(s):  
Charles TurnbiLL ◽  
Delbert E. Philpott
Keyword(s):  
Electron Microscopy ◽  
Carbon Dioxide ◽  
Surface Tension ◽  
Critical Point ◽  
Freeze Drying ◽  
Attractive Alternative ◽  
Crystal Formation ◽  
Critical Point Drying ◽  
Time Required ◽  
Scanning Electron

The advent of the scanning electron microscope (SCEM) has renewed interest in preparing specimens by avoiding the forces of surface tension. The present method of freeze drying by Boyde and Barger (1969) and Small and Marszalek (1969) does prevent surface tension but ice crystal formation and time required for pumping out the specimen to dryness has discouraged us. We believe an attractive alternative to freeze drying is the critical point method originated by Anderson (1951; for electron microscopy. He avoided surface tension effects during drying by first exchanging the specimen water with alcohol, amy L acetate and then with carbon dioxide. He then selected a specific temperature (36.5°C) and pressure (72 Atm.) at which carbon dioxide would pass from the liquid to the gaseous phase without the effect of surface tension This combination of temperature and, pressure is known as the "critical point" of the Liquid.

scholarly journals Liquid toroidal drop under uniform electric field

2017 ◽  
Vol 473 (2202) ◽  
pp. 20160633 ◽  
Author(s):  
Michael Zabarankin
Keyword(s):  
Surface Tension ◽  
Electric Field ◽  
Dielectric Constants ◽  
Uniform Electric Field ◽  
Normal Velocity ◽  
Spherical Drop ◽  
Electric Stress ◽  
Freely Suspended ◽  
Major Radius ◽  
External Forces

The problem of a stationary liquid toroidal drop freely suspended in another fluid and subjected to an electric field uniform at infinity is addressed analytically. Taylor’s discriminating function implies that, when the phases have equal viscosities and are assumed to be slightly conducting (leaky dielectrics), a spherical drop is stationary when Q =(2 R 2 +3 R +2)/(7 R 2 ), where R and Q are ratios of the phases’ electric conductivities and dielectric constants, respectively. This condition holds for any electric capillary number, Ca E , that defines the ratio of electric stress to surface tension. Pairam and Fernández-Nieves showed experimentally that, in the absence of external forces (Ca E =0), a toroidal drop shrinks towards its centre, and, consequently, the drop can be stationary only for some Ca E >0. This work finds Q and Ca E such that, under the presence of an electric field and with equal viscosities of the phases, a toroidal drop having major radius ρ and volume 4 π /3 is qualitatively stationary—the normal velocity of the drop’s interface is minute and the interface coincides visually with a streamline. The found Q and Ca E depend on R and ρ , and for large ρ , e.g. ρ ≥3, they have simple approximations: Q ∼( R 2 + R +1)/(3 R 2 ) and Ca E ∼ 3 3 π ρ / 2   ( 6  ln  ⁡ ρ + 2  ln ⁡ [ 96 π ] − 9 ) / ( 12  ln  ⁡ ρ + 4  ln ⁡ [ 96 π ] − 17 )   ( R + 1 ) 2 / ( R − 1 ) 2 .

Amplitude of the surface tension near the critical point

1984 ◽  
Vol 29 (1) ◽  
pp. 472-475 ◽  
Author(s):  
Edouard Brézin ◽  
Shechao Feng
Keyword(s):  
Surface Tension ◽  
Critical Point

scholarly journals Network of Palladium-Based Nanorings Synthesized by Liquid-Phase Reduction Using DMSO-H2O: In Situ Monitoring of Structure Formation and Drying Deformation by ASEM

2020 ◽  
Vol 21 (9) ◽  
pp. 3271 ◽  
Author(s):  
Takuki Komenami ◽  
Akihiro Yoshimura ◽  
Yasunari Matsuno ◽  
Mari Sato ◽  
Chikara Sato
Keyword(s):  
Surface Tension ◽  
Liquid Phase ◽  
Aqueous Solutions ◽  
Critical Point ◽  
Synthesis Method ◽  
Three Dimensional ◽  
In Situ Monitoring ◽  
Critical Point Drying ◽  
Micrometer Size

We developed a liquid-phase synthesis method for Pd-based nanostructure, in which Pd dissolved in dimethyl sulfoxide (DMSO) solutions was precipitated using acid aqueous solution. In the development of the method, in situ monitoring using atmospheric scanning electron microscopy (ASEM) revealed that three-dimensional (3D) Pd-based nanonetworks were deformed to micrometer-size particles possibly by the surface tension of the solutions during the drying process. To avoid surface tension, critical point drying was employed to dry the Pd-based precipitates. By combining ASEM monitoring with critical point drying, the synthesis parameters were optimized, resulting in the formation of lacelike delicate nanonetworks using citric acid aqueous solutions. Precipitation using HCl acid aqueous solutions allowed formation of 500-nm diameter nanorings connected by nanowires. The 3D nanostructure formation was controllable and modifiable into various shapes using different concentrations of the Pd and Cl ions as the parameters.

scholarly journals Sedimentation of a surfactant-laden drop under the influence of an electric field

2018 ◽  
Vol 849 ◽  
pp. 277-311 ◽  
Author(s):  
Antarip Poddar ◽  
Shubhadeep Mandal ◽  
Aditya Bandopadhyay ◽  
Suman Chakraborty
Keyword(s):  
Surface Tension ◽  
Electric Field ◽  
Surfactant Concentration ◽  
Perturbation Technique ◽  
Internal Flow ◽  
Dielectric Fluid ◽  
Regular Perturbation ◽  
Spherical Drop ◽  
Leaky Dielectric ◽  
Marangoni Stress

The sedimentation of a surfactant-laden deformable viscous drop acted upon by an electric field is considered theoretically. The convection of surfactants in conjunction with the combined effect of electrohydrodynamic flow and sedimentation leads to a locally varying surface tension, which subsequently alters the drop dynamics via the interplay of Marangoni, Maxwell and hydrodynamic stresses. Assuming small capillary number and small electric Reynolds number, we employ a regular perturbation technique to solve the coupled system of governing equations. It is shown that when a leaky dielectric drop is sedimenting in another leaky dielectric fluid, the Marangoni stress can oppose the electrohydrodynamic motion severely, thereby causing corresponding changes in the internal flow pattern. Such effects further result in retardation of the drop settling velocity, which would have otherwise increased due to the influence of charge convection. For non-spherical drop shapes, the effect of Marangoni stress is overcome by the ‘tip-stretching’ effect on the flow field. As a result, the drop deformation gets intensified with an increase in sensitivity of the surface tension to the local surfactant concentration. Consequently, for an oblate type of deformation the elevated drag force causes a further reduction in velocity. For similar reasons, prolate drops experience less drag and settle faster than the surfactant-free case. In addition to this, with increased sensitivity of the interfacial tension to the surfactant concentration, the asymmetric deformation about the equator gets suppressed. These findings may turn out to be of fundamental significance towards designing electrohydrodynamically actuated droplet-based microfluidic systems that are intrinsically tunable by varying the surfactant concentration.

Electric-field-induced structure in polymer solutions near the critical point

1992 ◽  
Vol 25 (26) ◽  
pp. 7234-7246 ◽  
Author(s):  
Denis Wirtz ◽  
Klaus Berend ◽  
Gerald G. Fuller
Keyword(s):  
Electric Field ◽  
Critical Point ◽  
Polymer Solutions ◽  
Induced Structure

Surface Deformation and Convection in Electrostatically-Positioned Droplets of Immiscible Liquids Under Microgravity

2005 ◽  
Vol 128 (6) ◽  
pp. 520-529 ◽  
Author(s):  
Y. Huo ◽  
B. Q. Li
Keyword(s):  
Surface Tension ◽  
Fluid Flow ◽  
Free Surface ◽  
Electric Field ◽  
Outer Layer ◽  
Thermal Gradient ◽  
Surface Deformation ◽  
Inertia Force ◽  
Weighted Residuals ◽  
Inertia Forces

A numerical study is presented of the free surface deformation and Marangoni convection in immiscible droplets positioned by an electrostatic field and heated by laser beams under microgravity. The boundary element and the weighted residuals methods are applied to iteratively solve for the electric field distribution and for the unknown free surface shapes, while the Galerkin finite element method for the thermal and fluid flow field in both the transient and steady states. Results show that the inner interface demarking the two immiscible fluids in an electrically conducting droplet maintains its sphericity in microgravity. The free surface of the droplet, however, deforms into an oval shape in an electric field, owing to the pulling action of the normal component of the Maxwell stress. The thermal and fluid flow distributions are rather complex in an immiscible droplet, with conduction being the main mechanism for the thermal transport. The non-uniform temperature along the free surface induces the flow in the outer layer, whereas the competition between the interfacial surface tension gradient and the inertia force in the outer layer is responsible for the flows in the inner core and near the immiscible interface. As the droplet cools into an undercooled state, surface radiation causes a reversal of the surface temperature gradients along the free surface, which in turn reverses the surface tension driven flow in the outer layer. The flow near the interfacial region, on the other hand, is driven by a complimentary mechanism between the interfacial and the inertia forces during the time when the thermal gradient on the free surface has been reversed while that on the interface has not yet. After the completion of the interfacial thermal gradient reversal, however, the interfacial flows are largely driven by the inertia forces of the outer layer fluid.

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