Formation of Ge nanocrystals in HfAlO high-k dielectric and application in memory device

2004 ◽  
Vol 84 (26) ◽  
pp. 5407-5409 ◽  
Author(s):  
Ying Qian Wang ◽  
Jing Hao Chen ◽  
Won Jong Yoo ◽  
Yee-Chia Yeo ◽  
Sun Jung Kim ◽  
...  
2004 ◽  
Vol 830 ◽  
Author(s):  
Ch. Sargentis ◽  
K. Giannakopoulos ◽  
A. Travlos ◽  
D. Tsamakis

ABSTRACTMOS memory devices containing semiconductor nanocrystals have drawn considerable attention recently, due to their advantages when compared to the conventional memories. Only little work has been done on memory devices containing metal nanoparticles.We describe the fabrication of a novel MOS device with embedded Pt nanoparticles in the HfO2 / SiO2 interface of a MOS device. Using as control oxide, a high-k dielectric, our device has a great degree of scalability. The fabricated nanoparticles are very small (about 5 nm) and have high density. High frequency C-V measurements demonstrate that this device operates as a memory device.


2007 ◽  
Vol 102 (9) ◽  
pp. 094307 ◽  
Author(s):  
M. Y. Chan ◽  
P. S. Lee ◽  
V. Ho ◽  
H. L. Seng

2007 ◽  
Vol 997 ◽  
Author(s):  
Mei Yin Chan ◽  
Pooi See Lee ◽  
Vincent Ho

AbstractA simple technique for the formation of Ge nanocrystals embedded in amorphous Lu2O3 high-k dielectric was demonstrated by pulsed laser ablation followed by rapid thermal annealing in N2 ambient. The structure and composition of the Ge nanocrystals in the oxide matrix have been studied by transmission electron microscopy (TEM) and x-ray photoelectron spectroscopy (XPS) analysis. A significant change in the structure and chemical composition of the film was obtained upon annealing. Cross-sectional and plan-view TEM images confirmed the formation of small Ge nanocrystals in amorphous Lu2O3 matrix with a mean size of about 6nm in diameter and a high areal density of 7 × 1011cm−2. The nanocrystals are well-isolated by the amorphous Lu2O3 in between, with almost spherical shape which are favorable for non-volatile memory (NVM) application due to an effective charge confinement. XPS measurements on the as-deposited sample indicate the existence of Ge in its oxidized state, consisting of GeO2 and Ge suboxides. A spontaneous reduction of GeO2 and GeOx was obtained after the annealing treatment, which provides Ge nuclei for nanocrystal formation. It is found that a low annealing temperature of 400oC is sufficient to dissociate the GeO2 and GeOx leading to the formation of Ge nanocrystals. The application of the nanocrystals in NVM devices was demonstrated by C-V characterization of the memory capacitor devices fabricated with Al2O3 control oxide layer. C-V results show a significant effect of the structure and composition of the film on the electrical performance of the device. The annealed device exhibits good memory behavior with a large memory window of 1.2V achieved with a low operation voltage.


2010 ◽  
Vol 27 (6) ◽  
pp. 068502 ◽  
Author(s):  
Lv Shi-Cheng ◽  
Ge Zhong-Yang ◽  
Zhou Yue ◽  
Xu Bo ◽  
Gao Li-Gang ◽  
...  

2018 ◽  
Author(s):  
Seng Nguon Ting ◽  
Hsien-Ching Lo ◽  
Donald Nedeau ◽  
Aaron Sinnott ◽  
Felix Beaudoin

Abstract With rapid scaling of semiconductor devices, new and more complicated challenges emerge as technology development progresses. In SRAM yield learning vehicles, it is becoming increasingly difficult to differentiate the voltage-sensitive SRAM yield loss from the expected hard bit-cells failures. It can only be accomplished by extensively leveraging yield, layout analysis and fault localization in sub-micron devices. In this paper, we describe the successful debugging of the yield gap observed between the High Density and the High Performance bit-cells. The SRAM yield loss is observed to be strongly modulated by different active sizing between two pull up (PU) bit-cells. Failure analysis focused at the weak point vicinity successfully identified abnormal poly edge profile with systematic High k Dielectric shorts. Tight active space on High Density cells led to limitation of complete trench gap-fill creating void filled with gate material. Thanks to this knowledge, the process was optimized with “Skip Active Atomic Level Oxide Deposition” step improving trench gap-fill margin.


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