Comparison of the Sorption of Hydrogen Phosphide, Methyl Bromide, Ethylene Dibromide, and Hydrocyanic Acid by Wheat and Corn of Different Moisture Contents and Load Factors

1971 ◽  
Vol 64 (1) ◽  
pp. 122-123 ◽  
Author(s):  
L. E. Vincent ◽  
D. L. Lindgren
1976 ◽  
Vol 16 (82) ◽  
pp. 780 ◽  
Author(s):  
G Singh ◽  
LE Rippon ◽  
WS Gilbert ◽  
BL Wild

Inorganic bromide residues were evaluated from fumigation schedules available in Australia for use against Queensland fruit fly, Dacus tryoni (Froggatt) and light brown apple moth, Epiphyas postvittana (Walker) in fruit and vegetables. Capsicums were fumigated for two hours at 20�C with 22 g m-3 ethylene dibromide (EDB). Bromide residues (40-45 �g g-1) were in excess of the maximum residue limit of 10 �g g-1 of the United States Food and Drug Administration (U.S.F.D.A.) and the current 20 �g g-1 recommendation of the Australian National Health and Medical Research Council (N.H.M.R.C.). Bananas were fumigated with dosages of 10, 12 and 14 g m-3 EDB for two hours at 20�C. Bromide residues increased with increasing dosages, and ranged from 11.7 to 15.6 �g g-1. Residues were within the recommended 20 �g g-1 limit of the N.H.M.R.C., but exceeded the 10 �g g-1 limit of the U.S.F.D.A. Cherries were fumigated for two hours at 15�C with 24 and 48 g m-3 methyl bromide (MB). Bromide residues (up to 8 �g g-1) were well within the 20 �g g-1 N.H.M.R.C. and U.S.F.D.A. limits. Apples were fumigated for two hours at 15�C with 24 g MB m-3 and at 7�C with 32 g MB m-3. Residues approximated or were less than the 5 �g g-1 limit of the U.S.F.D.A. and considerably lower than the 20 �g g-1 N.H.M.R.C. recommendation.


1975 ◽  
Vol 58 (4) ◽  
pp. 711-716 ◽  
Author(s):  
Milton E Getzendaner

Abstract Organic compounds containing bromine, including methyl bromide, ethylene dibromide, and l,2-dibromo-3-chloropropane, have been used extensively for the fumigation of foods, or soils in which foods grow, making it necessary to determine residues of bromine and bromine-containing organic compounds. A large number of methods for the determination of bromine in foods, as organic, inorganic, and combined total bromide, have been developed. In methods for organic bromide, the bromine is converted to the inorganic form for measurement by titration, photometry, or other means. In recent years, instrumental methods have been developed in which the total bromine in the sample is determined, regardless of the state in which it exists. X-ray fluorescence and neutron activation analysis are the 2 instrumental methods used most widely. Residue data are presented for some typical bromine-containing samples.


1978 ◽  
Vol 82 (20) ◽  
pp. 2252-2257 ◽  
Author(s):  
A. P. Uthman ◽  
P. J. Demlein ◽  
T. D. Allston ◽  
M. C. Withiam ◽  
M. J. McClements ◽  
...  

1942 ◽  
Vol 35 (4) ◽  
pp. 521-524 ◽  
Author(s):  
Harold R. Yust ◽  
R. L. Busbey ◽  
L. B. Howard

1953 ◽  
Vol 31 (3) ◽  
pp. 277-308 ◽  
Author(s):  
R. N. Wensley

Microbiological studies involving the use of three soil fumigants, methyl bromide, a propane–propene mixture, and ethylene dibromide, established a biological basis for the evaluation of soil fumigants as fungicides, bactericides, and actinomycides and provided quantitative and qualitative data from which the efficacy of each fumigant was rated as high, medium, low, and poor in each capacity and permitted a study of the significance of population trends. Due emphasis was placed on the two factors, concentration of the fumigant and the period of confined exposure, by determining the value of each factor required to produce, under controlled conditions of temperature and soil moisture, a 90% reduction in numbers of each microbiological group. Methyl bromide proved to be the most effective fumigant in all three capacities while ethylene dibromide formulations were least effective. The concentrations of, and exposure periods to, ethylene dibromide and the propane–propene mixture required to give satisfactory reduction of the three microbiological populations are considered high and neither fumigant is recommended as a fungicide, bactericide, or actinomycide. However, ethylene dibromide proved to be more effective than methyl bromide against root-knot nematodes and is recommended for use in this capacity. Soil fumigation effectively altered the microbiological balance in favor of fungi that were normally suppressed by a predominance of aspergilli and penicillia. Of four physiological groups of bacteria studied, nitrifiers and cellulose decomposers were most severely reduced in numbers by methyl bromide fumigation. The actinomycetes showed a greater tolerance of fumigation than either the fungi or bacteria.


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