Effect of electron concentration on electrical conductivity in in situ Al-TiB2 nanocomposites

2020 ◽  
Vol 116 (1) ◽  
pp. 014102 ◽  
Author(s):  
Shuaihang Pan ◽  
Jie Yuan ◽  
Peng Zhang ◽  
Maximilian Sokoluk ◽  
Gongcheng Yao ◽  
...  
2021 ◽  
pp. 004051752199547
Author(s):  
Min Hou ◽  
Xinghua Hong ◽  
Yanjun Tang ◽  
Zimin Jin ◽  
Chengyan Zhu ◽  
...  

Functionalized knitted fabric, as a kind of flexible, wearable, and waterproof material capable of conductivity, sensitivity and outstanding hydrophobicity, is valuable for multi-field applications. Herein, the reduced graphene oxide (RGO)-coated knitted fabric (polyester/spandex blended) is prepared, which involves the use of graphite oxide (GO) by modified Hummers method and in-situ chemical reduction with hydrazine hydrate. The treated fabric exhibits a high electrical conductivity (202.09 S/cm) and an outstanding hydrophobicity (140°). The outstanding hydrophobicity is associated with the morphology of the fabric and fiber with reference to pseudo-infiltration. These properties can withstand repeated bending and washing without serious deterioration, maintaining good electrical conductivity (35.70 S/cm) and contact angle (119.39°) after eight standard washing cycles. The material, which has RGO architecture and continuous loop mesh structure, can find wide use in smart garment applications.


RSC Advances ◽  
2016 ◽  
Vol 6 (87) ◽  
pp. 84200-84208 ◽  
Author(s):  
Adil Sultan ◽  
Sharique Ahmad ◽  
Faiz Mohammad

We report the synthesis of polypyrrole (PPy) and polypyrrole/silicon carbide nanocomposites (PPy/SiC) and PPy/SiC/dodecylbenzenesulfonic acid (DBSA) by in situ chemical polymerization and their application as sensors for the detection of highly toxic chlorine gas.


Energies ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 2849 ◽  
Author(s):  
Yong Du ◽  
Haixia Li ◽  
Xuechen Jia ◽  
Yunchen Dou ◽  
Jiayue Xu ◽  
...  

Graphite/poly(3,4-ethyenedioxythiophene) (PEDOT) nanocomposites were prepared by an in-situ oxidative polymerization process. The electrical conductivity and Seebeck coefficient of the graphite/PEDOT nanocomposites with different content of graphite were measured in the temperature range from 300 K to 380 K. The results show that as the content of graphite increased from 0 to 37.2 wt %, the electrical conductivity of the nanocomposites increased sharply from 3.6 S/cm to 80.1 S/cm, while the Seebeck coefficient kept almost the same value (in the range between 12.0 μV/K to 15.1 μV/K) at 300 K, which lead to an increased power factor. The Seebeck coefficient of the nanocomposites increased from 300 K to 380 K, while the electrical conductivity did not substantially depend on the measurement temperature. As a result, a power factor of 3.2 μWm−1 K−2 at 380 K was obtained for the nanocomposites with 37.2 wt % graphite.


2006 ◽  
Vol 11-12 ◽  
pp. 493-496 ◽  
Author(s):  
Ruben L. Menchavez ◽  
Koichiro Adachi ◽  
Masayoshi Fuji ◽  
Minoru Takahashi

This work demonstrated an in-situ pyrolysis of gelcast alumina under reduction sintering to make alumina and carbon composite in providing semi-electrical conductivity. To increase the carbon content, the monomer was varied in the premix solution with reduction sintering in nitrogen gas. Two-probe method was used to measure electrical resistance of the sintered samples. The results revealed that the increase of monomer addition and sintering treatment were effective in reducing electrical resistance. The lowest value was 3.6×106-cm, which is a potential candidate for electrostatic shielding application. The reduction-sintered sample was re-sintered in an air in order to gain insight on the conductive path due to carbon network. Further tests such as XRD, TGA/DTA, and scanning electron microscopywere used to explain the semi-conductive property of the material.


Soil Research ◽  
2001 ◽  
Vol 39 (6) ◽  
pp. 1359 ◽  
Author(s):  
I. Vogeler ◽  
S. Green ◽  
A. Nadler ◽  
C. Duwig

Time domain reflectometry (TDR) was used to monitor the transport of conservative tracers in the field under transient water flow in a controlled experiment under a kiwifruit vine. A mixed pulse of chloride and bromide was applied to the soil surface of a 16 m2 plot that had been isolated from the surrounding orchard soil. The movement of this solute pulse was monitored by TDR. A total of 63 TDR probes were installed into the plot for daily measurements of both the volumetric water content (θ) and the bulk soil electrical conductivity (σa). These TDR-measured σa were converted into pore water electrical conductivities (σw) and solute concentrations using various θ–σa–σw relationships that were established in the laboratory on repacked soil. The depth-wise field TDR measurements were compared with destructive measurement of the solute concentrations at the end of the experiment. These results were also compared with predictions using a deterministic model of water and solute transport based on Richards’ equation, and the convection–dispersion equation. TDR was found to give a good indication of the shape of the solute profile with depth, but the concentration of solute was under- or over-estimated by up to 50%, depending on the θ–σa–σw relationships used. Thus TDR can be used to monitor in situ transport of contaminants. However, only rough estimates of the electrical conductivity of the soil solution can so far be obtained by TDR.


POSITRON ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 52
Author(s):  
Kartika Hajar Kirana ◽  
Mechdi Ghazali ◽  
Luh Ayu Eka Safitri Septiana ◽  
Dini Fitriani ◽  
Eleonora Agustine ◽  
...  

Sungai Citarum merupakan sungai utama yang ada di Provinsi Jawa Barat yang sangat penting bagi kehidupan sosial dan ekonomi. Di bagian hilir, Sungai Citarum ini banyak melewati daerah pemukiman padat penduduk, daerah industri, dan bahkan pesawahan. Oleh karena itu, perlu kajian mengenai kondisi Sungai Citarum salah satunya dengan mengidentifikasi parameter electrical conductivity (EC), total dissolve solid (TDS), pH dan suhu serta karakteristik mineral magnetik pada sedimen melalui analisis sifat magnetik, mineralogi dan morfologi magnetiknya. Pengukuran parameter EC, TDS, pH dan suhu dilakukan secara in situ pada sampel air Sungai Citarum, pengukuran sifat magnetik dilakukan pada sampel sedimen yang telah dipreprasi, sedangkan pengukuran mineralogi dan morfologi dilakukan pada sampel sedimen yang telah diekstraksi. Sifat magnetik sedimen diketahui dari nilai suseptibilitas magnetik dual frekuensi yang diukur menggunakan Bartington Magnetik Susceptibilitymeter, sedangkan mineralogi dan morfologi magnetik diketahui berdasarkan hasil pengukuran scanning electron microscope–energy disperdsive x-ray (SEM-EDS) dan x-ray diffractometer (XRD). Hasil pengukuran secara in situ pada sampel air menunjukkan bahwa rentang nilai EC, TDS, pH dan suhu berturut-turut adalah (200–4120) mS/cm, (100–2060) ppt, 7,34–9,22, dan (26,8–32,6) oC. Sedangkan, hasil pengukuran sifat magnetik menunjukkan bahwa sampel sedimen Sungai Citarum bagian hilir memiliki nilai suseptibilitas magnetik frekuensi rendah (cLF) dengan rentang (65,00–173,80) x 10-8 m3/kg, sedangkan rentang nilai suseptibilitas magnetik frekuensi tinggi (cHF) adalah (64,90–165,70) x 10-8 m3/kg. Dari kedua pengukuran cLF dan cHF diperoleh rentang nilai cFD (%) sebesar 0,15–4,66. Selanjutnya, hasil analisis morfologi dari citra SEM-EDS dan analisis mineralogi berdasarkan pengukuran XRD menunjukkan dominasi jenis mineral magnetik pada sampel sedimen adalah magnetit. Mineral magnetit ini memiliki morfologi berbentuk oktahedral sebagai representasi mineral magnetik alami dan ada pula yang berbentuk spherule sebagai representasi mineral magnetik karena adanya proses oksidasi akibat kehadiran material antropogenik pada sedimen Sungai Citarum bagian hilir.


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