scholarly journals Study of heavy metal fractionation in the Lami municipal disposal facility, Fiji

2016 ◽  
Vol 34 (1) ◽  
pp. 21 ◽  
Author(s):  
Shaneel Chandra ◽  
Philomena Gangaiya ◽  
Culwick Togamana ◽  
Surendra Prasad
Keyword(s):  
Heavy Metals ◽  
Marine Environment ◽  
Soil Samples ◽  
Threshold Values ◽  
Toxicity Threshold ◽  
Disposal Facility ◽  
Heavy Metal Fractionation ◽  
Screening Study ◽  
Copper Zinc ◽  
Management Controls

This work reports the first screening study of the bioavailability of heavy metals such as copper, zinc, lead and nickel in the Lami municipal disposal facility, Suva, Fiji where virtually uncontrolled dumping had been carried out for over fifty years. The soil samples from three parts of the facility were collected and the potential for mobility into the surrounding marine environment was assessed according to international guidelines. The results showed high levels of Pb in Site A (109.0 mg kg–1) and that Zn was the predominant metal across Sites B and C with 550.7 mg kg–1 and 206.8 mg kg–1, respectively. Ni was present in the least amount with the highest value 8.7 mg kg–1. In addition, Cu, Pb and Zn concentrations exceeded commonly used eco-toxicity threshold values. Moreover, there were indications that considerable leaching of the studied heavy metals may have been occurring for long periods of time at the sites. Overall, this study showed that even in areas with little industrialization, lack of adequate waste management controls could result in unusually high levels of heavy metals contamination of the soil. The results raise concerns about the wellbeing of the communities living adjacent to the Lami municipal disposal facility that depend on the adjacent marine environment for their subsistence.

scholarly journals First screening study of metal content in soil from a mixed waste receptacle

2015 ◽  
Vol 33 (2) ◽  
pp. 7 ◽  
Author(s):  
Shaneel Chandra ◽  
Philomena Gangaiya ◽  
Culwick Togamana ◽  
Surendra Prasad
Keyword(s):  
Heavy Metals ◽  
Metal Content ◽  
Threshold Values ◽  
Toxicity Threshold ◽  
Disposal Facility ◽  
Screening Study ◽  
Copper Zinc ◽  
Management Controls ◽  
Lead 210 ◽  
Lead Nickel

We report the first screening study for the metals copper, zinc, lead, nickel and cadmium in the Lami municipal disposal facility, in Suva, Fiji where virtually uncontrolled dumping has been carried out for over fifty years. Soil from three parts of the facility having had different degrees of usage was analysed for a range of heavy metals, and evaluated according to international guidelines. The results show copper (100–220 mg kg–1), lead (200–500 mg kg–1) and zinc (220–350 mg kg–1) concentrations exceeded commonly used eco-toxicity threshold values (copper, 160 mg kg–1; lead, 210 mg kg–1; and zinc, 220 mg kg–1). Moreover, there were indications that considerable leaching may have been occurring for long periods of time at the site. Overall, this study shows that even in areas with little industrialization, lack of adequate waste management controls can result in unusually high levels of contamination. The results raise concerns about the wellbeing of the communities living adjacent to the facility that depend on the adjacent marine environment for subsistence.

scholarly journals Preliminary study on Copper, Zinc and Iron concentration in soils from waste dumping site in Tanah Merah, Kelantan, Malaysia

2021 ◽  
Vol 8 (1) ◽  
pp. 12-16
Author(s):  
Muhammad Firdaus Abdul Karim ◽  
Kamarul Hambali ◽  
Ai Yin Sow ◽  
Nor Hizami Hassin ◽  
Muhamad Azahar Abas ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Iron Concentration ◽  
Atomic Absorption Spectrophotometry ◽  
Soil Samples ◽  
Complex Matrix ◽  
Heavy Metal Concentrations ◽  
Absorption Spectrophotometry ◽  
Dumping Site ◽  
Copper Zinc ◽  
Preliminary Study

Soil is a complex matrix and a major reservoir of contamination. It can bind many potential toxicelements such as heavy metals, and they can exist in various forms. The main objective was tocharacterize the soil sample in relation to heavy metal concentrations in the Tanah Merah wastedumping site. Soil samples were taken from three different locations around the waste dumping siteand determined by Atomic Absorption Spectrophotometry (AAS) for Cu, Fe and Zn determination.High concentrations of Fe (9.18 mg/L) as compared to Cu (0.53 mg/L), and Zn (0.49 mg/L) werefound in the soil samples but were lower than previous studies. However, early precautionaryactions need to be implemented since a higher volume of waste disposal in the future might causechanges in heavy metals intensity at the waste dumping site.

Determination of Elemental Composition of Soil Samples from Selected Dumpsites in Nasarawa, Kogi and Niger States, Nigeria

2019 ◽  
Vol 45 (4) ◽  
pp. 457-467
Author(s):  
J.J. Musa ◽  
J.D. Bala ◽  
H.I. Mustapha ◽  
M.Y. Otache ◽  
E.T. Musa ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Soil Samples ◽  
Industrial Wastes ◽  
Undisturbed Soil ◽  
Dump Site ◽  
Appropriate Treatment ◽  
Guideline Values ◽  
Copper Zinc ◽  
Treatment And Disposal ◽  
Mean Concentration

The growing dominance of urban environment with heavy metals through natural and anthropogenic depositions and the potentially adverse health implications following environmental contaminations have focused attention on the disposal of municipal and industrial wastes. This study employed analytical procedures to investigate the concentrations of chromium, iron, copper, zinc, manganese and aluminium at the municipal waste dump site of the study areas. Soil samples were randomly collected from different waste dumpsite across Nasarawa, Kogi, and Niger states and an undisturbed soil 100m away from the dumpsites was chosen as the control. From the result obtained, it was observed that the metals in all dumpsite types followed the order: Mn>Fe>Zn>Cu>Cr>Al. Mn had the highest mean concentration which was recorded in Bida, Borgu and Minna in Niger State while Al was the least detected in all the dumpsites with the lowest mean concentrations (5.7±0.96) recorded in Borgu. Mean concentration of all the metals at the dumpsites was higher than at the control which means there is an anthropogenic contribution from the environment. The concentrations of the heavy metals were generally lower than their respective guideline values for the protection of human and environmental health. However, with prolong practice of dumping refuse at these sites; concentrations of the heavy metals may increase above the recommended limits. Therefore, we recommend that further research be carried out on the heavy metals concentration of the waste materials to identify those that are potential sources of soil contamination to suggest appropriate treatment and disposal methods.

scholarly journals Soil contamination in landfills: a case study of a landfill in Czech Republic

Solid Earth ◽  
2016 ◽  
Vol 7 (1) ◽  
pp. 239-247 ◽  
Author(s):  
D. Adamcová ◽  
M. D. Vaverková ◽  
S. Bartoň ◽  
Z. Havlíček ◽  
E. Břoušková
Keyword(s):  
Heavy Metals ◽  
Plant Biomass ◽  
Sinapis Alba ◽  
Soil Samples ◽  
Germination Capacity ◽  
Threshold Values ◽  
Sinapis Alba L ◽  
Phytotoxicity Test ◽  
Ecotoxicity Tests

Abstract. A phytotoxicity test was determined to assess ecotoxicity of landfill soil. Sinapis alba L. was used as a bioindicator of heavy metals. Soil samples 1–8, which were taken from the landfill body, edge of the landfill body, and its vicinity meet the limits for heavy metals Co, Cd, Pb, and Zn specified in the applicable legislation. Hg and Mn threshold values are not established in legislation, but values have been determined for the needs of the landfill operator. For heavy metals Cr, Cu, and Ni sample 2 exceeded the threshold values, which attained the highest values of all the samples tested for Cr, Cu, and Ni. For Cr and Ni the values were several times higher than values of the other samples. The second highest values for Cr, Cu, and Ni showed sample 6 and 7. Both samples exceeded the set limits. An increase in plant biomass was observed in plants growing on plates with soil samples, but no changes in appearance, slow growth, or necrotic lesions appeared. Ecotoxicity tests show that tested soils (concentration of 50 %) collected from the landfill body, edge of the landfill body, and its vicinity reach high percentage values of germination capacity of seeds of Sinapis alba L. (101–137 %). At a concentration of 25 %, tested soil samples exhibit lower values of germination capacity – in particular samples 3 to 8 – yet the seed germination capacity in all eight samples of tested soils ranges between 86 and 137 %.

scholarly journals Environmental impact of landfill on groundwater quality and agricultural soils in Nigeria

2012 ◽  
Vol 7 (No. 1) ◽  
pp. 18-26 ◽  
Author(s):  
C.O. Akinbile
Keyword(s):  
Heavy Metals ◽  
Crop Production ◽  
Agricultural Soils ◽  
Soil Samples ◽  
World Health ◽  
Total Hardness ◽  
Iron Nitrate ◽  
Sanitary Landfills ◽  
Copper Zinc ◽  
Health Organization

Physical, chemical and bacteriological analyses were carried out of water samples from three boreholes located near a landfill, and or soil samples at Akure, Nigeria, to ascertain the effect of the dumpsite on the groundwater and soil quality. The samples from borehole locations with radial distances of 50, 80, and 100 m, respectively, away from the landfill and twelve soil samples collected at distances 0 (dump centre), 10, 20, and 30 m away from the refuse dump were analysed. The parameters determined were the turbidity, temperature, pH, dissolved oxygen (DO), total dissolved solids (TDS), total hardness (TH), total iron, nitrate, nitrite, chloride, calcium and heavy metals like copper, zinc, and lead. Most of these parameters indicated pollution but were below the World Health Organization (WHO) limits for consumption. The pH ranged from 5.7 to 6.8 indicating toxic pollution, the turbidity values were between 1.6 and 6.6 NTU, and the temperature ranged from 26.5°C to 27.5°C. The concentrations of iron, nitrate, nitrite and calcium ranged from 0.9 to 1.4, 30 to 61, 0.7 to 0.9, and 17 to 122 mg/l, respectively. Out of heavy metals, zinc ranged between 3.3 and 5.4 mg/l and lead ranged from 1.1 to 1.2 mg/l. Soil water holding capacity, porosity, pH, organic matter, organic carbon and organic nitrogen ranged from 38 to 54, 44 to 48, 6.9–7.5, 2.44–4.27, 1.42–2.48, and 0.12–0.21%, respectively. Statistical analyses indicated significant differences at 95% level. The results showed that all the boreholes were not strongly polluted but require treatment before use while the soil is absolutely unsuitable for the crop production. Re-designing of sanitary landfills to prevent leachate from getting to the water table, adoption of clean technology for recycling greenhouse gases and a sustainable land management programme for reclamation are recommended.

scholarly journals Soil contaminations in landfill: a case study of the landfill in Czech Republic

2015 ◽  
Vol 7 (4) ◽  
pp. 2927-2952 ◽  
Author(s):  
D. Adamcová ◽  
M. D. Vaverková ◽  
S. Bartoň ◽  
Z. Havlíček ◽  
E. Břoušková
Keyword(s):  
Heavy Metals ◽  
Plant Biomass ◽  
Sinapis Alba ◽  
Soil Samples ◽  
Germination Capacity ◽  
Threshold Values ◽  
Sinapis Alba L ◽  
Phytotoxicity Test ◽  
Ecotoxicity Tests

Abstract. Phytotoxicity test was determined to assess ecotoxicity of landfill soil. Sinapis alba L. was used as heavy metals bioindicator. Soil samples 1–8, which were taken from the landfill body, edge of the landfill body and its vicinity meet the limits for heavy metals Co, Cd, Pb, and Zn specified in the applicable legislation. Hg and Mn threshold values are not established in legislation, but values have been determined for the needs of the landfill operator. For heavy metals Cr, Cu, and Ni sample 2 exceeded the threshold values, which attained the highest values of all the samples tested for Cr, Cu and Ni. For Cr and Ni the values were several times higher than values of the other samples. The second highest values for Cr, Cu, and Ni showed sample 6 and 7. Both samples exceeded the set limits. An increase in plant biomass was observed in plants growing on plates with soil samples, but no changes in appearance, slow growth or necrotic lesions appeared. Ecotoxicity tests show that tested soils (concentration of 50 %) collected from the landfill body, edge of the landfill body and its vicinity reach high percentage values of germination capacity of seeds of Sinapis alba L. (101–137 %). At a concentration of 25 %, tested soil samples exhibit lower values of germination capacity; in particular samples 3 to 8, yet the seed germination capacity in all 8 samples of tested soils range between 86 and 137 %.

The impact of urban effluents on the coastal marine environment of Mediterranean islands

1995 ◽  
Vol 32 (9-10) ◽  
pp. 85-94 ◽  
Author(s):  
Michael O. Angelidis
Keyword(s):  
Heavy Metals ◽  
Organic Matter ◽  
Marine Environment ◽  
Suspended Particle ◽  
Pollution Source ◽  
Mediterranean Islands ◽  
Coastal Marine Environment ◽  
Coastal Marine ◽  
The Impact ◽  
The City

The impact of the urban effluents of Mytilene (Lesvos island, Greece) on the receiving coastal marine environment, was evaluated by studying the quality of the city effluents (BOD5, COD, SS, heavy metals) and the marine sediments (grain size, organic matter, heavy metals). It was found that the urban effluents of Mytilene contain high organic matter and suspended particle load because of septage discharge into the sewerage network. Furthermore, although the city does not host important industrial activity, its effluents contain appreciable metal load, which is mainly associated with the particulate phase. The city effluents are discharged into the coastal marine environment and their colloidal and particulate matter after flocculation settles to the bottom, where is incorporated into the sediments. Over the years, the accumulation of organic matter and metals into the harbour mud has created a non-point pollution source in the relatively non-polluted coastal marine environment of the island. Copper and Zn were the metals which presented the higher enrichment in the sediments of the inner harbour of Mytilene.

scholarly journals Contamination of Heavy Metals, Polychlorinated Dibenzo-p-Dioxins/Furans and Dioxin-Like Polychlorinated Biphenyls in Wharf Roach Ligia spp. In Japanese Intertidal and Supratidal Zones

2021 ◽  
Vol 11 (4) ◽  
pp. 1856
Author(s):  
Masato Honda ◽  
Xuchun Qiu ◽  
Suzanne Lydia Undap ◽  
Takeshi Kimura ◽  
Tsuguhide Hori ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Polychlorinated Biphenyls ◽  
Limit Of Detection ◽  
Environmental Pollutants ◽  
Dry Weight ◽  
Polychlorinated Dibenzofurans ◽  
Environmental Indicator ◽  
Pollution Levels ◽  
Copper Zinc ◽  
Total Concentrations

We investigated the pollution levels of 6 heavy metals and 29 dioxins (polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and dioxin-like polychlorinated biphenyls (DL-PCBs)) in intertidal and supratidal zones by using wharf roaches (Ligia spp.) collected from 12 sampling sites on the coast of Northeast Japan from November 2011 to June 2012. The total concentrations of heavy metals ranged from 177 to 377 µg/g-dry weight (dw), and the predominant metals were copper, zinc, and aluminum. The order of the detected level of heavy metals was zinc > aluminum > copper > cadmium > lead > chromium, and this trend was similar to a previous report. The total toxic equivalent (TEQ) value of the PCDD/Fs ranged from less than the limit of detection (<LOD) to 2.33 pg-TEQ/g-dw, and the predominant congener was octachlorodibenzodioxin (<LOD to 110 pg/g-dw). Compared with PCDD/Fs, DL-PCBs were detected at a predominantly higher level (total TEQ value: 0.64–27.79 pg-TEQ/g-dw). Detected levels of dioxins, especially DL-PCBs in the wharf roach, were like those in the bivalves. These results indicate that the wharf roach could reflect heavy metals and dioxin pollution in the supratidal zones and is a suitable environmental indicator for these environmental pollutants. This is the first study to investigate heavy metals, PCDD/Fs, and DL-PCBs pollution in coastal isopods in Japan.

scholarly journals Chemical Properties of Heavy Metal-Contaminated Soils from a Korean Military Shooting Range: Evaluation of Pb Sources Using Pb Isotope Ratios

2021 ◽  
Vol 11 (15) ◽  
pp. 7099
Author(s):  
Inkyeong Moon ◽  
Honghyun Kim ◽  
Sangjo Jeong ◽  
Hyungjin Choi ◽  
Jungtae Park ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Contaminated Soils ◽  
Management Strategies ◽  
Chemical Properties ◽  
Heavy Metal Concentration ◽  
Soil Samples ◽  
Shooting Range ◽  
Geochemical Properties ◽  
Mineral Phases

In this study, the geochemical properties of heavy metal-contaminated soils from a Korean military shooting range were analyzed. The chemical behavior of heavy metals was determined by analyzing the soil pH, heavy metal concentration, mineral composition, and Pb isotopes. In total, 24 soil samples were collected from a Korean military shooting range. The soil samples consist of quartz, albite, microcline, muscovite/illite, kaolinite, chlorite, and calcite. Lead minerals, such as hydrocerussite and anglesite, which are indicative of a transformation into secondary mineral phases, were not observed. All soils were strongly contaminated with Pb with minor concentrations of Cu, Ni, Cd, and Zn. Arsenic was rarely detected. The obtained results are indicated that the soils from the shooting range are contaminated with heavy metals and have evidences of different degree of anthropogenic Pb sources. This study is crucial for the evaluation of heavy metal-contaminated soils in shooting ranges and their environmental effect as well as for the establishment of management strategies for the mitigation of environmental risks.

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