Thermal stability of TiSi2on mono‐ and polycrystalline silicon

1986 ◽  
Vol 60 (1) ◽  
pp. 243-246 ◽  
Author(s):  
C. Y. Wong ◽  
L. K. Wang ◽  
P. A. McFarland ◽  
C. Y. Ting
2001 ◽  
Vol 40 (Part 1, No. 11) ◽  
pp. 6307-6310
Author(s):  
Jong-Uk Bae ◽  
Dong Kyun Sohn ◽  
Ji-Soo Park ◽  
Chang Hee Han ◽  
Jin Won Park ◽  
...  

1990 ◽  
Vol 182 ◽  
Author(s):  
J. R. Phillips ◽  
P. Revesz ◽  
J. O. Olowolafe ◽  
J. W. Mayer

AbstractThe thermal stability of Co silicide on single crystal and polycrystalline Si has been investigated. Co films were evaporated onto (100) Si and undoped polycrystalline Si and annealed in vacuum. Resulting silicide films were examined using Rutherford backscattering spectroscopy, scanning electron microscopy, electron—induced x—ray spectroscopy, and sheet resistivity measurements. We find that CoSi2 on single crystal (100) Si remains stable through 1000ºC. In contact with undoped polycrystalline Si, intermixing begins at temperatures as low as 650ºC for 30min annealing. The Co silicide and Si layers are intermixed after 750ºC 30min annealing, giving islands of Si surrounded by silicide material, with both components extending from the surface down to the underlying oxide layer. The behavior of CoSi2 contrasts with results reported for TiSi2 which agglomerates on single crystal Si around 900ºC but is stable on polycrystalline silicon as high as 800ºC. Resistivity measurements show that the Co silicide remained interconnected despite massive incursion by Si into the silicide layer.


2002 ◽  
Vol 81 (22) ◽  
pp. 4157-4158 ◽  
Author(s):  
A. Callegari ◽  
E. Gousev ◽  
T. Zabel ◽  
D. Lacey ◽  
M. Gribelyuk ◽  
...  

1991 ◽  
Vol 6 (7) ◽  
pp. 1502-1511 ◽  
Author(s):  
Krishna Shenai

The stability of selectively formed TiSi2 films on single crystal and polycrystalline silicon layers at elevated process temperatures is reported. Extensive electrical and analytical studies were performed to understand the high-temperature stability of TiSi2 films as a function of (i) substrate dopant concentration, (ii) titanium silicide thickness, (iii) silicide formation sequence, and (iv) silicide post-processing steps. It is shown that all four process variations have a profound influence on the thermal stability of TiSi2 films. It is observed that titanium silicide films formed on single crystal silicon are stable at higher processing temperatures compared to those formed on polysilicon substrates under similar conditions. The degradation of high-temperature stability of TiSi2 films on polycrystalline silicon can be related to increased number of defects and grain boundaries. It is shown that TiSi2 films can be successfully used in silicon integrated circuit applications where the post-silicide processing temperatures do not exceed 1000 °C.


2002 ◽  
Vol 40 (4) ◽  
pp. 737 ◽  
Author(s):  
Kim Min-Joo ◽  
Choi Hyo-Jick ◽  
Ko Dae-Hong ◽  
Ku Ja-Hum ◽  
Choi Siyoung ◽  
...  

1990 ◽  
Vol 181 ◽  
Author(s):  
J. R. Phillips ◽  
P. Revesz ◽  
J. O. Olowolafe ◽  
J. W. Mayer

ABSTRACTThe thermal stability of Co silicide on single crystal and polycrystalline Si has been investigated. Co films were evaporated onto (100) Si and undoped polycrystalline Si and annealed in vacuum. Resulting silicide films were examined using Rutherford backscattering spectroscopy, scanning electron microscopy, electron-induced x-ray spectroscopy, and sheet resistivity measurements. We find that CoSi2 on single crystal (100) Si remains stable through 1000°C. In contact with undoped polycrystalline Si, intermixing begins at temperatures as low as 650°C for 30min annealing. The Co silicide and Si layers are intermixed after 750°C 30min annealing, giving islands of Si surrounded by silicide material, with both components extending from the surface down to the underlying oxide layer. The behavior of CoSi2 contrasts with results reported for TiSi2 which agglomerates on single crystal Si around 900°C but is stable on polycrystalline silicon as high as 800°C. Resistivity measurements show that the Co silicide remained interconnected despite massive incursion by Si into the silicide layer.


1997 ◽  
Vol 17 (1-4) ◽  
pp. 489-500 ◽  
Author(s):  
Yoo-Chan Jeon ◽  
Jeong-Min Seon ◽  
Jae-Hyun Joo ◽  
Ki-Young Oh ◽  
Jae-Sung Roh ◽  
...  

1987 ◽  
Vol 106 ◽  
Author(s):  
J. Randall Phillips ◽  
Lung-Ru Zheng ◽  
James W. Mayer

ABSTRACTThe thermal stability of silicide fine lines on undoped CVD polycrystalline silicon was investigated. Heat treatments were in vacuum at temperatures up to 950 ° C. We observed that fine silicide lines on undoped polysilicon degrade during vacuum annealing. Voids and hillocks are formed as silicon diffuses out from the fine grained poly-Si, undergoes long-range transport through the silicide, and recrystallizes into large grains. The phenomenon is similar to that seen previously in planar samples, but fine lines were found to degrade at lower temperatures and especially along line edges. Lines of two refractory metal silicides, TiSi2 and CrSi2, and one near-noble silicide, CoSi2 were examined.


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