scholarly journals Photoelectron Spectroscopy of Solids ? VUV Band Structure Studies

1990 ◽  
Vol 43 (5) ◽  
pp. 651 ◽  
Author(s):  
Robert Leckey ◽  
John Riley

The electronic band structure of solids, including states specific to the surface, may now be explored in very great detail by photoelectron spectroscopy. Variable energy photon sources (synchroton radiation sources) coupled with advanced angle resolving electron spectrometers permit access to emission from specific points within the complete Brillouin zone. The technique of band mapping has now reached a stage where the small k-dependent changes to individual valence bands due to the effects of introduced lattice strain can be observed, for example. The relative importance of emission from surface states, as opposed to bulk band states, can be demonstated dramatically using off-normal emission data. Angle resolved constant initial state spectroscopy has recently been shown to provide details of excited state bandstructure and has clarified the involvement of surface and bulk Umklapp scattering in the photoemission process. The above capabilities of photoelectron spectroscopy are discussed, using metallic and semiconducting examples, and are related to interface problems in general.

1987 ◽  
Vol 56 (7) ◽  
pp. 2581-2589 ◽  
Author(s):  
Nihal Gunasekara ◽  
Takashi Takahashi ◽  
Fumihiko Maeda ◽  
Takasi Sagawa ◽  
Hiroyoshi Suematsu

2018 ◽  
Vol 924 ◽  
pp. 239-244 ◽  
Author(s):  
Walter M. Klahold ◽  
Wolfgang J. Choyke ◽  
Robert P. Devaty

We use thick, relatively high purity 4H SiC boule material to measure the wavelength modulated absorption spectrum with improved wavelength resolution and sensitivity with respect to previous work. We observe several small 0.6 ± 0.1 meV splittings, which we attribute to electron mass anisotropy and electron-hole exchange interaction. In addition, we identify several features in the absorption spectrum as signatures of nonparabolicity in the free exciton dispersion relations, the primary origin of which is likely the nonparabolic energy dispersion of the valence bands, as revealed by published band structure calculations based on density functional theory.


2020 ◽  
Vol 2 (3) ◽  
pp. 1358-1364
Author(s):  
A. C. Pakpour-Tabrizi ◽  
A. K. Schenk ◽  
A. J. U. Holt ◽  
S. K. Mahatha ◽  
F. Arnold ◽  
...  

Using angle-resolved photoelectron spectroscopy, we compare the electronic band structure of an ultrathin (1.8 nm) δ-layer of boron-doped diamond with a bulk-like boron doped diamond film (3 μm).


Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 773
Author(s):  
Ke Wang ◽  
Ben Ecker ◽  
Yongli Gao

Angle-resolved photoemission spectroscopy (ARPES) is a vital technique, collecting data from both the energy and momentum of photoemitted electrons, and is indispensable for investigating the electronic band structure of solids. This article provides a review on ARPES studies of the electronic band structure of organic single crystals, including organic charge transfer conductors; organic semiconductors; and organo-metallic perovskites. In organic conductors and semiconductors, band dispersions are observed that are highly anisotropic. The Van der Waals crystal nature, the weak electron wavefunction overlap, as well as the strong electron-phonon coupling result in many organic crystals having indiscernible dispersion. In comparison, organo-metallic perovskite halides are characterized by strong s-p orbitals from the metal and halide at the top of the valence bands, with dispersions similar to those in inorganic materials.


2020 ◽  
Vol 8 (27) ◽  
pp. 9090-9132 ◽  
Author(s):  
Yasuo Nakayama ◽  
Satoshi Kera ◽  
Nobuo Ueno

Methodologies and experimental achievements for exploration into electronic band structures of organic semiconductor and hybrid perovskite single crystals are reviewed.


1992 ◽  
Vol 70 (10-11) ◽  
pp. 1099-1103 ◽  
Author(s):  
D. M. Swanston ◽  
A. B. McLean ◽  
D. N. McIlroy ◽  
D. Heskett ◽  
R. Ludeke ◽  
...  

The initial state dispersion of the two-dimensional electronic surface states on the nonpolar InAs(110) surface has been measured using momentum-resolved photoelectron spectroscopy with synchrotron radiation. The InAs(110) surfaces were grown using molecular beam epitaxy on a GaAs(110) substrate. The A5 surface state, which arises from the surface As lone pair, is split off from the bulk bands away from the surface zone centre and is clearly visible in the photoemission spectra at the high symmetry points ([Formula: see text], [Formula: see text] and [Formula: see text]) of the surface reciprocal lattice. Lower lying surface states overlap more strongly with the bulk bands and consequently it is harder to determine their band dispersion. To alleviate this problem we have applied nonlinear line shape analysis techniques to the valence bands. We demonstrate the viability of this approach to extract the binding energy and width of optical transitions.


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