Preparation and characterization of polybutylene succinate (PBS) and polybutylene adipate-terephthalate (PBAT) biodegradable blends

2018 ◽  
Author(s):  
Maria Rossella Nobile ◽  
Andrea Crocitti ◽  
Mario Malinconico ◽  
Gabriella Santagata ◽  
Pierfrancesco Cerruti
2010 ◽  
Vol 156 (1) ◽  
pp. 65-69 ◽  
Author(s):  
Yu.N. Pankova ◽  
A.N. Shchegolikhin ◽  
A.L. Iordanskii ◽  
A.L. Zhulkina ◽  
A.A. Ol'khov ◽  
...  

2013 ◽  
Vol 706-708 ◽  
pp. 28-31
Author(s):  
Tong Wan ◽  
Si Zhang ◽  
Tao Du

A new poly (diethylene glycol adipate -co- neopentylglycol adipate) (PDNA) was synthesized from diethylene glycol adipate (DEAP) with neopentylglycol adipate (NPAP). The chemical structure of PDNA was characterized by 1H-NMR. PLA was plasticized by various amount of PDNA to obtain biodegradable blends. The effects of both temperature and shear rate on the rheologies of PLA/PDNA blends were evaluated by a parallel plate rheometer.


2016 ◽  
Vol 93 ◽  
pp. 276-289 ◽  
Author(s):  
F. Luzi ◽  
E. Fortunati ◽  
A. Jiménez ◽  
D. Puglia ◽  
D. Pezzolla ◽  
...  

Polymers ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 104
Author(s):  
Saw Yin Yap ◽  
Srimala Sreekantan ◽  
Mohd Hassan ◽  
Kumar Sudesh ◽  
Ming Thong Ong

The fabrication of affordable biodegradable plastics remains a challenging issue for both the scientific community and industries as mechanical properties and biodegradability improve at the expense of the high cost of the material. Hence, the present work deals with fabrication and characterization of biodegradable polymer with 40% rice husk waste filler and 60% polymer-containing mixture of polybutylene succinate (PBS) and poly butylenes adipate-Co-terephthalate (PBAT) to achieve good mechanical properties, 92% biodegradation in six months, and competitive pricing. The challenge in incorporating high amounts of hydrophilic nature filler material into hydrophobic PBS/PBAT was addressed by adding plasticizers such as glycerol and calcium stearate. The compatibilizers such as maleic anhydride (MA) and dicumyl peroxide (DCP) was used to improve the miscibility between hydrophobic PBS/PBAT and hydrophilic filler material. The component with the formulation of 24:36:40 (PBS/PBAT/TPRH) possessed the tensile strength of 14.27 MPa, modulus of 200.43 MPa, and elongation at break of 12.99%, which was suitable for the production of molded products such as a tray, lunch box, and straw. The obtained composite polymer achieved 92% mass loss after six months of soil burial test confirming its biodegradability.


2016 ◽  
Vol 36 (5) ◽  
pp. 473-480 ◽  
Author(s):  
Min Zhang ◽  
Xiaoqian Diao ◽  
Yujuan Jin ◽  
Yunxuan Weng

Abstract Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH) was blended with poly(butylene adipate-co-terephthalate) (PBAT) by extrusion at different weight ratios (PHBH/PBAT: 100:0, 80:20, 60:40, 50:50, 40:60, 20:80 and 0:100). Films were then prepared from the blends and characterized in terms of their morphological, rheological, mechanical and thermal properties. The morphological and rheological results indicated that PHBH/PBAT blends are immiscible but exhibit possible molecular interaction. The crystallization temperature of PHBH in the blends decreased, indicating that the addition of PBAT inhibited the crystallization of PHBH. Blending PBAT with PHBH improved the processability compared with that of pure polymers. The mechanical properties, including tensile strength, elongation at break and tear strength, increased with increasing PBAT content. The PHBH/PBAT 20:80 blend exhibited significantly improved mechanical properties, which was due to the reinforcing and toughening effect of the finely dispersed PHBH phase.


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